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Org Biomol Chem
; 16(44): 8491-8494, 2018 11 14.
Article
in English
| MEDLINE
| ID: mdl-30383060
ABSTRACT
The construction of the ABC tricyclic skeleton of malabanone A with the required 4 stereocenters was accomplished in a concise route starting from R-carvone. The synthesis featured an intramolecular [3 + 2] cycloaddition reaction to assemble its A ring and an intramolecular Diels-Alder reaction to construct its C ring.