Analytical study on heavy metal output fluxes and source apportionment of a non-ferrous smelter in southwest China.

Abandoned Pb/Zn smelters are often accompanied by a large amount of smelting slag, which is a serious environmental problem. Previous studies have demonstrated that slag deposits pose an environmental threat even if the smelters are shut down. Herein, a Pb/Zn smelter and its impacted zone in GeJiu, Yunnan, China were selected as the study area. The risk and source apportionment of heavy metals (HMs) in the soil of the impacted zone were systematically studied. Based on the hydrogeological features, the migration path and output fluxes of the HMs released from smelting slag to the impacted zone were investigated. The HM contents (Cd, As, Zn, Pb, and Cu) in the soil substantially exceeded the screening values of the Chinese soil standard (GB15618-2018). Based on the results of the Pb isotopic and statistical analyses for source apportionment, the contaminated sites and agricultural irrigation water had a large impact on the HMs of soil. The hydrological analysis results showed that runoff, as an HM migration path under rainfall, continued to affect the environment. The water balance calculations using the Hydrologic Evaluation of Landfill Performance model showed that the rainfall was distributed on site as follows: evaporation (57.35%), runoff (32.63%), and infiltration (10.02%). Finally, the output fluxes were calculated in combination with the leaching experiment. As, Zn, Cd, Pb, and Cu runoff had the output fluxes of 6.1 × 10-3, 4.2 × 10-3, 4.1, 1.4 × 10-2, and 7.2 × 10-4 mg/kg/y, and infiltration of 1.9 × 10-3, 1.3 × 10-3, 1.3, 4.0 × 10-4, and 2.2 × 10-4 mg/kg/y, respectively. Therefore, this study offers theoretical and scientific recommendations for effective environmental management and engineering remediation.

The selective and sustainable separation of Cd(II) using C6MImT/[C6MIm]PF6 extractant.

Cadmium has been classified as a kind of human carcinogens, and has a strong mobility in the water environment and this can result in serious harm to human health and environmental safety. Here, a new selective and efficient extraction-recovery strategy for Cd purification is provided by using C6MimT/[C6Mim]PF6 as the green extractant. Due to the high compatibility between C6MimT and [C6Mim]PF6, C6MimT-Cd was efficiently separated from the aqueous phase. When the concentration of Cd(II) was 1000 mg/L, the extraction rate could reached 99.9 %. By comparing [C6MIm]BF4 with [C6MIm]PF6, the hydrophobicity restrained the ion exchange between cation and Cd and significantly reduced the loss of extractant. The extracted Cd(II) was separated in the form of precipitation after stripping. The extraction system of C6MimT/[C6Mim]PF6 was stable after several extraction-stripping cycles. The extraction of Cd(II) by C6MimT/[C6Mim]PF6 system mainly realized by forming a neutral and extractable cadmium complexes between Cd(II) and thione. Based on the natural complexation mechanism between metal and C6MImT, Cd exists as obvious competitive advantage in coordination with C6MimT compare to Pb, Zn, Mg, Cr, Fe. This work overcomes the problems of extractant loss and organic pollution caused by volatile or ion exchange, which can only reduce environmental hazards, but also promote the recovery of cadmium and other valuable resources.

A review on adsorption characteristics and influencing mechanism of heavy metals in farmland soil.

The accumulation of heavy metals in soil and crops is considered to be a severe environmental problem due to its various harmful effects on animals and plants. Soil adsorption is an essential characteristic of mud, which is the fundamental reason for soil to have a specific self-purification capacity and environmental capacity for heavy metals. The adsorption of heavy metals by soil reduces the uptake of these pollutants by crops, thereby limiting food contamination. Therefore, the adsorption of heavy metals in crop soils was taken as the primary research object. Based on the entire reading of the literature, the previous research results were compared and discussed from the four aspects of heterogeneity, physical and chemical properties, competitive adsorption, and external factors. The influencing mechanism of heavy metal adsorption characteristics in soil was reviewed. Finally, suggestions and prospects for future research on heavy metal adsorption were put forward.

Synthesis and influencing factors of high-performance concrete based on copper tailings for efficient solidification of heavy metals.

Copper tailings containing a large amount of heavy metals such as Pb, Cu, As, Mn, and Cr discharged from its mining are a typical bulk solid waste, which is highly hazardous to human and the environment. This research proposed a sustainable and effective method for the environmentally sound utilization of copper tailings solid waste. A high-strength concrete material with copper tailings as the main raw material was successfully prepared, with a 28-day compressive strength of up to 85.35 MPa, the flexural strength reached 12.46 MPa, and the tailings utilization rate of 60%. The mechanical properties and heavy metal stabilization properties of the prepared high-performance concrete were obtained by adding coarse aggregates such as river sand, while changing the sand rate, cementitious material admixture and water-cement ratio. A long-term leaching experiment of the high-strength concrete material with 190 day was carried and proved that the material can be made with low or no risk of heavy metal contamination in copper tailings. Incorporation of copper tailings into the high-performance concrete hydration mainly contains three mechanisms: (i) Pore sealing effect generated by the formation of tailings geopolymer prompted the hardening of the geopolymer layer to form a monolithic package structure; (ii) The active SiO2 material in copper tailings reacts with Ca(OH)2 in the hydration products to produce a strong volcanic ash effect; (iii) the primary hydration of 3CaO·SiO2(C3S) and 3CaO·Al2O3(C3A) in the cement, and the secondary hydration reaction induced by the copper tailings and silica fume. These mechanisms are blended with each other to form a dense microstructure of the slurry, which embodies extremely high mechanical properties on a macroscopic scale, providing a reference role for the bulk utilization of copper tailings.

Efficient purification of hydrogen cyanide by synergistic effects of electrochemical and liquid phase catalysis.

In this study, Co, Cu, Pd, and Pd/Cu composite metal ions were used to synthesize metal nanoparticles with high efficiency in purifying hydrogen cyanide gas. The pure liquid phase catalytic purification of hydrogen cyanide gas was studied. According to the removal rate, the Pd/Cu composite metal ions had the best purification efficiency among the nanoparticles of different metal types. The removal rate order was Pd/Cu>Pd>Cu>Co. The gas after reaction were analyzed by gas chromatography, and it was found that HCN was converted into CO2, N2 and NH3 by nanoparticles. Then, Pd/Cu composite metal ions with the highest purification efficiency were used to study the electrochemical synergistic liquid-phase catalytic purification of HCN gas. The effects of electrochemical conditions and current on the electro-hydraulic synergistic purification were studied. The removal efficiency of HCN by electrochemical synergistic liquid phase catalysis was better than that by pure liquid phase catalysis. The different nanoparticles before and after HCN absorption were characterized and analyzed to explore the purification process of HCN. The purification mechanism of hydrogen cyanide by Pd-Cu catalyst under applied voltage was studied under certain conditions. During the catalytic reaction, the nano-catalyst was partially dissolved in liquid phase and partially HCN reacts with metal ions on the free or nanoparticles to form complex [Mc(CN)n]2-n. Homogeneous and quasi-homogeneous reactions in liquid phase interweave together to form a more complex reaction system.

Treatment of coking wastewater by a novel electric assisted micro-electrolysis filter.

A newly designed electric assisted micro-electrolysis filter (E-ME) was developed to investigate its degradation efficiency for coking wastewater and correlated characteristics. The performance of the E-ME system was compared with separate electrolysis (SE) and micro-electrolysis (ME) systems. The results showed a prominent synergistic effect on COD removal in E-ME systems. Gas chromatography/mass spectrometry (GC-MS) analysis confirmed that the applied electric field enhanced the degradation of phenolic compounds. Meanwhile, more biodegradable oxygen-bearing compounds were detected. SEM images of granular activated carbon (GAC) showed that inactivation and blocking were inhibited during the E-ME process. The effects of applied voltage and initial pH in E-ME systems were also studied. The best voltage value was 1V, but synergistic effects existed even with lower applied voltage. E-ME systems exhibited some pH buffering capacity and attained the best efficiency in neutral media, which means that there is no need to adjust pH prior to or during the treatment process. Therefore, E-ME systems were confirmed as a promising technology for treatment of coking wastewater and other refractory wastewater.