Simultaneous degradation of p-nitrophenol and reduction of Cr(VI) in one step using microwave atmospheric pressure plasma.

Different physicochemical properties between Cr(VI) and phenolic compounds pose serious challenges for the effective treatment of co-contamination. This study developed an electrodeless high-flow microwave atmospheric plasma jet for the single-step simultaneous degradation of p-nitrophenol (PNP) and reduction of Cr(VI). Following a 15 min treatment with microwave atmospheric pressure plasma, the removal efficiency of Cr(VI) and PNP reached 97.5% and 93.6%, respectively, whereas that of total organic carbon reached 30.2%. Adding PNP to the solution significantly improved Cr(VI) reduction, whereas PNP degradation increased slightly with Cr(VI). The results indicate that the PNP intermediates significantly affected Cr(VI) reduction. Additionally, long-lived H2O2 and short-lived ·H aided the reduction of Cr(VI) during plasma treatment. The addition of hydroxyl scavengers during treatment implied that ·OH was largely responsible for PNP oxidation. High-performance liquid chromatography-mass spectroscopy (HPLC-MS) revealed that PNP intermediates, including p-nitrocatechol and 5-nitrobenzene-1,2,3-triol, function as Cr(VI) reductants. On the basis of the examined intermediate products, the potential PNP degradation pathway was investigated. The factors that could influence simultaneous dehgradation and reduction, including solution pH, gas velocity, and distance between the plasma outlet and the water surface were researched. Low pH supports Cr(VI) reduction, and the promotion of PNP for Cr(VI) reduction applies to all pH values. The degradation of PNP is insensitive to pH values with or without Cr(VI). The optimal gas velocity for PNP degradation and Cr(VI) reduction was revealed to be 6 L/min. The simultaneous removal of PNP and Cr(VI) benefits from a shorter distance between the plasma outlet and the water's surface.

An electrodeless atmospheric microwave plasma jet for efficient degradation of antibiotic norfloxacin.

Plasma technology is increasingly being used for the degradation of residual antibiotics in aquatic environments. However, the electrodes in conventional plasma generators are subject to erosion, which can pollute the reaction system and shorten its lifetime. To overcome these drawbacks, we developed an electrodeless high-flow atmospheric microwave plasma jet (MPJ) for fast and efficient degradation of residual norfloxacin (NOR), a typical fluoroquinolone antibiotic that is frequently detected in the aquatic environment owing to its widespread use in the treatment of various infectious diseases. Stable plasma was generated through a low-cost magnetron with the assistance of injection-locking technology. The degradation efficiency of NOR (20 mg/L) reached 98.27 ± 1.03% at 6 min and the mineralisation efficiency reached 68.67 ± 3.21% at 15 min. The fast degradation process of the NOR solution contributes to the large cross-section (approximately 153 mm2) of the plasma in direct contact with the solution. Hydroxyl radical (•OH) scavengers were used to identify the generated oxidising species, which indicated that their non-selective oxidation plays a major role in NOR degradation. Three main possible degradation pathways and mechanisms were proposed, namely the attack of •OH on the piperazine ring, quinolone ring, and benzene ring. The NOR solution was not toxic to Escherichia coli after 20 min of degradation. Thus, the high-flow atmospheric MPJ is an effective technology for the degradation of antibiotics in aqueous solutions.

A microwave atmospheric plasma strategy for fast and efficient degradation of aqueous p-nitrophenol.

Plasma technology has received intensive research interest in pollutants degradation. However, conventional plasma generator suffers from erosion of electrodes and consequent short life time and pollution. In this work, an electrodeless high-flow microwave atmospheric plasma jet is developed for fast degradation of p-nitrophenol. With the assistance of injection locking technology, stable plasma is managed to be generated by low-cost magnetron. 100% removal of 100 mg/L PNP is achieved after 12 min, with a TOC removal efficiency of 57.6%. The fast degradation is probably due to the high cross section (around 153 mm2) of plasma gas. Change in the removal efficiency are less than 4% and 5% as the pH of the solution changes from 2.02 to 12.07 and conductivity varies between 5.38 × 10-2 and 43.6 mS/cm, respectively. Moreover, optical emission spectroscopy spectra of the microwave plasma and a hydroxyl radical scavenger (t-butanol) are employed to identify the generated oxidizing species, which indicates that •OH is the key factor during the degradation process. The hydroxylated intermediates and organic acid transformed from PNP were revealed. Based on the examined intermediate products, the possible degradation mechanism and pathway are analyzed.

A convenient sol-gel approach to the preparation of nano-porous silica coatings with very low refractive indices.

Silica coatings with refractive indices as low as 1.10 were prepared via a one-step base-catalysed sol-gel process using methyltriethoxysilane and tetraethoxysilane as co-precursors. No expensive equipment was required and the method did not require etching or high-temperature calcination.