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1.
Bioact Mater ; 37: 424-438, 2024 Jul.
Article in English | MEDLINE | ID: mdl-38689661

ABSTRACT

Bone nonunion poses an urgent clinical challenge that needs to be addressed. Recent studies have revealed that the metabolic microenvironment plays a vital role in fracture healing. Macrophages and bone marrow-derived mesenchymal stromal cells (BMSCs) are important targets for therapeutic interventions in bone fractures. Itaconate is a TCA cycle metabolite that has emerged as a potent macrophage immunomodulator that limits the inflammatory response. During osteogenic differentiation, BMSCs tend to undergo aerobic glycolysis and metabolize glucose to lactate. Copper ion (Cu2+) is an essential trace element that participates in glucose metabolism and may stimulate glycolysis in BMSCs and promote osteogenesis. In this study, we develop a 4-octyl itaconate (4-OI)@Cu@Gel nanocomposite hydrogel that can effectively deliver and release 4-OI and Cu2+ to modulate the metabolic microenvironment and improve the functions of cells involved in the fracture healing process. The findings reveal that burst release of 4-OI reduces the inflammatory response, promotes M2 macrophage polarization, and alleviates oxidative stress, while sustained release of Cu2+ stimulates BMSC glycolysis and osteogenic differentiation and enhances endothelial cell angiogenesis. Consequently, the 4-OI@Cu@Gel system achieves rapid fracture healing in mice. Thus, this study proposes a promising regenerative strategy to expedite bone fracture healing through metabolic reprogramming of macrophages and BMSCs.

2.
Sci Rep ; 14(1): 7458, 2024 Mar 29.
Article in English | MEDLINE | ID: mdl-38548876

ABSTRACT

The glass-glass interfaces (GGIs) are in a unique glass phase, while current knowledge on the interfacial phase has not completely established to explain the unprecedented improvements in the ductility of metallic nanoglasses (NGs). In this work, Co-P NGs prepared through the pulse electrodeposition are investigated, whose GGI regions clearly show elemental segregation with chemical composition dominated by element Co. Such compositional heterogeneity is further verified by molecular dynamics (MD) simulation on the formation of GGIs in Co-P NGs and atomic structures of GGIs with Co segregation are found to be less dense than those of glassy grains. More importantly, Co segregation at GGIs is closely related to the improved ductility observed in Co-P NGs, as demonstrated by nanoindentation measurements and MD simulations. This work facilitates the understanding on the relations between compositional heterogeneity and improved ductility as observed in Co-P NGs, and thus opens a new window for controlling the mechanical properties of NGs through GGI engineering.

3.
Small ; : e2311731, 2024 Feb 06.
Article in English | MEDLINE | ID: mdl-38321844

ABSTRACT

Wilderness adventure favored by many enthusiasts often endanger lives due to lacking freshwater or drinking contaminated water. Therefore, compared to the inefficient methods of filtration, steaming, and direct solar heating, it is of great meaningfulness to develop a solar-driven water purification device with efficiency, lightweight, portability, and multi-water-quality purification by taking full advantage of solar-driven interfacial evaporation. Here, a tent-inspired portable solar-driven water purification device consisting of Janus-structured bacterial cellulose aerogel (JBCA) solar evaporator and tent-type condensation recovery device is reported. For the JBCA solar evaporator, it is prepared from biomass bacterial cellulose (BC) as raw material and hydroxylated carbon nanotubes (HCNT) as photothermal material, and the Janus property is achieved by the assistance of hydrophobic and hydrophilic chemical cross-linking. It exhibits lightweight, unibody, high photothermal conversion, efficient evaporation, and multi-water-quality purification capability for representative seawater, urine, and bacterial river water. For the tent-type condensation recovery device, it is based on the prototype of tent and uses flexible ultra-transparent polyvinyl chloride (PVC) film as raw material. Thanks to the rational prototype and material selection, it displays outstanding portability and lightweight through the folding/unfolding method. Therefore, the designed tent-inspired portable solar-driven water purification device demonstrates great potential application in wilderness exploration.

4.
BMJ Open ; 14(2): e077078, 2024 Feb 10.
Article in English | MEDLINE | ID: mdl-38341212

ABSTRACT

OBJECTIVES: To investigate the prevalence of depression and anxiety symptoms among older adults in an urban district in China, as well as their associated factors. DESIGN: Cross-sectional study. SETTING: General communities in Shenzhen, Guangdong, China. PARTICIPANTS: A total of 5372 community-dwelling older adults aged 65 years or older were initially recruited. Ultimately, 5331 participants met the inclusion criteria and were included in this study. METHODS: Participants completed a sociodemographic questionnaire, along with assessments including the Patient Health Questionnaire-9, Generalised Anxiety Scale-7, UCLA Loneliness Simplification Scale, Insomnia Severity Index Scale (ISI), Community Dementia Brief Screening Scale and the 8-item Dementia Screening Questionnaire. Statistical analyses included the Shapiro-Wilk test, independent t-test, Wilcoxon rank test, χ2 test and univariate and multivariate linear regression analysis. RESULTS: The prevalence of depression and anxiety symptoms among older adults in Shenzhen communities was 10.4% and 11.3%, respectively. In multivariate analysis, age (B=-0.01, p<0.05), relatively poor health status in the past year (B=1.00, p<0.01), poor health status in the past year (B=2.40, p<0.01), ISI score (B=0.21, p<0.01), -item Ascertain Dementia Questionnaire (AD8) score (B=0.22, p<0.01), UCLA Loneliness Scale (ULS) score (B=0.24, p<0.01) were significantly associated with the severity of depression symptom, Compared with their respective reference categories, relatively poor health status in the past year (B=0.50, p<0.01), poor health status in the past year (B=1.32, p<0.01), ISI score (B=0.23, p<0.01), sleep duration (B=0.05, p<0.01), AD8 score (B=0.21, p<0.01), Community Screening Instrument for Dementia score (B=0.13, p<0.01), ULS score (B=0.22, p<0.01) were significantly associated with the severity of anxiety symptom. CONCLUSIONS: We observed a high prevalence of depression and anxiety symptoms among older adults in this study. The existing welfare system and infrastructure should remain and targeted mental health programmes addressing the identified risk factors should be proposed.


Subject(s)
Dementia , Depression , Humans , Aged , Cross-Sectional Studies , Prevalence , Depression/psychology , Anxiety/psychology , China/epidemiology , Dementia/epidemiology
5.
Small ; 20(12): e2307259, 2024 Mar.
Article in English | MEDLINE | ID: mdl-37948421

ABSTRACT

As one of the important directions of solar energy utilization, the construction of composite photothermal phase change materials (PCM) with reasonable network support and low leakage in the simple method is important to solve the transient availability of solar energy and achieve long-lasting energy output. Here, a multifunctional silylated bacterial cellulose (BC)/hydroxylated carbon nanotube (HCNT)/polyethylene glycol (PEG) (SBTP) photothermal film-based PCM with cross-linked network structure is prepared by simple one-step synthesis. The formation of the cross-linked network structure achieves the enhancement of BC support network, prominent dispersion of HCNT and the direct introduction and perfect interlocking of PEG. Therefore, the optimal SBTP film exhibits high thermal enthalpy of 145.1 J g-1, enthalpy efficiency of over 94%, robust shape stability and low leakage of <1.2%. It also displays high photothermal conversion of over 80 °C, photothermal storage of 394 s g-1 and excellent stability. Thus, it can demonstrate a maximum output voltage of 423 mV and high power density of 30.26 W m-2 under three solar irradiations when applied in the solar-thermal-electric energy conversion field. Meanwhile, it also can apply in the thermal management of solar cell and light-emitting diode (LED) chip, and convert the waste heat into electricity, demonstrating multi-scene application capability.

6.
Adv Mater ; 36(9): e2307708, 2024 Mar.
Article in English | MEDLINE | ID: mdl-37879760

ABSTRACT

Aqueous zinc electrolytes offer the potential for cheaper rechargeable batteries due to their safe compatibility with the high capacity metal anode; yet, they are stymied by irregular zinc deposition and consequent dendrite growth. Suppressing dendrite formation by tailoring the electrolyte is a proven approach from lithium batteries; yet, the underlying mechanistic understanding that guides such tailoring does not necessarily directly translate from one system to the other. Here, it is shown that the electrostatic shielding mechanism, a fundamental concept in electrolyte engineering for stable metal anodes, has different consequences for the plating morphology in aqueous zinc batteries. Operando electrochemical transmission electron microscopy is used to directly observe the zinc nucleation and growth under different electrolyte compositions and reveal that electrostatic shielding additive suppresses dendrites by inhibiting secondary zinc nucleation along the (100) edges of existing primary deposits and encouraging preferential deposition on the (002) faces, leading to a dense and block-like zinc morphology. The strong influence of the crystallography of Zn on the electrostatic shielding mechanism is further confirmed with Zn||Ti cells and density functional theory modeling. This work demonstrates the importance of considering the unique aspects of the aqueous zinc battery system when using concepts from other battery chemistries.

7.
Foods ; 12(14)2023 Jul 23.
Article in English | MEDLINE | ID: mdl-37509886

ABSTRACT

To reduce the usage of petroleum-based plastic products, a lignin-based film material named aminated lignin/Fe(III)/PVA was developed. The mixture of 8 g lignin, 12 mL diethylenetriamine, 200 mL NaOH solution (0.4 mol·L-1), and 8 mL formaldehyde was heated at 85 °C for 4 h; after the aminated lignin was impregnated in the Fe(NO3)3 solution, a mixture of 3 g aminated lignin/Fe(III), 7 g PVA, and 200 mL NaOH solution (pH 8) was heated at 85 °C for 60 min; after 2 mL of glycerin was added, the mixture was spread on a glass plate to obtain the aminated lignin/Fe(III)/PVA film. This film demonstrated hydrophobicity, an UV-blocking function, and a good slow-release performance. Due to the formation of hydrogen bonds between the hydroxyl groups of lignin and PVA, the tensile strength, the elongation at break, and the fracture resistance of the film were 9.1%, 107.8%, and 21.9% higher than that of pure PVA film, respectively. The iron content of aminated lignin/Fe(III)/PVA was 1.06 wt%, which mainly existed in a trivalent form. The aminated lignin/Fe(III)/PVA film has the potential to be used as a food packaging material with anti-ultraviolet light function and can also be developed as other packaging materials, such as seedling bowls, pots for transplanting, and coating films during transport.

8.
Nature ; 618(7964): 287-293, 2023 Jun.
Article in English | MEDLINE | ID: mdl-37286650

ABSTRACT

All-solid-state batteries with a Li anode and ceramic electrolyte have the potential to deliver a step change in performance compared with today's Li-ion batteries1,2. However, Li dendrites (filaments) form on charging at practical rates and penetrate the ceramic electrolyte, leading to short circuit and cell failure3,4. Previous models of dendrite penetration have generally focused on a single process for dendrite initiation and propagation, with Li driving the crack at its tip5-9. Here we show that initiation and propagation are separate processes. Initiation arises from Li deposition into subsurface pores, by means of microcracks that connect the pores to the surface. Once filled, further charging builds pressure in the pores owing to the slow extrusion of Li (viscoplastic flow) back to the surface, leading to cracking. By contrast, dendrite propagation occurs by wedge opening, with Li driving the dry crack from the rear, not the tip. Whereas initiation is determined by the local (microscopic) fracture strength at the grain boundaries, the pore size, pore population density and current density, propagation depends on the (macroscopic) fracture toughness of the ceramic, the length of the Li dendrite (filament) that partially occupies the dry crack, current density, stack pressure and the charge capacity accessed during each cycle. Lower stack pressures suppress propagation, markedly extending the number of cycles before short circuit in cells in which dendrites have initiated.

9.
RSC Adv ; 13(11): 7694-7702, 2023 Mar 01.
Article in English | MEDLINE | ID: mdl-36908530

ABSTRACT

Bio-oil can be used as a substitute for fossil fuels after it is upgraded. Bimetal-modified HZSM-5 catalysts with various Ni-to-Co ratios were prepared to address catalysis problems, including deactivation of the catalysts and low hydrocarbon yields. The catalytic performance of Ni-Co/HZSM-5 in upgrading the simulated bio-oil was investigated with a fixed-bed reactor, and the influence of the loaded duplex metal ratio was also discussed. The new moderately strong/strong acid sites of Ni-Co/HZSM-5 changed according to the Ni/Co loading ratios, which substantially affected the acidity, catalytic activity and selectivity of the Ni-Co/HZSM-5. However, incorporating Co and Ni into the zeolite did not alter the structure of the HZSM-5. The interactions of the loaded bimetallic oxides reached equilibrium in 6Ni-4Co/HZSM-5, in which moderately strong acid sites and strong acid sites were formed after loading with Co3O4 and NiO. With a suitable acid site ratio, 6Ni-4Co/HZSM-5 exhibited excellent performance, with a lower coke deposition of 3.29 wt% and stable catalytic activity, and the conversion remained at 83-73% during 360 min of uninterrupted catalysis. Periodic changes in the acid sites and interfacial protons were the critical factors that improved the properties of the 6Ni-4Co/HZSM-5 and enhanced its selectivity for aromatic compounds.

10.
Heliyon ; 8(11): e11503, 2022 Nov.
Article in English | MEDLINE | ID: mdl-36411886

ABSTRACT

Metformin is a drug that has been applied in clinical use for many years for the treatment of type 2 diabetes mellitus (T2DM). It achieves its function through multiple targets and modulation of multiple signaling pathways. To date, the mechanism of the action of metformin is still not fully understood. Along with glycemic control, metformin has shown good inhibitory effects on the development of many tumors. Here, we elucidated that plasma exosomal microRNA-122-5p (miR-122) is closely related to the mechanism of metformin. MiR-122 regulates glycogen-glucose metabolism in hepatocytes or hepatocellular carcinoma cells (HCC) by inhibiting the phosphorylation of AMPK. Since miR-122 and metformin regulate glucose metabolism homeostasis through similar mechanisms, miR-122 can antagonize the effects of metformin. MiR-122 expression increases the sensitivity of hepatocytes or HCC to metformin. Conversely, decreased expression of miR-122 results in hepatocyte insensitivity to metformin. Therefore, significantly elevated levels of miR-122 in plasma exosomes of hepatocellular carcinoma patients could enhance their sensitivity to metformin. The results of the present study revealed a key regulatory role of plasma exosomal miR-122 on the molecular mechanism of metformin. The regulation of key molecules of related signaling pathways by miR-122 may lead to similar glycemic lowering and tumor suppression therapeutic effects as metformin. This provides new ideas for the development of new therapeutic strategies for hepatocellular carcinoma based on the mechanism of miR-122 and metformin.

11.
Materials (Basel) ; 15(15)2022 Jul 26.
Article in English | MEDLINE | ID: mdl-35897602

ABSTRACT

Soil mulch composite films composed of biodegradable materials are being increasingly used in agriculture. In this study, mulch films based on wheat straw fiber and an environmentally friendly modifier were prepared via in situ polymerization and tested as the ridge mulch for crops. The mechanical properties of the straw fiber film were significantly enhanced by the modification. In particular, the films exhibited a noticeable increase in dry and wet tensile strength from 2.35 to 4.15 and 0.41 to 1.51 kN/m, respectively, with increasing filler content from 0% to 25%. The contact angle of the straw also showed an improvement based on its hydrophilicity. The crystallinity of the modified film was higher than that of the unmodified film and increased with modifier content. The changes in chemical interaction of the straw fiber film were determined by Fourier transform infrared spectroscopy, and the thermal stability of the unmodified film was improved by in situ polymerization. Scanning electron microscopy images indicated that the modifier was uniformly dispersed in the fiber film, resulting in an improvement in its mechanical properties. The modified straw fiber films could be degraded after mulching for approximately 50 days. Overall, the superior properties of the modified straw fiber film lend it great potential for agricultural application.

12.
Medicine (Baltimore) ; 101(28): e29839, 2022 Jul 15.
Article in English | MEDLINE | ID: mdl-35839036

ABSTRACT

The aim was to investigate the circadian and seasonal variation of acute myocardial infarction (AMI). Clinical data of 3867 AMI patients hospitalized from November 2010 to October 2019 in the Border Yanbian Minority Autonomous Prefecture, China were collected, and 3158 patients with definite AMI onset times were analyzed. The clinical data analyzed included the time of onset, nationality, age, laboratory data. We divided the patients into 4 groups based on the timepoint of their AMI onsets: 00:00-05:59, 06:00-11:59, 12:00-17:59, and 18:00-23:59. We also divided the patients based on nationality: Chinese Korean and Han groups. We observed that there is a circadian rhythm in the incidence of AMI, and the peak of AMI is in the morning (7:00-9:00). Unexpectedly, the incidence of AMI was significantly lower in the cold winter than that of other 3 warm seasons (P < 0.01) and the peak of AMI presented at the months of the large contrast between day and night temperature difference (over 20°C) like May of Spring and October of Fall. Finally, there was no difference in circadian rhythm between Chinese Korean and Han, although these groups differed in age, body mass index, and the inflammatory cell level. These findings have shown a different seasonal and circadian variation in onset of AMI. Further studies are required to determine the pathophysiological mechanism(s) underlying these differences and to guide prevention of AMI for reducing its mortality and disability.


Subject(s)
Myocardial Infarction , Circadian Rhythm , Climate , Humans , Incidence , Myocardial Infarction/epidemiology , Myocardial Infarction/etiology , Seasons
13.
Adv Mater ; 34(28): e2202552, 2022 Jul.
Article in English | MEDLINE | ID: mdl-35560650

ABSTRACT

Despite being one of the most promising candidates for grid-level energy storage, practical aqueous zinc batteries are limited by dendrite formation, which leads to significantly compromised safety and cycling performance. In this study, by using single-crystal Zn-metal anodes, reversible electrodeposition of planar Zn with a high capacity of 8 mAh cm-2 can be achieved at an unprecedentedly high current density of 200 mA cm-2 . This dendrite-free electrode is well maintained even after prolonged cycling (>1200 cycles at 50 mA cm- 2 ). Such excellent electrochemical performance is due to single-crystal Zn suppressing the major sources of defect generation during electroplating and heavily favoring planar deposition morphologies. As so few defect sites form, including those that would normally be found along grain boundaries or to accommodate lattice mismatch, there is little opportunity for dendritic structures to nucleate, even under extreme plating rates. This scarcity of defects is in part due to perfect atomic-stitching between merging Zn islands, ensuring no defective shallow-angle grain boundaries are formed and thus removing a significant source of non-planar Zn nucleation. It is demonstrated that an ideal high-rate Zn anode should offer perfect lattice matching as this facilitates planar epitaxial Zn growth and minimizes the formation of any defective regions.

14.
Ther Clin Risk Manag ; 18: 31-45, 2022.
Article in English | MEDLINE | ID: mdl-35027830

ABSTRACT

BACKGROUND: The prognostic implications of the admission cTnI level and D2B time combined on in-hospital and 1-year heart failure (HF) and mortality in STEMI patients undergoing a primary percutaneous coronary intervention (PCI) are remain uncertain. METHODS AND RESULTS: We divided the consecutive 1485 STEMI patients who underwent PCI from January 2015 to October 2019 at our hospital into three groups based on their admission cTnI levels: normal group (<0.1 ng/mL), middle group (0.1 to less than 3 ng/mL), and high group (≥3 ng/mL) and into two groups by their D2B times: >90 min (>90-D2B) and ≤90 min (≤90-D2B). During the in-hospital and 1-year follow-up periods, the incidence of composite clinical events increased significantly with the increase in the admission cTnI level (p < 0.05). In-hospital, the composite rate of death and HF events was significantly higher in the >90-D2B group compared to the ≤90-D2B group (p = 0.006), but its influence disappeared in the 1-year follow-up (p > 0.05). A multivariable logistic analysis revealed that, in the ≤90-D2B group, with the exception of the cTnI ≥3 ng/mL patients, the cTnI level had no effect on in-hospital or 1-year outcomes; in >90-D2B group, cTnI ≥3ng/mL increased outcomes in both periods. CONCLUSION: High cTnI levels (≥3 ng/mL) on admission are independent of the D2B time for predicting in-hospital and 1-year cardiac events in STEMI patients undergoing PCI.

15.
Exp Anim ; 70(4): 541-552, 2021 Nov 10.
Article in English | MEDLINE | ID: mdl-34219073

ABSTRACT

Exposure to chronic psychosocial stress is a risk factor for various pulmonary diseases. In view of the essential role of dipeptidyl peptidase 4 (DPP4) in animal and human lung pathobiology, we investigated the role of DPP4 in stress-related lung injury in mice. Eight-week-old male mice were randomly divided into a non-stress group and a 2-week immobilization stress group. Non-stress control mice were left undisturbed. The mice subjected to immobilized stress were randomly assigned to the vehicle or the DPP4 inhibitor anagliptin for 2 weeks. Chronic stress reduced subcutaneous and inguinal adipose volumes and increased blood DPP4 levels. The stressed mice showed increased levels in the lungs of genes and/or proteins related to oxidative stress (p67phox, p47phox, p22phox and gp91phox), inflammation (monocyte chemoattractant protein-1, vascular cell adhesion molecule-1, and intracellular adhesion molecule-1), apoptosis (caspase-3, -8, -9), senescence (p16INK4A, p21, and p53) and proteolysis (matrix metalloproteinase-2 to -9, cathepsin S/K, and tissue inhibitor of matrix metalloproteinase-1 and -2), and reduced levels of eNOS, Sirt1, and Bcl-2 proteins; and these effects were reversed by genetic and pharmacological inhibitions of DPP4. We then exposed human umbilical vein endothelial cells in vitro to hydrogen peroxide; anagliptin treatment was also observed to mitigate oxidative and inflammatory molecules in this setting. Anagliptin can improve lung injury in stressed mice, possibly by mitigating vascular inflammation, oxidative stress production, and proteolysis. DPP4 may become a new therapeutic target for chronic psychological stress-related lung disease in humans and animals.


Subject(s)
Dipeptidyl Peptidase 4/genetics , Dipeptidyl-Peptidase IV Inhibitors/pharmacology , Inflammation/genetics , Lung Injury/prevention & control , Oxidative Stress , Animals , Dipeptidyl Peptidase 4/metabolism , Male , Mice , Mice, Inbred C57BL , Stress, Physiological , Stress, Psychological
16.
Int Heart J ; 62(1): 9-15, 2021 Jan 30.
Article in English | MEDLINE | ID: mdl-33390563

ABSTRACT

Cathepsin L (CatL) is a potent collagenase involved in atherosclerotic vascular remodeling and dysfunction in animals and humans. This study investigated the hypothesis that plasma CatL is associated with the prevalence of coronary artery disease (CAD). Between February May 2011 and January 2013, 206 consecutive subjects were enrolled from among patients who underwent coronary angiography and percutaneous coronary intervention treatment. Age-matched subjects (n = 215) served as controls. Plasma CatL and high-sensitive C-reactive protein (hs-CRP) and high-density lipoprotein cholesterol were measured. The patients with CAD had significantly higher plasma CatL levels compared to the controls (1.4 ± 0.4 versus 0.4 ± 0.2 ng/mL, P < 0.001), and the patients with acute coronary syndrome had significantly higher plasma CatL levels compared to those with stable angina pectoris (1.7 ± 0.7 versus 0.8 ± 0.4 ng/mL, P < 0.01). Linear regression analysis showed that overall, the plasma CatL levels were inversely correlated with the high-density lipoprotein levels (r = -0.32, P < 0.01) and positively with hs-CRP levels (r = 0.35, P < 0.01). Multiple logistic regression analyses shows that cathepsin L levels were independent predictors of CAD (add ratio, 1.8; 95% CI, 1.2 to 2.1; P < 0.01). These data demonstrated that increased levels of plasma CatL are closely associated with the presence of CAD and that circulating CatL serves as a useful biomarker for CAD.


Subject(s)
Atherosclerosis/blood , Biomarkers/blood , Cathepsin L/metabolism , Coronary Artery Disease/blood , Acute Coronary Syndrome/blood , Adult , Aged , Angina, Stable/blood , Atherosclerosis/physiopathology , C-Reactive Protein/metabolism , Case-Control Studies , China/epidemiology , Coronary Angiography/methods , Coronary Artery Disease/diagnosis , Coronary Artery Disease/epidemiology , Coronary Artery Disease/surgery , Female , Humans , Lipoproteins, HDL/blood , Male , Middle Aged , Percutaneous Coronary Intervention/methods , Prevalence
17.
Dalton Trans ; 49(6): 1785-1793, 2020 Feb 14.
Article in English | MEDLINE | ID: mdl-31971192

ABSTRACT

Increasing the voltage window of an electrode material is effective for improving the energy density of aqueous symmetric supercapacitors. Herein, a novel aqueous symmetric supercapacitor equipped with a high cell voltage window of 2.6 V was assembled by P-doped TiO2 nanotube arrays on a Ti sheet. The arrays exhibit a wide potential range of about 1.2 V as the cathode, and a stable wide potential range of 1.4 V as the anode was also obtained. These wide potential windows in the cathode and anode render the symmetric supercapacitor with a very large working voltage window reaching 2.6 V, and thus a high volumetric energy density (1.65 mW h cm-3). These results suggest that P-doped TiO2 nanotube arrays can be promising candidates for energy storage devices.

18.
J Colloid Interface Sci ; 565: 458-464, 2020 Apr 01.
Article in English | MEDLINE | ID: mdl-31982712

ABSTRACT

As a promising anode material for supercapacitors, Fe2O3 has been widely studied but still face the problem of low conductivity. Inducing oxygen vacancy (Vo) into Fe2O3 is a widely used approach to tune the conductivity to enhance its capacitive performance, but there is little research on the influence of Vo content. Herein, we report the effect of Vo in Fe2O3 nanoplates with various content. We tuned the Vo content by annealing at 200-500 °C. XPS and EPR were taken to characterize the Vo content, ranging from 11% to 26%. Electrochemical results show that FO-300 with 17% Vo has the highest capacity of 301 mAh g-1, and the capacity of the highest Vo content's (26% Vo) is only 107 mAh g-1. The symmetric supercapacitor based on FO-300 shows a considerably high energy density of 58.5 Wh kg-1 at a power density of 9.32 kW kg-1 and remains 84.6% after 12,000 cycles.

19.
Appl Opt ; 58(32): 8950-8958, 2019 Nov 10.
Article in English | MEDLINE | ID: mdl-31873677

ABSTRACT

Phase-based stereo matching (PSM) is a vital step in binocular structured light. PSM is hard to strike a balance between efficiency and accuracy, especially because of the absolute phase matrix's (APM) double data type. It means that PSM needs more run time and memory than conventional intensity images' stereo matching. In this paper, we propose a modified absolute difference (AD)-Census algorithm called the fixed window aggregation AD-Census (FWA-AD-Census) to balance the contradiction between efficiency and accuracy in PSM. The FWA-AD-Census aggregates matching cost in a fixed support window instead of an adaptive support window in AD-Census. We analyze the reason why PSM is more suitable to aggregate the matching cost in a fixed support window. Simulations and experiments are conducted to verify the FWA-AD-Census's performances by comparing the FWA-AD-Census with two other local stereo matching algorithms. One is the AD-Census, which is more accurate but less efficient. Its matching cost is aggregated in an adaptive support window. Another is the sum of absolute difference (SAD), which is more efficient but less accurate, and its matching cost is aggregated in a fixed support window. Theoretical analysis and experimental results both indicate that the proposed algorithm can achieve similar accuracy to the AD-Census with less run time.

20.
Polymers (Basel) ; 11(12)2019 Dec 14.
Article in English | MEDLINE | ID: mdl-31847424

ABSTRACT

Using 2,5-furandicarboxylic acid, ethylene glycol, and poly(ethylene glycol) as raw materials and ethylene glycol antimony as a catalyst, poly(ethylene furandicarboxylate) (PEF) and polyethylene glycol (PEG) copolymers (PEGFs) were synthesized by transesterification by changing the molecular weight of PEG (from 600 to 10,000 g/mol) and the PEG content (from 10 to 60 wt %). The thermal, hydrophilic, degradation, and spinnility characteristics of these copolymers were then investigated. Thermogravimetric analysis shows that PEGF is thermally stable at 62 °C, much lower than the temperature for PEF. The intrinsic viscosity of the obtained copolyester was between 0.67 and 0.99 dL/g, which is higher than the viscosity value of PEF. The contact angle experiment shows that the hydrophilicity of PEGFs is improved (the surface contact angle is reduced from 91.9 to 63.3°), which gives PEGFs a certain degradability, and the maximum mass loss can reach approximately 15%. Melt spinning experiments show that the PEGF polymer has poor spinnability, but the mechanical properties of the polymer monofilament are better.

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