ABSTRACT
Utilizing city-level data from China, the paper employs a spatial econometric analysis to investigate the impact of fiscal decentralization on urban pollution. Empirical evidence indicates: (1) In the context of the emphasis of ecological civilization construction in China, an increase of fiscal autonomy for local governments is conducive to mitigating urban pollution intensity. Specifically, fiscal decentralization in one city not only promotes a reduction in local pollution intensity but alleviates environmental pollution problems in adjacent cities through spatial spillover effects. (2) Industrial structure upgrading and green technology progress become crucial measures for local governments to realize pollution reduction targets through fiscal expenditure. (3) Heterogeneity analysis reveals that the positive significance of decentralization is most prominent in the eastern China, while local governments with fiscal autonomy in central region tend to transfer pollution to neighboring cities. (4) There is a threshold characteristic for fiscal decentralization to promote a reduction in urban pollution intensity, and its marginal effect becomes more significant accompanied by continuous introduction of sophisticated foreign direct investment. Finally, the paper summarizes the potential significance of fiscal decentralization among Chinese local governments against the background of "Chinese-style decentralization" and proposes corresponding policy recommendations.
ABSTRACT
Based on the panel data of 259 cities across China from 2011 to 2019, the study investigates the long-run impact of digital economy on regional pollution intensity by employing multiple models. The estimation results reveal that (1) the relatively heavily polluted areas are concentrated in the north, especially in the northeast of China; the overall pollution intensity is decreasing year by year at the national level; (2) the development of digital economy can significantly contribute to the reduction of regional pollution intensity and it has a statistically significant negative spatial spillover effect on the pollution intensity of neighboring cities; (3) mechanism analysis shows that the development of digital economy not only has a direct effect on the reduction of pollution intensity but also promotes the reduction through the channel of industrial structure upgrading and green technology progress; (4) the results of threshold model suggest that as the level of development of the digital economy increases, its marginal inhibitory effect of promoting the decrease in pollution intensity will diminish; (5) heterogeneity analysis shows that the development of digital economy makes the strongest marginal contribution to pollution intensity reduction in the northeast region. Finally, the conclusions remain valid after controlling for exogenous shocks such as "smart city" policy, various robustness, and endogeneity tests.
Subject(s)
Environmental Pollution , Industry , China , Cities , Policy , Economic DevelopmentABSTRACT
Swarming regulation is complicated in flagellated bacteria, especially those possessing dual flagellar systems. It remains unclear whether and how the movement of the constitutive polar flagellum is regulated during swarming motility of these bacteria. Here, we report the downregulation of polar flagellar motility by the c-di-GMP effector FilZ in the marine sedimentary bacterium Pseudoalteromonas sp. SM9913. Strain SM9913 possesses two flagellar systems, and filZ is located in the lateral flagellar gene cluster. The function of FilZ is negatively controlled by intracellular c-di-GMP. Swarming in strain SM9913 consists of three periods. Deletion and overexpression of filZ revealed that, during the period when strain SM9913 expands quickly, FilZ facilitates swarming. In vitro pull-down and bacterial two-hybrid assays suggested that, in the absence of c-di-GMP, FilZ interacts with the CheW homolog A2230, which may be involved in the chemotactic signal transduction pathway to the polar flagellar motor protein FliMp, to interfere with polar flagellar motility. When bound to c-di-GMP, FilZ loses its ability to interact with A2230. Bioinformatic investigation indicated that filZ-like genes are present in many bacteria with dual flagellar systems. Our findings demonstrate a novel mode of regulation of bacterial swarming motility.
ABSTRACT
The current study aims to explore one factor that likely contributes to these statistical regularities, familiarity. Are highly familiar stimuli perceived more readily? Previous work showing effects of familiarity on perception have used recognition tasks, which arguably tap into post-perceptual processes. Here we use a perceptual task that does not depend on explicit recognition; participants were asked to discriminate whether a rapidly presented image was intact or scrambled. The familiarity level of stimuli was manipulated. Results show that famous or upright orientated logos (Experiments 1 and 2) or faces (Experiment 3) were better discriminated than novel or inverted logos and faces. To further dissociate our task from recognition, we implemented a simple detection task (Experiment 4) and directly compared the intact/scrambled task to a recognition task (Experiment 5) on the same set of faces used in Experiment 3. The fame and orientation familiarity effect were still present in the simple detection task, and the duration needed on the intact/scrambled task was significantly less than the recognition task. We conclude that familiarity effect demonstrated here is not driven by explicit recognition and instead reflects a true perceptual effect.
Subject(s)
Face , Recognition, Psychology , Humans , Orientation, Spatial , Pattern Recognition, VisualABSTRACT
Braun's lipoprotein (Lpp) plays a major role in stabilizing the integrity of the cell envelope in Escherichia coli, as it provides a covalent cross-link between the outer membrane and the peptidoglycan layer. An important challenge in elucidating the physiological role of Lpp lies in attaining a detailed understanding of its distribution on the peptidoglycan layer. Here, using atomic force microscopy, we visualized Lpp directly on peptidoglycan sacculi. Lpp is homogeneously distributed over the outer surface of the sacculus at a high density. However, it is absent at the constriction site during cell division, revealing its role in the cell division process with Pal, another cell envelope-associated protein. Collectively, we have established a framework to elucidate the distribution of Lpp and other peptidoglycan-bound proteins via a direct imaging modality.
Subject(s)
Escherichia coli , Lipoproteins , Microscopy, Atomic Force , Molecular Imaging , Bacterial Outer Membrane Proteins/metabolism , Cell Membrane/metabolism , Escherichia coli/chemistry , Lipoproteins/chemistry , Peptidoglycan/chemistry , Molecular Imaging/methodsABSTRACT
Industry dominates energy consumption and carbon emissions in China, and industrial energy efficiency is critical for the achievement of energy transformation and carbon emission reduction. With the rapid development of the digital economy, its impact on energy efficiency is gradually emerging, and it is necessary to clarify the influencing mechanism on industrial energy efficiency. Based on the panel data of industrial sectors in 41 cities in the Yangtze River Delta from 2011 to 2019, the main objectives of this study are to more accurately measure the industrial total factor energy efficiency in each city by using the Super-Dynamic-SBM model. It analyses the influence mechanism of the digital economy and other influencing factors on industrial total factor energy efficiency with different methods. The research results indicate that, first, the total factor energy efficiency of the industrial sector in the Yangtze River Delta urban agglomeration generally showed a steady upward trend. Second, the digital economy and environmental regulation play a significant role in promoting total factor energy efficiency. In addition, industrial energy efficiency and the digital economy show an inverted "U" shaped relationship. With the improvement of the digital economy, its marginal contribution to total factor energy efficiency gradually weakens. Finally, technological progress is an important transmission channel for the impact of the digital economy on total factor energy efficiency.
Subject(s)
Conservation of Energy Resources , Rivers , Cities , China , Economic Development , Efficiency , Carbon/analysisABSTRACT
Previous work has claimed that canonical viewpoints of objects are more readily perceived than noncanonical viewpoints. However, all of these studies required participants to identify the object, a late perceptual process at best and arguably a cognitive process (Pylyshyn, 1999). Here, we extend this work to early vision by removing the explicit need to identify the objects. In particular, we asked participants to make an intact/scrambled discrimination of briefly presented objects that were viewed from either typical or atypical viewpoints. Notably, participants did not have to identify the object; only discriminate it from noise (scrambled). Participants were more sensitive in discriminating objects presented in typically encountered orientations than when objects were presented in atypical depth rotations (Experiment 1). However, the same effect for objects presented in atypical picture plane rotations (as opposed to typical ones) did not reach statistical significance (Experiments 2 and 3), suggesting that particular informative views may play a critical role in this effect. We interpret this enhanced perceptibility, for both these items and good exemplars and probable scenes, as deriving from their high real-world statistical regularity.
Subject(s)
Orientation , HumansABSTRACT
BACKGROUND: Di-nitrogen oxide (N2O) emissions from soil may lead to nonpoint-source pollution in farmland. Improving the C and N content in the soil is an excellent strategy to reduce N2O emission and mitigate soil N loss. However, this method lacks a unified mathematical index or standard to evaluate its effect. METHODS: To quantify the impact of soil improvement (C and N) on N2O emissions, we conducted a 2-year field experiment using biochar as carbon source and fertilizer as nitrogen source, setting three treatments (fertilization (300 kg N ha-1), fertilization + biochar (30 t ha-1), control). RESULTS: Results indicate that after biochar application, the average soil water content above 20 cm increased by â¼26% and 26.92% in 2019, and â¼10% and 12.49% in 2020. The average soil temperature above 20 cm also increased by â¼2% and 3.41% in 2019. Fertigation significantly promotes the soil N2O emissions, and biochar application indeed inhibited the cumulation by approximately 52.4% in 2019 and 33.9% in 2020, respectively. N2O emissions strongly depend on the deep soil moisture and temperature (20-80 cm), in addition to the surface soil moisture and temperature (0-20 cm). Therefore, we established an exponential model between the soil moisture and N2O emissions based on theoretical analysis. We find that the N2O emissions exponentially increase with increasing soil moisture regardless of fertilization or biochar application. Furthermore, the coefficient a < 0 means that N2O emissions initially increase and then decrease. The aRU < aCK indicates that fertilization does promote the rate of N2O emissions, and the aBRU > aRU indicates that biochar application mitigates this rate induced by fertilization. This conclusion can be verified by the sensitivity coefficient (SCB of 1.02 and 14.74; SCU of 19.18 and 20.83). Thus, we believe the model can quantify the impact of soil C and N changes on N2O emissions. We can conclude that biochar does significantly reduce N2O emissions from farmland.
ABSTRACT
The utility of neutrophil-to-lymphocyte ratio (NLR) and platelet-to-lymphocyte ratio (PLR) utility in predicting immune-related adverse events (irAEs) and survival have not been well studied in the context of treatment with immune checkpoint inhibitors (ICIs). We performed a case-control study of cancer patients who received at least one dose of ICI in a tertiary hospital. We examined NLR and PLR in irAE cases and controls. Logistic and Cox regression models were used to identify independent risk factors for irAEs, progression-free survival (PFS), and overall survival (OS). The study included 91 patients with irAEs and 56 controls. Multiple logistic regression showed that NLR < 3 at baseline was associated with higher occurrence of irAEs. Multivariate Cox regression showed that development of irAEs and reduction in NLR from baseline to week 6 were associated with longer PFS. Higher NLR values at baseline and/or week 6 were independently associated with shorter OS. A reduction in NLR from baseline to week 6 was associated with longer OS. In this study of cancer patients treated with ICIs, NLR has a bidirectional relationship with adverse outcomes. Lower NLR was associated with increased occurrence of irAEs while higher NLR values were associated with worse clinical outcomes.
ABSTRACT
Drip irrigation and brackish water irrigation are considered to be the two main ways to alleviate the current shortage of agricultural freshwater resources and have been widely used in countries around the world. Our purpose is to evaluate the effects of different irrigation methods (flood irrigation and drip irrigation) and irrigation water salinities (1.1 g·L-1, 2.0 g·L-1, 3.5 g·L-1, and 5.0 g·L-1) on the soil CO2 emissions during the growth and fallow periods of spring maize. Therefore, a two-year field experiment was conducted in Hetao Irrigation District in China from 2017 to 2019. The results showed that compared with flood irrigation, drip irrigation significantly decreased the soil CO2 emissions in the growth period. After irrigation with a salinity of 5.0 g·L-1, the soil moisture was the highest because the plant water absorption was inhabited by soil salt, and the soil CO2 emissions were also promoted during the growth period. Irrigation method and irrigation water salinity had no effect on the soil CO2 emissions in the fallow period. Soil temperature, moisture and inorganic nitrogen content were the main factors affecting the daily CO2 emission flux. The soil CO2 emissions during the growth period accounted for more than 83.93% of the annual soil emissions. Based on the goal of saving freshwater resources, ensuring soil safety, reducing soil CO2 emissions and increasing the size of the carbon pool, adoption of drip irrigation with 2.0 g·L-1 brackish water could be adopted to ensure the sustainable development of local agriculture.
ABSTRACT
Human activities have strongly influenced nitrogen loads; thus, the accurate evaluation of net anthropogenic nitrogen input (NANI) is very important for developing countermeasures to control N pollution. The spatiotemporal distribution and main components of NANI at the city scale in Hubei Province in 2008-2018 were analyzed using the NANI model. Furthermore, the relationships between NANI and socioeconomic factors, namely, the gross industrial output value per unit area (GIOV), gross agricultural output value per unit area (GAOV), grain yield per unit area (GY), fertilizer consumption density (FCD), population density (PD), and cultivated land area per unit area (CLA), were further analyzed. The results show that NANI in Hubei tended to increase from 14,422.66 kg km-2 year-1 in 2008 to 16,779.39 kg km-2 year-1 in 2012 and then fell to 13,415.74 kg km-2 year-1 in 2018. In terms of the spatial distribution, the NANI values in the mid-east region of Hubei, i.e., Xiangyang, Jingmen, Jingzhou, Suizhou, Xiaogan, Wuhan, Ezhou, and Huanggang and counties directly under the jurisdiction of the province, were significantly higher than those in the west, i.e., Shiyan, Yichang, and Enshi autonomous prefecture. The largest 11-year annual NANI, 39,462.03 kg km-2 year-1, occurred in Ezhou, while Shiyan had the lowest 11-year annual NANI of 6592.32 kg km-2 year-1. N fertilizer use (Nfer), which accounted for 55.23% of the NANI was the largest N input source, followed by net N import in food and feed (Nim), atmospheric N deposition (Ndep), N fixation (Nfix), and seeding N (Nsee). Pearson correlation analysis between the components of NANI and 6 socioeconomic factors revealed FCD as the primary factor responsible for NANI (r = 0.948), followed by GAOV (r = 0.607) and CLA (r = 0.558). The most direct driving factors of Ndep, Nfer, Nsee, and Nim were GIOV (r = 0.727), FCD (r = 0.966), CLA (r = 0.813), and GAOV (r = 0.746), respectively. All factors had a significant negative impact on Nfix. Therefore, the most efficient strategy to decrease NANI is to control the fertilizer application amount and improve agricultural development. Additionally, it is necessary to replace traditional high-polluting industries with ecological industry to reduce industrial pollution. Graphical abstract.
Subject(s)
Environmental Monitoring , Nitrogen , China , Cities , Fertilizers/analysis , Humans , Nitrogen/analysis , Socioeconomic FactorsABSTRACT
Water and inorganic nitrogen fertilizer have a notable impact on crop yield and greenhouse gas (GHG) emissions from soil. Reclaimed water (RW) is widely used for irrigation when there are shortages of water resources. It is very important to control yield and greenhouse gas emissions by fertilization under reclaimed water irrigation (RWI). The study consisted of a continuous test that evaluated three types of fertilizer treatments (urea, amine, and slow-release fertilizer) and a no-fertilizer treatment under three-year RWI and four fertilizer levels (150, 200, 250 and 300 kg.N.ha-1) under one-year RWI to determine the best fertilizer to support maize production and reduce GHG (CO2 and N2O) emissions from soil; further, the applicability of RWI in the DNDC model was verified. For many years, GHG emissions under RWI showed an increasing trend, but the effect was not significant. A strong correlation was found between the GHG emissions flux and fertilizer amount, and a threshold fertilization amount existed between 220 and 260 kg.N.ha-1 that minimized yield-scaled N2O emissions and the ratio of GHG cumulative emission to yield (GHG/Y). The results indicated that the optimal amounts of SF and UF under RWI were 240 and 225 kg.N.ha-1 by second-order equation and the DNDC model, respectively, and the rate better balanced the yield and GHG emissions.
ABSTRACT
The use of fertilizers as addition inputs in agricultural systems can increase the yield of wheat and maize, while also stimulating the emission of carbon dioxide from soil that the main man-made greenhouse gas. Our objectives focused on the impact of different types of synthetic fertilizers and water quality. The purposes were to determine the feasibility of using wasted water for irrigation and to relate CO2 fluxes to the yield of maize and wheat, as well as to select the best fertilizer type with low CO2 emission and high yield. The experiment consisted of a double factors test focusing on four forms of fertilizer (urea, amine and slow release fertilizer) and the quality of water (reclaimed water and underground water). The results showed that the reclaimed water was not significant on the CO2 discharge rate, the maize-wheat yield or the soil properties in 2014 or 2015; however, the CO2 emission increased slightly in 2015. Focusing on fertilizer treatments, the reclaimed water & amine fertilizer treatment (CAF) that had higher cumulative CO2 emissions was 32.75â¯t·ha-1 in 2014 and 33.86â¯t·ha-1 in 2015. According to the ratio CO2/Y, the slow released fertilizer that reduces CO2 emissions and keeps the yield high is the preferred choice.
Subject(s)
Air Pollutants/analysis , Carbon Dioxide/analysis , Fertilizers , Triticum , Water Quality , Zea mays , Agriculture , ChinaABSTRACT
The application of flue gas desulfurization (FGD) gypsum has been recognized as a feasible measure in enhancing the quality of sodic soils. Quantitative evaluation of the effects of FGD gypsum on three-dimension (3D) pore characteristics is beneficial for understanding the reclamation mechanism of FGD gypsum on sodic soils. We collected intact soil cores from a sodic field at four depths (0-10, 10-20, 20-40, and 40-60â¯cm) in northern China to reconstruct 3D pore structures using X-ray computed tomography (CT), thus quantifying the effects of FGD gypsum (10.1 and 14.5â¯tâ¯hm-2) and leaching water (1520 and 2200â¯tâ¯hm-2) on the 3D pore characteristics and related soil physical properties. The treatments using FGD gypsum with leaching water promoted the formation of new pores and significantly (pâ¯<â¯0.05) increased the 3D image-based macroporosity, mesoporosity, total pore length, and number of nodes at depths of 0-20â¯cm, improving the permeability of sodic soils investigated, which is validated by the enhanced saturated hydraulic conductivity (Ksat). Irrigation water of 1520â¯tâ¯hm-2 is demonstrated effective in assisting FGD gypsum dissolution and leaching, but excessive leaching water (2200â¯tâ¯hm-2) may reduce the permeability of 20-40â¯cm depth. The combined application of 14.5â¯tâ¯hm-2 FGD gypsum and 1520â¯tâ¯hm-2 leaching water is suggested to obtain the optimal result for the investigated sodic soils. This study offers an applicable strategy for sodic soils reclamation and provides a reference for revealing the improvement mechanism of sodic soils by FGD gypsum and leaching water.
Subject(s)
Calcium Sulfate , Soil , China , Conservation of Natural Resources , WaterABSTRACT
Alternative irrigation between saline water and groundwater can alleviate shortages of available agricultural water while effectively slowing the adverse effects of saline water on the soil-crop system when compared with continuous irrigation with saline water and blending irrigation between saline water and groundwater. In 2018, we tested the effect on soil CO2 and N2O emissions by two types of irrigation regimes (alternating groundwater and saline water (GW-SW), and alternating groundwater, followed by two cycles of saline water (GW-SW-SW)) between groundwater and three levels of salinity of irrigation water (mineralization of 2 g/L, 3.5 g/L, and 5 g/L), analyzed the correlation between gas emissions and soil properties, calculated comprehensive global warming potential (GWP), and investigated the maize yield. The results show that, with the same alternate irrigation regime, cumulative CO2 emissions decreased with increasing irrigation water salinity, and cumulative N2O emissions increased. Cumulative CO2 emissions were higher in the GW-SW regime for the same irrigation water salinity, and cumulative N2O emissions were higher in the GW-SW-SW regime. The GW-SW-SW regime had less comprehensive GWP and maize yield as compared to the GW-SW regime. The 2 g/L salinity in both regimes showed larger comprehensive GWP and maize yield. The 3.5 g/L salinity under the GW-SW regime will be the best choice while considering that the smaller comprehensive GWP and the larger maize yield are appropriate for agricultural implication. Fertilizer type and irrigation amount can be taken into consideration in future research direction.
Subject(s)
Agricultural Irrigation , Carbon Dioxide/analysis , Groundwater/analysis , Nitrous Oxide/analysis , Saline Waters/analysis , Soil/chemistry , China , Greenhouse Gases/analysis , Greenhouse Gases/chemistry , Groundwater/chemistry , Saline Waters/chemistry , Zea mays/growth & developmentABSTRACT
BACKGROUND: With global aging, robots are considered a promising solution for handling the shortage of aged care and companionships. However, these technologies would serve little purpose if their intended users do not accept them. While the socioemotional selectivity theory predicts that older adults would accept robots that offer emotionally meaningful relationships, selective optimization with compensation model predicts that older adults would accept robots that compensate for their functional losses. OBJECTIVE: The present study aims to understand older adults' expectations for robots and to compare older adults' acceptance ratings for 2 existing robots: one of them is a more human-like and more service-oriented robot and the other one is a more animal-like and more companion-oriented robot. METHODS: A mixed methods study was conducted with 33 healthy, community-dwelling Taiwanese older adults (age range: 59-82 years). Participants first completed a semi-structured interview regarding their ideal robot. After receiving information about the 2 existing robots, they then completed the Unified Theory of Acceptance and Use of Technology questionnaires to report their pre-implementation acceptance of the 2 robots. RESULTS: Interviews were transcribed for conventional content analysis with satisfactory inter-rater reliability. From the interview data, a collection of older adults' ideal robot characteristics emerged with highlights of humanlike qualities. From the questionnaire data, respondents showed a higher level of acceptance toward the more service-oriented robot than the more companion-oriented robot in terms of attitude, perceived adaptiveness, and perceived usefulness. From the mixed methods analyses, the finding that older adults had a higher level of positive attitude towards the more service-oriented robot than the more companion-oriented robot was predicted by higher expectation or preference for robots with more service-related functions. CONCLUSION: This study identified older adults' preference toward more functional and humanlike robots. Our findings provide practical suggestions for future robot designs that target the older population.
Subject(s)
Activities of Daily Living , Attitude , Robotics , Social Support , Aged , Aged, 80 and over , Female , Humans , Independent Living , Male , Middle Aged , Psychological Theory , Qualitative Research , Taiwan , TechnologyABSTRACT
Intrinsically photosensitive retinal ganglion cells (ipRGCs) contain photoreceptors that are especially sensitive to blue light. Nevertheless, how blue light and ipRGCs affect time perception remains unsolved. We used the oddball paradigm and manipulated the background light to examine whether and how blue light and ipRGCs affect perceived duration. In the oddball paradigm, participants were asked to judge the duration of the target (oddball), compared to that of the standard, with a two alternative-forced-choice procedure. When the background light was controlled to be either blue or red in Experiment 1, results showed that blue light led to longer subjective duration compared to red light. Experiment 2 further clarified the contribution of the ipRGCs. A set of multi-primary projector system that could manipulate the ipRGC stimulation were used, while the color and luminance of the background lights were kept constant throughout. Results showed that increased stimulation of ipRGCs under metameric background expanded subjective time. These results suggest that ipRGC stimulation increases arousal/attention so as to expand subjective duration.
Subject(s)
Light , Photic Stimulation , Retinal Ganglion Cells/radiation effects , Humans , Male , Retinal Ganglion Cells/cytology , Time Factors , Young AdultABSTRACT
The nutrient loss caused by soil erosion is the main reason for soil degradation and environmental pollution, and polyacrylamide (PAM) as a common soil amendment has a great influence on runoff and erosion processes at the slope. In order to investigate the mechanism of nutrient transport with runoff, a field experiment was conducted and a simple mathematical model was developed in this study. Four PAM application rates (0, 1, 2, and 4 g·m-2) and two rainfall intensities (50 and 80 mm·h-1) were applied in the field experiment. The results revealed that runoff rate of 2 g·m-2 PAM application treatments decreased by 5.3%-10.6% compared with the control groups, but it increased by10.9%-18.7% at 4 g·m-2 PAM application treatments. Polyacrylamide application reduced ammonium nitrogen concentrations of runoff by 10.0% to 44.3% relative to the control groups. The best performance with correlation coefficient (R2) and Nash-Sutcliffe efficiency (NSE) showed that the ammonium transport with runoff could be well described by the proposed model. Furthermore, the model parameter of the depth of the mixing layer (hm) linearly increased with an increase in flow velocity, but exponentially decreased with an increase in PAM application rate.
ABSTRACT
Wastewater reclamation now represents an effective measure for sustainable water resource management in arid regions, however wastewater components (organic micropollutants) may potentially impact local ecological and/or human health. Previous studies have shown that sodium bentonite/natural clay (BC) mixes may be used to effectively reduce riverbed infiltration in regions characterized by excessively high hydraulic conductivity. Accordingly, the current study sought to investigate the contaminant removal efficiency (Re) of several BC mass ratios in simulated dry riverbeds. Results indicate that the measured Re of NH4+-N, CODcr and BOD5 increased in concurrence with an increasing sodium bentonite ratio, up to a maximum Re of 97.4% (NH4+-N), 55.2% (CODcr), and 51.5% (BOD5). The primary contaminant removal site was shown to be the infiltration-reducing (BC) layer, accounting for approximately 40%, 60%, and 70% of NH4+-N, CODcr and BOD5 removal, respectively. Conversely, the removal efficiency of NO3-N was found to be low (<15%), while total phosphorous (TP) was found to actively leach from the infiltration-reduction layer, resulting in measured TP discharges 2.4-4.8 times those of initial infiltration values. The current study provides a technical baseline for the efficacy of sodium bentonite as an effective bi-functional material in areas utilizing reclaimed water i.e. concurrent reduction of infiltration rates (Function 1) and decontamination of reclaimed wastewater infiltration/recharge (Function 2). Findings indicate that sodium bentonite-clay mixes may represent a feasible alternative for managing recharge of non-potable aquifers with reclaimed wastewater.
Subject(s)
Bentonite/chemistry , Clay/chemistry , Groundwater/chemistry , Wastewater/chemistry , Water Pollutants, Chemical/analysis , Water Purification/methods , Filtration , Geologic Sediments/chemistry , Humans , Models, Theoretical , Permeability , Rivers/chemistryABSTRACT
To monitor and manage hydrological pollution effectively, tracing sources of pollutants is of great importance and also is in urgent need. A variety of tracers have been developed such as isotopes, silica, bromide, and dyes; however, practical limitations of these traditional tracers still exist such as lack of multiplexed, multipoint tracing and interference of background noise. To overcome these limitations, a new tracing system based on DNA nanomaterials, namely DNA tracer, has already been developed. DNA tracers possess remarkable advantages including sufficient species, specificity, environmental friendly, stable migration, and high sensitivity as well as allowing for multipoints tracing. In this review article, we introduce the molecular design, synthesis, protection and signal readout strategies of DNA tracers, compare the advantages and disadvantages of DNA tracer with traditional tracers, and summarize the-state-of-art applications in hydrological environment investigations. In the end, we provide our perspective on the future development of DNA tracers.