Facile Prepared MOF-OH-PAN Nanofiber for Separation Co(II) from Waste Batteries.

Recovering cobalt from waste batteries is crucial for resource recycling and environmental protection. Here, MOF-OH, a Zr-based MOF, was synthesized and merged into a polyacrylonitrile (PAN) matrix to create MOF-OH-PAN nanofibers (NFs). These NFs showed a high cobalt ion adsorption capacity of 33.1 mg/g, retaining over 90% of the capacity after six cycles. The adsorption mechanism involves Co(II) surface diffusion followed by strong bonding with functional groups. This technology enables efficient cobalt recovery from waste batteries, supporting reuse and reducing resource depletion and environmental pollution. The study provides insights into waste battery resource management, highlighting environmental and economic benefits and contributing to green resource recovery and circular economy initiatives.

Facile construction of ZIF-94/PAN nanofiber by electrospinning for the removal of Co(II) from wastewater.

This study aimed to synthesize a novel nanofiber adsorbent based on metal-organic frameworks (MOFs), ZIF-94-PAN, by incorporating ZIF-94 into polyacrylonitrile (PAN) through electrospinning. The investigation of the adsorption characteristics of ZIF-94-PAN for cobalt ions was undertaken, yielding findings that suggest an optimum ZIF-94 loading content within the ZIF-94-PAN composite of 8%. The adsorption experiments revealed that, under pH 8.3 and 298 K, ZIF-94-PAN-8% attained cobalt ion equilibrium adsorption (139.08 mg/g). Additionally, the adsorption kinetics of cobalt ions exhibited conformity with the pseudo-second-order model, whereas adherence to the Freundlich isotherm model indicated a non-homogeneous, endothermic process. XPS analysis unveiled that the adsorption mechanism was characterized by the coordination of nitrogen and oxygen atoms within ZIF-94-PAN with cobalt ions. This study effectively addressed the challenges of separating and recovering MOFs adsorbents by fabricating them as nanofibers. The remarkable adsorption performance and stability of the ZIF-94-PAN nanofibers highlight their potential for removing cobalt-contaminated wastewater.

In Situ Synthesis of NH2-MIL-53-Al/PAN Nanofibers for Removal Co(II) through an Electrospinning Process.

In this study, researchers developed a novel composite material called NH2-MIL-53-Al/PAN, which consists of metal-organic frameworks (MOFs) grown on electrospun PAN nanofibers (NFs). The successful formation of the composite was confirmed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR), and the hydrophilicity of NH2-MIL-53-Al/PAN was demonstrated by the water contact angle (WCA). Batch experiments were conducted to investigate the adsorption performance of Co(II) under different conditions. The maximum adsorption capacity reached 58.72 mg/g, and almost 95% of the adsorption was achieved within the first 6 h. The adsorption process was found to be spontaneous and endothermic and followed the pseudo-second-order kinetics and Langmuir models. Chemisorption and molecular layer adsorption are the main mechanisms of adsorption, and X-ray photoelectron spectroscopy (XPS) analysis further reveals that the interaction between the adsorbent and cobalt is a coordination interaction. In this study, NH2-MIL-53-Al was grown in situ on PAN to ensure effective loading of MOFs and prevent agglomeration during the NF mixing process. This approach successfully addressed the challenge of exposing active sites within the embedded MOF crystals. Additionally, it overcame the difficulty of recycling traditional MOF adsorbents. As a result, the exceptional performance of MOF NFs offers a promising solution for the efficient removal of cobalt-containing wastewater.

Facile preparation of UiO-66-Lys/PAN nanofiber membrane by electrospinning for the removal of Co(II) from simulated radioactive wastewater.

In this study, metal-organic framework (MOF) nanofiber membranes (NFMs) UiO-66-Lys/PAN were prepared by electrospinning using polyacrylonitrile (PAN) as the matrix, UiO-66-NH2 as the filler, and lysine (Lys) as the functional monomer. The membranes were subsequently employed to extract cobalt ions from simulated radioactive wastewater. The findings showed that the best performance of the membrane was obtained with a 3 % MOF content (3%UiO-66-Lys/PAN). Specifically, the pure water flux (PWF) of the 3 % UiO-66-Lys/PAN membrane reached 872 L m-2 h-1 with a cobalt ion retention of 45.4 %. In addition, adsorption experiments indicated that the NFMs had a theoretical maximum adsorption capacity of 41.4 mg/g for cobalt ions. The Langmuir isotherm model and the pseudo-second-order kinetic model were observed in the adsorption process, suggesting that the membrane material showed uniform adsorption of cobalt ions on a monolayer level, with an endothermic absorption process. XPS analysis confirmed that 3%UiO-66-Lys/PAN facilitated the adsorption of cobalt ions through a coordination effect, with the N and O atoms serving as coordinating atoms. Moreover, the material displayed excellent radiation stability even when exposed to doses ranging from 20 to 200 kGy. This study validated the stability of the MOF NFMs under real irradiation with radioactive nuclides (60Co) and demonstrated efficient cobalt ion separation. This study has important practical implications for the treatment and disposal of small volumes of 60Co-containing radioactive wastewater for engineering applications.

One-pot synthesis of novel mesoporous FeOOH modified NaZrH(PO4)2·H2O for the enhanced removal of Co(II) from aqueous solution.

One-pot synthesis of a novel mesoporous hydroxyl oxidize iron functional Na-zirconium phosphate (FeOOH-NaZrH(PO4)2·H2O) composites was firstly characterized and investigated its Co(II) adsorption from aqueous solution. Compared to NaZrH(PO4)2·H2O (65.7 mg⋅g-1), the maximum Co(II) adsorption capacity of FeOOH-NaZrH(PO4)2·H2O was improved to be 95.1 mg⋅g-1. BET verified the mesoporous structures of FeOOH-NaZrH(PO4)2·H2O with a larger pore volume than NaZrH(PO4)2·H2O. High pH values, initial Co(II) concentration, and temperature benefited the Co(II) adsorption. Kinetics, isotherms, and thermodynamics indicated an endothermic, spontaneous chemisorption process. FeOOH-NaZrH(PO4)2·H2O has a better Co(II) adsorption selectivity than that of NaZrH(PO4)2·H2O. In particular, FeOOH-NaZrH(PO4)2·H2O exhibited an outstanding reusability after ten cycles of tests. The main possible mechanism for adsorbents uptake Co(II) involved in ion exchange, electrostatic interaction, and -OH, Zr-O bond coordination based on FTIR and XPS analysis. This work presents a feasible strategy to prepare novel modified zirconium phosphate composites for extracting Co(II) from solutions and providing a new insight into the understanding of Co(II) adsorption in the real nuclear Co(II)-containing wastewater.

Synthesis and Application of a Novel Metal-Organic Frameworks-Based Ion-Imprinted Polymer for Effective Removal of Co(II) from Simulated Radioactive Wastewater.

In this work, a novel metal-organic frameworks (MOFs)-based ion-imprinted polymer (MIIP) was prepared to remove Co(II) from simulated radioactive wastewater. The batch experiments indicated that the sorption was well described by the pseudo-second-order kinetic and Langmuir models, and it is monolayer chemisorption. The theoretical maximum sorption capacity was estimated to be 181.5 mg∙g-1, which is by far the reported maximum value of Co(II) sorption by the imprinted materials. The MIIP presented an excellent selectivity for Co(II) in the presence of common monovalent and divalent metal ions, and the selectivity coefficients were 44.31, 33.19, 10.84, 27.71, 9.45, 16.25, and 7.60 to Li(I), K(I), Mg(II), Ca(II), Mn(II), Ba(II), and Cd(II), respectively. The sorption mechanism was explored by X-ray photoelectron spectroscopy (XPS) technology and density functional theory (DFT) calculations, suggesting that Co(II) was adsorbed by the MIIP via the chelation of 4-vinylpyridine (VP) ligands with Co(II), which was a spontaneous process, and the optimal coordination ratio of VP to Co(II) was 6. This work suggested that the MIIP has a high sorption capacity and excellent selectivity for Co(II), which is of great significance for the selective separation of Co-60 from radioactive wastewater.

The influence of humic substances on uranium biomineralization induced by Bacillus sp. dwc-2.

In this paper, the influence of humic acid (HA) and fulvic acid (FA) on biomineralization behaviour was evaluated. The results showed HA and FA did not obviously inhabit or promote the precipitation of U-phosphate minerals. The data from molecular dynamic simulation indicated that the free energy for the dissociation of uranyl the PO43- -uranyl was 202.49 kJ/mol, which was much larger than that form HA-uranyl (88.3 kJ/mol). These simulated results revealed the less competitiveness of HA and FA with PO43- for uranyl and explained why HA and FA had less impacted on the formation of U-phosphate minerals. However, the influence of HA/FA on the morphology was obvious, the microstructure of the bio-minerals changed from small particles to lamellar stacking structure with the addition of HA or FA. The findings of this study are helpful for us to gain a better understanding natural U-phosphate biomineralization behaviour.