Unraveling the mechanism of interaction: accelerated phenanthrene degradation and rhizosphere biofilm/iron plaque formation influenced by phenolic root exudates.

Phenolic root exudates (PREs) secreted by wetland plants facilitate the accumulation of iron in the rhizosphere, potentially providing the essential active iron required for the generation of enzymes that degrade polycyclic aromatic hydrocarbon, thereby enhancing their biodegradation. However, the underlying mechanisms involved are yet to be elucidated. This study focuses on phenanthrene (PHE), a typical polycyclic aromatic hydrocarbon pollutant, utilizing representative PREs from wetland plants, including p-hydroxybenzoic, p-coumaric, caffeic, and ferulic acids. Using hydroponic experiments, 16S rRNA sequencing, and multiple characterization techniques, we aimed to elucidate the interaction mechanism between the accelerated degradation of PHE and the formation of rhizosphere biofilm/iron plaque influenced by PREs. Although all four types of PREs altered the biofilm composition and promoted the formation of iron plaque on the root surface, only caffeic acid, possessing a similar structure to the intermediate metabolite of PHE (catechol), could accelerate the PHE degradation rate. Caffeic acid, notable for its catechol structure, plays a significant role in enhancing PHE degradation through two main mechanisms: (a) it directly boosts PHE co-metabolism by fostering the growth of PHE-degrading bacteria, specifically Burkholderiaceae, and by facilitating the production of the key metabolic enzyme catechol 1,2-dioxygenase (C12O) and (b) it indirectly supports PHE biodegradation by promoting iron plaque formation on root surfaces, thereby enriching free iron for efficient microbial synthesis of C12O, a crucial factor in PHE decomposition.

Selective removal of oxytetracycline by molecularly imprinted magnetic biochar.

Molecularly imprinted magnetic biochar (MBC@MIPs) was synthesized through molecular imprinting precipitation polymerization. This material demonstrated a selective adsorption capacity of oxytetracycline (OTC) from water samples. Upon characterization of MBC@MIPs, results revealed the formation of a memory cavity shell layer on the magnetic biochar's surface, exhibiting a distinctive recognition effect alongside commendable magnetic and thermal stability. Analysis of the adsorption kinetics indicated that the OTC adsorption process aligned well with the pseudo-second-order rate equation, with chemisorption acting as the predominant mechanism for antibiotic adsorption onto MBC@MIPs. The data could be well described by the Langmuir isotherm model. At 299 K, MBC@MIPs showed a maximum binding capacity of 67.89 mg·g-1, surpassing that of MBC (38.84 mg·g-1) by 1.77 times. MBC@MIPs exhibited the highest selectivity towards OTC, with an imprinting factor (IF) of 5.64. Even amidst interference from antibiotics, MBC@MIPs maintained a significant adsorption capacity for OTC (6.10 mg·g-1), with IF of 6.70.

Mechanisms of low cadmium accumulation in crops: A comprehensive overview from rhizosphere soil to edible parts.

Cadmium (Cd) is a toxic heavy metal often found in soil and agricultural products. Due to its high mobility, Cd poses a significant health risk when absorbed by crops, a crucial component of the human diet. This absorption primarily occurs through roots and leaves, leading to Cd accumulation in edible parts of the plant. Our research aimed to understand the mechanisms behind the reduced Cd accumulation in certain crop cultivars through an extensive review of the literature. Crops employ various strategies to limit Cd influx from the soil, including rhizosphere microbial fixation and altering root cell metabolism. Additional mechanisms include membrane efflux, specific transport, chelation, and detoxification, facilitated by metalloproteins such as the natural resistance-associated macrophage protein (Nramp) family, heavy metal P-type ATPases (HMA), zinc-iron permease (ZIP), and ATP-binding cassette (ABC) transporters. This paper synthesizes differences in Cd accumulation among plant varieties, presents methods for identifying cultivars with low Cd accumulation, and explores the unique molecular biology of Cd accumulation. Overall, this review provides a comprehensive resource for managing agricultural lands with lower contamination levels and supports the development of crops engineered to accumulate minimal amounts of Cd.

Nitrogen-rich magnetic biochar prepared by urea was used as an efficient catalyst to activate persulfate to degrade organic pollutants.

In order to fully exploit the potential of magnetic biochar-based persulfate (PS) systems, N was utilized to modify the magnetic biochar-based catalysts through impregnation-pyrolysis method. A typical antifungal drug, metronidazole (MNZ), is selected as the target pollutant to score the reactivity of as-synthetic nitrogen-rich magnetic biochar (NMBC) catalysts. In the modified system, 99.6% of MNZ was removed, 13.6 times of that in the unmodified system. Active radical verification experiments showed that 1O2 was the key active radical. Various characterization showed that the nitrogen-rich significantly improved the persistent free radical, defect degree, content of oxygen-containing groups, electrochemical conductivity and other catalytic activity related properties. Physicochemical characterization, Fe(II) semi-quantitative analysis and masking experiments confirmed that the doping of magnetic biochar with nitrogen increased its Fe(II) content (23.79 mg/g), approximately 2.6 times higher than that of pristine magnetic biochar. Moreover, N induces strong electron accretion of Fe atom through coordination bond, which leads to the increase of electron density on the Fe atom, which increases the content of Fe (II) in the material, thus improving the ability of the material to activate PS to generate 1O2, and promoting the degradation reaction of MNZ. This paper provides a method to improve the activation performance of magnetic biochar.

Simultaneous remediation of co-contaminated soil by ball-milled zero-valent iron coupled with persulfate oxidation.

The problem of co-contaminated soil at e-waste dismantling sites is serious and constitutes a critical threat to human health and the ecological environment. Zero-valent iron (ZVI) has been proven to be effective in the stabilization of heavy metals and the removal of halogenated organic compounds (HOCs) from soils. However, for the remediation of co-contamination of heavy metals with HOCs, ZVI has disadvantages such as high remediation cost and inability to take into account both pollutants, which limits its large-scale application. In this paper, boric acid and commercial zero-valent iron (cZVI) were used as raw materials to prepare boric acid-modified zero-valent iron (B-ZVIbm) through a high-energy ball milling strategy. B-ZVIbm coupled with persulfate (PS) to achieve simultaneous remediation of co-contaminated soil. The synergistic treatment of PS and B-ZVIbm resulted in the removal efficiency of 81.3% for decabromodiphenyl ether (BDE209) and the stabilization efficiencies of 96.5%, 99.8%, and 28.8% for Cu, Pb, and Cd respectively in the co-contaminated soil. A series of physical and chemical characterization methods showed that the oxide coat on the surface of B-ZVIbm could be replaced by borides during ball milling. The boride coat facilitated the exposure of the Fe0 core, promoted the corrosion of ZVI and the orderly release of Fe2+. The analysis of the morphological transformation of heavy metals in soils revealed that most of the heavy metals in the exchangeable, carbonate-bound state were transformed into the residue state, which was the key mechanism for the remediation of heavy metal-contaminated soils with B-ZVIbm. The analysis of BDE209 degradation products showed that BDE209 was degraded to lower brominated products and further mineralized by ZVI reduction and free radical oxidation. In general, B-ZVIbm coupled with PS is a good recipe for synergistic remediation of co-contaminated soils with heavy metals and HOCs.

Effect of Mn-based magnetic biochar /PS reaction system on oxidation of metronidazole.

In order to fully exploit the potential of magnetic biochar-based persulfate (PS) systems, Mn was utilized to modify the magnetic biochar-based catalysts through impregnation-pyrolysis method. Taking metronidazole (MNZ), a typical antifungal drug, as the target contaminant, the reactivity of the synthesized magnetic biochar (MMBC) catalyst was evaluated. The degradation efficiency of MNZ in MMBC/persulfate system was 95.6%, which was 13.0 times higher than that in MBC/PS system. The characterization experiments confirmed the degradation of metronidazole by surface binding free radicals, the ·OH and 1O2 played the key role in remove of MNZ in the system of MMBC/PS. Physicochemical characterization, Fe(II) semi-quantitative analysis and masking experiments confirmed that the doping of MBC with Mn increased its Fe(II) content (43.0 mg/g), approximately 7.8 times higher than that of pristine MBC. The increase of Fe(II) content in MBC is the key reason to improve the optimization of MBC modified with Mn. Simultaneously, both Fe(II) and Mn(II) were the key components of PS activation by magnetic biochar. This paper presents a method to optimize the high efficiency of PS activation by magnetic biochar.

Sophorolipid modification enables high reactivity and electron selectivity of nanoscale zerovalent iron toward hexavalent chromium.

Nanoscale zero-valent iron is considered to be a promising nanostructure for environmental remediation, while increasing the electron selectivity of nanoscale zerovalent iron (nZVI) during target contaminant removal is still a challenge (electron selectivity, defined as the percentage of electrons transferred to the target contaminants over the number of electrons donated by nZVI). In this study, the strategy for increasing the reactivity and electron selectivity of nZVI via sophorolipid (SL-nZVI) modification was proposed. The results showed that the removal efficiency and electron selectivity of SL-nZVI toward Cr(VI) was 99.99% and 56.30%, which was higher than that of nZVI (61.16%, 25.91%). Meanwhile, the particles were well characterized and the mechanism for enhanced reactivity and electron selectivity was investigated. Specially, both the morphology and BET specific surface area characterization suggested that stability against aggregation was higher in SL-nZVI nanoparticles than in nZVI. Besides, X-ray photoelectron spectroscopy (XPS), Tafel polarization curves, and Electrochemical impedance spectroscopy also indicated that the introduction of sophorolipid successfully prevent the nanoparticles from oxidation and benefit the electron transferring. In addition, a water contact angle test revealed that SL-nZVI nanoparticles were less hydrophilic (contact angle = 34.8°) than nZVI (contact angle = 23.9°). Therefore, in terms of reactivity, sophorolipid modification inhibited the aggregation of the nanoparticles and enhanced the electrical conductivity. For electron selectivity, the introduction of sophorolipid not only benefited Cr(VI) adsorption and the electron transfer from Fe0 to the surface-adsorbed Cr(VI) that followed but also reduced the possibility of side reactions between Fe0 and H2O. This study demonstrates that the introduction of sophorolipid is an effective strategy for developing a highly efficient nZVI-based nanocomposite system and highlights the potential role of sophorolipid in improving the electron selectivity of nZVI.

Remediation of cadmium or arsenic contaminated water and soil by modified biochar: A review.

Biochar has a high specific surface area with abundant pore structure and functional groups, which has been widely used in remediation of cadmium or arsenic contaminated water and soil. However, the bottleneck problem of low-efficiency of pristine biochar in remediation of contaminated environments always occurs. Nowadays, the modification of biochar is a feasible way to enhance the performance of biochar. Based on the Web of science™, the research progress of modified biochar and its application in remediation of cadmium or arsenic contaminated water and soil have been systematically summarized in this paper. The main modification strategies of biochar were summarized, and the variation of physicochemical properties of biochar before and after modification were illustrated. The efficiency and key mechanisms of modified biochar for remediation of cadmium or arsenic contaminated water and soil were expounded in detail. Finally, some constructive suggestions were given for the future direction and challenges of modified biochar research.

Impacts of anions on activated persulfate oxidation of Fe(II) - Rich potassium doped magnetic biochar.

The potassium-doped magnetic biochar (KMBC) preparation was inevitably introduced the different anions in the process of modifying magnetic biochar (MBC) with different potassium salts, but the effect and mechanism of different anion on KMBC activation properties has not been reported. Therefore, in this paper, five different KMBCs were prepared using several common potassium salts under the same dosage of K+ and Fe2+, and then was added in the presence of persulfate (PS) for the removal of metronidazole (MNZ). The removal rate of metronidazole was ordered as KMBCK2SO4 (98.40%) > KMBCKNO3 (76.84%) > KMBCKCl (20.79%) > KMBCK2CO3 (19.02%) > KMBCK2C2O4 (14.23%). However, the semi-quantitative of Fe(II) experiments results confirmed that the effectively increase of Fe(II) content by potassium salts modification played the dominant role in improvement of KMBC activation performance. The Fe(II) content of KMBC were ordered as KMBCK2CO3 > KMBCK2SO4 > KMBCKNO3 > KMBCKCl > KMBCK2C2O4, with the Fe(II) content of KMBC of 36.74, 17.70, 8.79, 5.24 and 4.85 mg/g, respectively. The indicated that the introduction of different anions would lead to different optimal Fe(Ⅱ) content in KMBC modified with different potassium salts, which was most directly reflected in 1O2 content in different KMBC/PS systems, and account for the difference in MNZ degradation efficiency. Meanwhile, when the Fe(II) content in KMBC reached the range of 13.7-28.8 mg/g, KMBC had the better performance of activating PS.

Nanoscale zero-valent iron immobilized by ZIF-8 metal-organic frameworks for enhanced removal of hexavalent chromium.

nZVI is considered to be a promising material for environmental remediation. However, the drawbacks of easy agglomeration and low activity severely limit its application. In this work, nZVI/ZIF-8 was obtained by in-situ reduction of nZVI in the presence of performed ZIF-8. The reactivity of the as-obtained nZVI/ZIF-8 nanocomposites was investigated by removing hexavalent chromium (Cr(VI)) from wastewater. The as-obtained nZVI/ZIF-8 nanocomposites showed a superior activity for Cr(VI) removal, with an optimum activity (91.27%) achieved over 0.25 nZVI/ZIF-8 (i e., the mass ratio of ZIF-8 to nZVI was 0.25), higher than that of nZVI (64.55%), and this could be owned to the excellent dispersion of nZVI in nZVI/ZIF-8 and the high specific surface area as compared with the bare nZVI. The results of XPS characterization, quenching experiment analysis and kinetics fitting indicated that the Cr(VI) elimination was a surface-dominated chemical reduction process. Besides, more than 99.00% Cd(II), Cu(II), Cr(VI) and Pb(II) was removed from wastewater over nZVI/ZIF-8 nanocomposites, and negligible zinc ion was detected in the aqueous solutions. The results of our finding demonstrate that the introduction of MOFs is an effective strategy in developing a highly efficient nZVI-based nanocomposites system, and also highlight the promising role of using nZVI/MOFs in heavy metal treatment for practical wastewater.

Removal of fluconazole from aqueous solution by magnetic biochar treated by ball milling: adsorption performance and mechanism.

The problem of low adsorption capacity of pristine magnetic biochar for organic pollutants always occurs. It is of great significance to select a suitable method to improve the adsorption performance of magnetic biochar. In this study, magnetic biochar was treated by ball milling and tested for its fluconazole adsorption capacity. The maximum adsorption capacity of ball-milled magnetic biochar (BMBC) for fluconazole reached nearly 15.90 mg/g, which was approximately five times higher than that of pristine magnetic biochar (MBC). Fluconazole adsorption by BMBC was mainly attributed to π-π interactions, hydrogen bonding, and surface complexation with oxygen-containing functional groups. The enhancement in fluconazole adsorption by BMBC was attributed to an increase in oxygen-containing functional groups. Batch adsorption experiments also illustrated that BMBC could be successfully applied in a wide range of pH values. The high efficiency of fluconazole removal confirmed that ball milling was an effective strategy to enhance the adsorptive performance of magnetic biochar.

Activation of persulfate for highly efficient degradation of metronidazole using Fe(II)-rich potassium doped magnetic biochar.

The content of active components in magnetic biochar, especially Fe(II), is closely related to its activation performance. Therefore, improving Fe(II) content in magnetic biochar is an ideal strategy to enhance the activation performance of magnetic biochar. In this study, the potassium-doped magnetic biochar was prepared and employed to activate persulfate for degradation of metronidazole. The degradation efficiency of metronidazole in potassium-doped magnetic biochar/persulfate system was 98.4%, which was 13.1 times higher than that in magnetic biochar/persulfate system. Free radicals quenching experiments and electron spin resonance analyses confirmed that surface-bound free radicals were responsible for metronidazole degradation followed the order of 1O2 > ·OH > SO4·- > O2·-. The doping of magnetic biochar with potassium increased its Fe(II) content, approximately 3.1 times higher than that of pristine magnetic biochar. The differences in Fe(II) content between potassium-doped magnetic biochar and magnetic biochar were the key reasons for the activation performance differences. Based on the ultra-high pressure liquid chromatography-quadrupole tandem time-of-flight mass spectrometer, the primary degradation intermediates of metronidazole were identified, and possible degrading pathways were proposed. Overall, this work provides an effective strategy to improve the activation performance of magnetic biochar.

Increasing the electron selectivity of nanoscale zero-valent iron in environmental remediation: A review.

Nanoscale zero-valent iron nanoparticles (nZVI) have been used for groundwater remediation and wastewater treatment due to their high reactivity, high adsorption capacity and nontoxicity. However, side reactions generally occur in tandem with the target contaminants removal process, resulting in poor electron selectivity (ES) of nZVI, and subsequently restricting its commercial application. Major efforts to increase ES of nZVI have been made in recent years. This review's objective is to provide a progress report on the significant developments in nZVI's ES during the past decade. Firstly, the definition of ES and its quantification approaches were documented, and the intrinsic (i.e. particle size, crystallinity, and surface area) and extrinsic factors (i.e. solutions pH, target contaminant concentration, and presence of co-contaminants) affecting the ES of nZVI were reported. The latest techniques for increasing ES were summarized in detail, with reference made to sulfidation, magnetization, carbon loading and other features. Then the mechanisms of those strategies for ES enhancement were described. Finally, some constructive suggestions on future research directions concerning nZVI's ES in the future were proposed.

Magnetic biochar derived from rice straw and stainless steel pickling waste liquor for highly efficient adsorption of crystal violet.

Reducing the preparation cost of magnetic biochar is necessary for its large-scale application as an adsorbent. In this study, stainless steel pickling waste liquor and rice straw were successfully applied to synthesize of magnetic biochar (SPWL-MBC). Several iron oxides adhered on the biochar matrix, mainly Fe3O4, Fe2O3 and FeO. SPWL-MBC exhibited superparamagnetism, and its specific surface area was 274.29 m2/g. The material was able to adsorb a model contaminant, crystal violet (CV), with a maximum adsorption capacity of approximately 111.48 mg/g. Adsorption mechanism analysis showed that iron oxides, π-π interaction, hydrogen bonding and electrostatic interaction were responsible for the adsorption of CV. The CV adsorption efficiency of SPWL-MBC remained 71.91% after three adsorption-regeneration cycles. These outcomes illustrate that the magnetic biochar prepared from stainless steel pickling waste liquor can effectively remove CV from wastewater.

Highly efficient remediation of decabromodiphenyl ether-contaminated soil using mechanochemistry in the presence of additive and its mechanism.

Mechanochemistry has been proved to be an effective method to remediation of organic-contaminated sites. However, the high ball-to-powder mass ratio (CR) limits the large-scale application of mechanochemistry. In this study, co-milling additives were introduced to enhance the mechanochemical degradation of decabromodiphenyl ether (BDE209)-contaminated soil under the condition of low CR. Based on additive screening experiments, sodium borohydride was selected as the ideal additive to assist the mechanochemical degradation of BDE209, and the resulting removal efficiency was approximately 100% with 2 h of ball milling at a rotational speed of 550 rpm. The main degradation intermediates and degradation pathway of BDE209 were identified using gas chromatography-tandem mass spectrometry. It was proposed that the degradation of BDE209 by sodium borohydride-assisted mechanochemistry was a concurrent process of stepwise and multistage debromination. Meanwhile, the meta-bromine atom in BDE209 was more susceptible to debromination than those at the para and ortho positions. The evolution of the concentration of Br- was monitored by ion chromatography, which revealed that reduction and oxidation both occurred in the removal of BDE209. This paper provides a new perspective for reducing the CR in the mechanochemical remediation of BDE209-contaminated soil.

First-Line Contact Aspiration vs Stent Retriever for Proximal Occlusion in Acute Ischemic Stroke: A Systemic Review and Meta-Analysis.

INTRODUCTION: The aim of this systematic review and meta-analysis was to compare the performance of first-line contact aspiration (ASP) and stent retriever (SR) in acute ischemic stroke caused by proximal large vessel occlusion. METHODS: Cochrane databases, MEDLINE and EMBASE were systematically searched for literatures reporting outcomes on thrombectomy with both first-line aspiration and first-line stent retriever in proximal occlusion. RESULTS: Thirteen studies with a total of 1614 patients were included. No differences were identified between the SR and ASP groups in terms of final reperfusion rate (modified thrombolysis in cerebral infarction 2b/3) (OR: 1.54, 95% CI: 0.88-2.70), complete recanalization rate (modified thrombolysis in cerebral infarction 3) (OR: 1.78, 95% CI: 0.58-5.44), and favorable outcomes (modified Rankin scale ≤2) (OR: 1.02, 95% CI: 0.79-1.32). With regard to adverse events, emboli to new territories (OR: 0.81, 95% CI: 0.31-2.14), intracranial hemorrhage (OR: 0.71, 95% CI: 0.40-1.28), 90-days mortality (OR: 1.02, 95% CI: 0.71-1.47) were similar between groups, while symptomatic intracerebral hemorrhage (OR: 0.43 95% CI: 0.21-0.86) was less seen in ASP. Subgroup analysis indicated that ASP was comparable to stent retriever with local aspiration (SRLA) (OR: 1.25 95% CI: 0.25-6.22) and superior to stent retriever alone (OR: 1.85 95% CI: 1.22-2.81). Moreover, in posterior circulation, contact aspiration achieved a significantly higher reperfusion (OR: 1.97 95% CI: 1.03-3.76) compared to stent retriever, and needed relatively less rescue therapies (21.5% vs 29.6%, p < 0.05). CONCLUSION: Our study suggested that contact aspiration might be advantageous over stent retriever alone and more suitable in posterior circulation. While ASP and SRLA thrombectomy were equally effective in achieving good clinical outcomes. However, further studies are needed to confirm these results.

Effective degradation of tetracycline by magnetic palygorskite synthesized with different dosages of NaOH.

In the process of preparing magnetic palygorskite from waste pickling liquor of the steel industry, the dosage of NaOH will affect the properties of the magnetic palygorskite. The experimental results showed that magnetic palygorskite can be effectively prepared when NaOH dosage is between 255 and 330 g/L. Vibration sample magnetometry proved that different NaOH dosages can affect the saturation magnetization of magnetic palygorskite. The catalytic performance of five catalysts synthesized with different NaOH dosages hardly changed after five cycles of Fenton-like catalytic degradation of tetracycline (TC). The magnetic palygorskite prepared by this method had good catalytic performance even when the catalyst preparation conditions were magnified ten times, which can provide a reference for large-scale preparation of magnetic palygorskite.

Magnetic biochar for environmental remediation: A review.

The difficulty of separating the powdered biochar from the environmental medium may lead to secondary pollution and hinder the large-scale application of biochar as an adsorbent. An effective strategy to solve this bottleneck is to introduce transition metals and their oxides into the biochar matrix, creating easily separable magnetic biochar. Magnetic biochar is also effective for the removal of pollutants from aqueous solution. This review comprises a systematic analysis of 109 papers published in recent years (From 2011 to June 2019), and summarises the synthetic methods and raw materials required for magnetic biochar preparation. The basic physicochemical properties of magnetic biochar are expounded, together with findings from relevant studies, and the application of magnetic biochar as an adsorbent or catalyst in environmental remediation are summarised. Other applications of magnetic biochar are also discussed. Finally, some constructive suggestions are given for the future direction of magnetic biochar research.

Aging effects on the stabilisation and reactivity of iron-based nanoparticles green synthesised using aqueous extracts of Eichhornia crassipes.

Aging effects play a crucial role in determining applications of green-synthesised iron-based nanoparticles in wastewater treatment from laboratory scale to practical applications. In this study, iron-based nanoparticles (Ec-Fe-NPs) were synthesised using the extract of Eichhornia crassipes and ferric chloride. Scanning electron microscopy (SEM) revealed that the fresh Ec-Fe-NPs were spherical and had a narrow particle size range (50 to 80 nm). X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) demonstrated that the Ec-Fe-NPs were mainly amorphous in nature and consisted of Fe0, FeO, Fe2O3 and Fe3O4. As they aged, the particle size of the liquid Ec-Fe-NPs gradually increased and then tended to stabilise. Ec-Fe-NPs that were aged for 28 days were only 19% less efficient than fresh material at removing Cr(VI). Extracts aged up to 28 days were also tested, and their antioxidant capacity was found to be 15.4% lower than that of the fresh extracts. Furthermore, the removal efficiency of Cr(VI) using iron-based nanoparticles synthesised with the aged extracts was 67.2%. Finally, the active components of the extracts, which were responsible for the reactivity and stability of the iron-based nanoparticles, were identified by liquid chromatography-mass spectrometry. Overall, green-synthesised iron-based nanoparticles show promise for Cr(VI) removal from wastewater in practical applications.

Pyrolysis of different biomass pre-impregnated with steel pickling waste liquor to prepare magnetic biochars and their use for the degradation of metronidazole.

In this study, Fenton-like catalysts (magnetic biochar) were synthesised by pyrolysis the different biomass pre-impregnated with steel pickling waste liquor. The results of degradation of metronidazole illustrated that the catalytic performance of magnetic biochar was significantly affected by biomass feedstocks. Electron spin resonance (ESR) and radical quenching experiments showed that the hydroxide radicals (OH) were the key reactive oxygen species responsible for the metronidazole removal. Levels of OH varied among different systems consistent with the removal of metronidazole. The activation of H2O2 by carbon-containing components and Fe species (Fe2O3 and Fe3O4) in magnetic biochar were confirmed to be less crucial to the degradation of metronidazole. Moreover, the Fe(II) (FeO) in magnetic biochar played the dominating role in degradation of metronidazole, and the Fe(II) content difference caused by biomass feedstocks was responsible for differences in the catalytic performance of different types of magnetic biochar.