[Traceability Analysis and Environmental Quality Assessment of Soil Heavy Metal Pollution in West Hunan Province].

In order to explore the status of soil heavy metal pollution and environmental quality in west Hunan, relevant areas of Phoenix County were selected as the study area. Using data from 440 soil samples collected in the study area from June to August 2022, the pH value of the soil and contents of eight heavy metal elements, namely, As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn, were analyzed. The PMF model was used for traceability analysis and geochemical evaluation of soil environmental quality. The results showed that the average values of soil heavy metals ω(Zn), ω(Cr), ω(Pb), ω(Ni), ω(Cu), ω(As), ω(Cd), and ω(Hg) were 81.02, 64.67, 31.63, 29.27, 25.52, 9.93, 0.28, and 0.13 mg·kg-1, respectively. The soil in the study area was mainly weakly acidic, and the contents of the Cd and Hg elements were relatively high compared to the national soil background values and were highly variable. The contents of the Hg and Cd elements in forest land were higher than that in other land uses. The PMF model results showed that the contribution rates of heavy metal pollution sources in the study area were mining sources (37.4%), atmospheric sedimentation sources (7.7%), natural sources (41.1%), and agricultural activity sources (13.8%) and provided suggestions on pollution control measures according to the spatial distribution of the four types of pollution sources. Through the comprehensive assessment of soil environmental geochemistry, the study area was divided into three types of plots, namely, non-risk areas (94.27 km2), accounting for 76.38%; risk-controllable areas (27.45 km2), accounting for 22.24%; and high-risk areas (1.7 km2), accounting for 1.38%. This study provided data support for the prevention and control measures of land pollution in the research area, as well as the delineation of the prevention and control scope.

[Geochemical Characteristics of Cd in Different Parent Soils in Karst Area and Prediction of Cd Content in Maize].

The naturally high background value region of Cd derived from the weathering of carbonate has received wide attention. Due to the significant difference in soil physicochemical properties, soil Cd content, and bioavailability of different parent materials in the karst area, there are certain limitations in using the total soil Cd content to classify the environmental quality of cultivated land. In this study, surface soil and maize samples of eluvium and alluvial parent material in typical karst areas were collected systematically; the contents of maize Cd, soil Cd, pH, and oxides were analyzed, the Cd geochemical characteristics of different parent soils and the influencing factors of their bioavailability were revealed, and scientific and effective arable land use zoning suggestions based on the prediction model were suggested. The results showed that the physicochemical properties of different parent material soils in the karst area were obviously different. The alluvial parent material soil had low Cd content but high bioavailability, and the maize Cd exceeding rate was high. The maize Cd bioaccumulation factor was significantly negatively correlated with soil CaO, pH, Mn, and TC, and the correlation coefficients were -0.385, -0.620, -0.484, and -0.384, respectively. Compared with the multiple linear regression prediction model, using the random forest model to predict the maize Cd enrichment coefficient had higher accuracy and precision. Furthermore, a new scheme for the safe utilization of cultivated land at the plot scale based on soil Cd and predicted crop Cd content was proposed in this study, making full use of arable land resources to ensure crop safety.

[Characteristics and Source Analysis of Heavy Metals in Farmland Soil on the South of Dongting Lake].

Based on the grid distribution method, 1589 topsoil samples were collected from farmland on the south side of Dongting Lake from April to August 2020. The content, potential ecological risk, spatial distribution characteristics, and source analysis of heavy metals in the soil were studied. The concentrations and pH of As, Cd, Pb, Cu, Zn, Ni, Cr, and Hg in the soil were determined using ICP-MS, ICP-OES, HG-AFS, and ISE methods. The results showed that the average concentrations of Zn, Cr, Pb, Cu, Ni, As, Cd, and Hg were 118.18, 82.21, 52.1, 33.76, 32.81, 18.25, 0.42, and 0.13 mg·kg-1, respectively. All heavy metals had medium or high variability. The soil was mainly weakly acidic with a pH between 3.96 and 7.90. Hg and Cd had high ecological risks. The spatial distribution of heavy metals showed a tendency of being high in the southwest and low in the northeast. The PMF and PCA methods were used to analyze the sources and calculate the contribution rates of the eight types of heavy metals. The PMF results showed that the contribution rates of soil heavy metals in the study area were as follows:agricultural activity sources (36.98%), natural sources (32.94%), water and soil exchange sources (17.05%), and atmospheric dry and wet deposition sources (13.03%). The PCA results showed that the soil heavy metals in the study area mainly came from agricultural activity sources (68.04%), natural sources (31.02%), and atmospheric deposition sources (0.94%). The conclusions of the two source analysis methods tended to be consistent, that is, agricultural activities were the main source of soil heavy metals in the study area. The vertical profile analysis showed that the contents of Cd, Hg, and Pb elements were high in the surface layer and low in the deep layer, and the phenomenon of anthropogenic input was obvious. These results can provide a scientific basis for the formulation of prevention and control countermeasures of farmland soil heavy metal pollution around Dongting Lake.

Characteristics and DGT Based Bioavailability of Cadmium in the Soil-Crop Systems from the East Edge of the Dongting Lake, China.

Contamination of heavy metals (including the cadmium, Cd) in agricultural soils has become an increased issue, posing a threat to the crop safety and human health. In order to evaluate the contamination characteristics and bioavailability of Cd in the soil−crop systems from the East edge of the Dongting Lake, four kinds of agricultural products for typical crops (rice, peanut, sweet potato, and corn) and corresponding rhizosphere soils were collected and analyzed for the Cd concentrations. The technique of diffusive gradients in thin-films (DGT) was applied to evaluate the Cd bioavailability in the rhizosphere soils. Concentrations of Cd ranged from 0.04 to 2.95 mg/kg (average 0.24 mg/kg) with 73.9% sites above the background levels, especially for paddy soils. Cd concentrations in the agricultural products ranged from 0.01 to 2.19 mg/kg (average 0.18 mg/kg), with Cd enrichment observed in the peanut samples. No obvious correlations (R2 < 0.25) were observed between the Cd concentrations in the agricultural products and total Cd concentrations in the rhizosphere soils, this indicated that the total Cd concentrations in the soils cannot predict the concentrations in the agricultural products of crops. While the DGT measured Cd concentrations showed good correlations (R2 = 0.64−0.90) with the concentrations in the most agricultural products of crops, which may be used to evaluate the safety of the soil and further safety of the agricultural products of crops. Overall, DGT showed a good potential for prediction of heavy metal bioavailability in soil since the DGT technique can simulate the sustained supply of heavy metals from solid to liquid in the soils.

Enhanced nutrient removal from stormwater runoff by a compact on-site treatment system.

Efficient and space-saving technologies for on-site treatment of stormwater runoff are required to control water pollution in the urban surface. The intermittent nature of stormwater runoff and extremely limited land available greatly hindered the application of current wastewater treatment technologies, and thus synchronous removal of multiple contaminants (especially for nutrient) efficiently was failed by current processes. In this study, a new compact CFFA treatment system, consisting of coagulation, flocculation, filtration and ammonium ion exchange units, was constructed for on-site treatment of stormwater runoff based on batch test optimization and pilot-scale test verification. The coagulation process effectively aggregated particles and precipitated phosphorus by dosing Al2(SO4)3, while flocculation using anionic polyacrylamide further enlarged particle size for efficient micromesh filtration. The dynamic micromesh filtration obtained turbidity and phosphorus removal efficiencies comparable to 30 min gravity settling with greatly smaller footprint. Ion exchange by zeolite showed higher exchange capacity owing to lower initial ammonium nitrogen concentration in the stormwater runoff. The pilot-scale experiments with treatment capacity of 1 L/s showed that the CFFA treatment system achieved synchronous removal of particles (97.2%), nitrogen (79.7%), phosphorus (95.0%) and organic matters (83.3%) efficiently within short hydraulic retention time of 0.35 h, yielding effluent with chemical oxygen demand, suspended solids, total phosphorus and total nitrogen of 38.7, 7.80, 0.22 and 2.80 mg/L, respectively. The CFFA treatment system had the highest pollutant removal loads compared to reported runoff treatment processes in literatures, and was well suited to on-site treatment of stormwater runoff with high space utilization efficiency.

Compact wastewater treatment process based on abiotic nitrogen management achieved high-rate and facile pollutants removal.

Chemically enhanced primary treatment (CEPT), ammonium ion exchange and regeneration (AIR) and membrane bioreactor (MBR) were coupled as CAIRM to treat domestic wastewater compactly and efficiently. CAIRM achieved efficient removal of chemical oxygen demand, ammonia nitrogen, total nitrogen (TN) and total phosphorus with total hydraulic retention time of 4.6 h, and obtained 2.3 ± 0.9 mg/L TN in the effluent. CEPT removed phosphate and impurities and prevented AIR from pollution. AIR maintained excellent nitrogen removal with a slight decrease in the exchange capacity of ion exchangers. MBR polished the effluent from AIR, and the larger particle size and better dewaterability of sludge mitigated the membrane fouling. Many heterotrophic genera, such as Rhodobacter and Defluviimonas, were enriched in the oligotrophic MBR. This study demonstrates the viability and stability of CAIRM in efficient wastewater treatment, which will address critical challenges in insufficient nitrogen removal and high land occupancy of current processes.

Emerging wastewater treatment strategy for efficient nitrogen removal and compact footprint by coupling mainstream nitrogen separation with chemical coagulation and biological aerated filter.

In this study, an ammonia nitrogen (NH4+-N) ion exchange (IE) and regeneration (AIR) was constructed, and the chemical enhanced primary treatment (CEPT), AIR and biological aerated filter (BAF) were coupled in series to construct a novel CEPT-AIR-BAF process for efficient pollutants removal. At total hydraulic retention time of 4.6 h, the pilot-scale CEPT-AIR-BAF system obtained effluent with chemical oxygen demand of 17.9 ± 6.0 mg/L, NH4+-N of 0.5 ± 0.3 mg/L, total nitrogen of 2.4 ± 1.0 mg/L and total phosphorus of 0.08 ± 0.05 mg/L. AIR module achieved outstanding NH4+-N IE performance with NaClO-NaCl regeneration, and long-term regeneration increased surface area and mesopore of zeolites. Faster-growing heterotrophic bacteria, such as Pseudomonas and Comamonas, were enriched in BAF. The CEPT-AIR-BAF system saved at least 60% of land occupation and upfront investment, and the treatment cost ($ 0.155/m3) should be further reduced by investigations on the regeneration of loaded zeolite.