Polyaniline derived carbon membrane and its in-situ membrane fouling mitigation performance in MBR based on metal-free electro-Fenton.

An electro-enhanced membrane bioreactor (EMBR) was constructed with polyaniline-based carbon (PAC) separation membrane as the membrane-electrode, which could realize the in-situ electro-generation and activation of H2O2 to ·OH depending on the graphitic and pyridinic N as active sites without metal catalyst. After the continuous operation of the bioreactor for 74 days, approximately 77.41% irreversible membrane fouling occurred on the electrochemically enhanced membrane, which was less than that on the control membrane (85.96%). The ·OH oxidation combined with electrostatic barrier formed by -1.0 V enhanced PAC membrane suppressed the extracellular polymeric substances deposition on membrane. After operation, the strength of total cell, proteins, ß-polysaccharides and α-polysaccharides on the membrane without bias were 5.17, 4.32, 9.65 and 16.31, respectively. In EMBR, the corresponding strength were 2.03, 3.35, 2.15 and 6.73. After calculation, the unblocked pores accounted for 35.3% and 78.5% of the total membrane surface in MBR and EMBR, respectively, indicating the fouling was alleviated obviously. Meanwhile, the EMBR owned a satisfactory wastewater treatment effect with average effluent chemical oxygen demand and NH4+-N around 18.98 mg/L and 0.68 mg/L. The successful implementation of this strategy achieved a green and metal-free method for ·OH production with electrochemical effect for membrane fouling control in MBR.

Electro-Fenton improving fouling mitigation and microalgae harvesting performance in a novel membrane photobioreactor.

An innovative electro-Fenton enhanced membrane photobioreactor with satisfactory membrane fouling mitigation was constructed for microalgae harvesting. The porous carbon and carbon nanotubes hollow fiber membranes (PC-CHFMs) were used as the separation unit and cathode, simultaneously. H2O2 was generated by cathode reducing O2 in-situ, which would further produce •OH as the main oxidant by coupling H2O2 with Fe2+. The •OH could deeply remove the extracellular organic matter (EOM) deposited on the membrane surface or inside the pores. Experimental results showed that the permeate flux recovery rates of PC-CHFMs by electro-Fenton at the 18th, 29th and 41st day were 100%, 100% and 98.3%, respectively. The corresponding recovery rates by chemical cleaning at the same time were 99.8%, 81.7% and 54.4%. The stable and high permeate flux of PC-CHFMs made a great contribution to the microalgae harvesting efficiency, where the concentration factor could be 4.8 times higher than that of the control group. Filtrating superiority of PC-CHFMs was becoming more prominent with the extension of operating time. In addition, the removal efficiency of NH4+-N and TP in wastewater was approximately 100% at stable culture period.