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Org Lett ; 15(20): 5286-9, 2013 Oct 18.
Article in English | MEDLINE | ID: mdl-24099181

ABSTRACT

The Ru(II)-catalyzed ortho-C-H amination directed by a weakly coordinating amide auxiliary with O-benzoyl hydroxylamines at room temperature has been achieved. This reaction is compatible with heterocycles including pyrazole, thiophene, benzothiophene, furan, benzofuran, and indole.


Subject(s)
Amines/chemical synthesis , Hydrocarbons, Aromatic/chemistry , Organometallic Compounds/chemistry , Ruthenium/chemistry , Temperature , Amides/chemistry , Amination , Amines/chemistry , Catalysis , Molecular Structure
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