Association of mental disorders with sepsis: a bidirectional Mendelian randomization study.

Background: Substantial research evidence supports the correlation between mental disorders and sepsis. Nevertheless, the causal connection between a particular psychological disorder and sepsis remains unclear. Methods: For investigating the causal relationships between mental disorders and sepsis, genetic variants correlated with mental disorders, including anorexia nervosa (AN), attention-deficit hyperactivity disorder (ADHD), autism spectrum disorder (ASD), bipolar disorder (BD), major depressive disorder (MDD), obsessive-compulsive disorder (OCD), panic disorder (PD), posttraumatic stress disorder (PTSD), schizophrenia (SCZ), and tourette syndrome (TS), were all extracted from the Psychiatric Genomics Consortium (PGC). The causal estimates and direction between these mental disorders and sepsis were evaluated employing a two-sample bidirectional MR strategy. The inverse variance weighted (IVW) method was the primary approach utilized. Various sensitivity analyses were performed to confirm the validity of the causal effect. Meta-analysis, multivariable MR, and mediation MR were conducted to ensure the credibility and depth of this research. Results: The presence of AN was in relation to a greater likelihood of sepsis (OR 1.08, 95% CI 1.02-1.14; p = 0.013). A meta-analysis including validation cohorts supported this observation (OR 1.06, 95% CI 1.02-1.09). None of the investigated mental disorders appeared to be impacted when sepsis was set as the exposure factor. Even after adjusting for confounding factors, AN remained statistically significant (OR 1.08, 95% CI 1.02-1.15; p = 0.013). Mediation analysis indicated N-formylmethionine levels (with a mediated proportion of 7.47%), cystatin D levels (2.97%), ketogluconate Metabolism (17.41%) and N10-formyl-tetrahydrofolate biosynthesis (20.06%) might serve as mediators in the pathogenesis of AN-sepsis. Conclusion: At the gene prediction level, two-sample bidirectional MR analysis revealed that mental disorder AN had a causal association with an increased likelihood of sepsis. In addition, N-formylmethionine levels, cystatin D levels, ketogluconate metabolism and N10-formyl-tetrahydrofolate biosynthesis may function as potential mediators in the pathophysiology of AN-sepsis. Our research may contribute to the investigation of novel therapeutic strategies for mental illness and sepsis.

Dual-Energy-Barrier Stable Superhydrophobic Structures for Long Icing Delay.

Using superhydrophobic surfaces (SHSs) with the water-repellent Cassie-Baxter (CB) state is widely acknowledged as an effective approach for anti-icing performances. Nonetheless, the CB state is susceptible to diverse physical phenomena (e.g., vapor condensation, gas contraction, etc.) at low temperatures, resulting in the transition to the sticky Wenzel state and the loss of anti-icing capabilities. SHSs with various micronanostructures have been empirically examined for enhancing the CB stability; however, the energy barrier transits from the metastable CB state to the stable Wenzel state and thus the CB stability enhancement is currently not enough to guarantee a well and appliable anti-icing performance at low temperatures. Here, we proposed a dual-energy-barrier design strategy on superhydrophobic micronanostructures. Rather than the typical single energy barrier of the conventional CB-to-Wenzel transition, we introduced two CB states (i.e., CB I and CB II), where the state transition needed to go through CB I and CB II then to Wenzel state, thus significantly improving the entire CB stability. We applied ultrafast laser to fabricate this dual-energy-barrier micronanostructures, established a theoretical framework, and performed a series of experiments. The anti-icing performances were exhibited with long delay icing times (over 27,000 s) and low ice-adhesion strengths (0.9 kPa). The kinetic mechanism underpinning the enhanced CB anti-icing stability was elucidated and attributed to the preferential liquid pinning in the shallow closed structures, enabling the higher CB-Wenzel transition energy barrier to sustain the CB state. Comprehensive durability tests further corroborated the potentials of the designed dual-energy-barrier structures for anti-icing applications.

Localized in-situ deposition: a new dimension to control in fabricating surface micro/nano structures via ultrafast laser ablation.

Controllable fabrication of surface micro/nano structures is the key to realizing surface functionalization for various applications. As a versatile approach, ultrafast laser ablation has been widely studied for surface micro/nano structuring. Increasing research efforts in this field have been devoted to gaining more control over the fabrication processes to meet the increasing need for creation of complex structures. In this paper, we focus on the in-situ deposition process following the plasma formation under ultrafast laser ablation. From an overview perspective, we firstly summarize the different roles that plasma plumes, from pulsed laser ablation of solids, play in different laser processing approaches. Then, the distinctive in-situ deposition process within surface micro/nano structuring is highlighted. Our experimental work demonstrated that the in-situ deposition during ultrafast laser surface structuring can be controlled as a localized micro-additive process to pile up secondary ordered structures, through which a unique kind of hierarchical structure with fort-like bodies sitting on top of micro cone arrays were fabricated as a showcase. The revealed laser-matter interaction mechanism can be inspiring for the development of new ultrafast laser fabrication approaches, adding a new dimension and more flexibility in controlling the fabrication of functional surface micro/nano structures.

1000 °C High-Temperature Wetting Behaviors of Molten Metals on Laser-Microstructured Metal Surfaces.

The melting of metals at high temperatures is common and important in many fields, e.g., metallurgy, refining, casting, welding, brazing, even newly developed batteries, and nuclear fusion, which is thus of great value in modern industrialization. However, the knowledge of the wetting behaviors of molten metals on various substrate surfaces remains insufficient, especially when the temperature is over 1000 °C and with microstructured metal substrate surfaces. Herein, we selected molten cerium (Ce) on a tantalum (Ta) substrate as an example and investigated in detail its wetting at temperatures up to 1000 °C by modulating the microstructures of the substrate surfaces via laser processing. We discovered that the wetting states of molten Ce on Ta surfaces at temperatures over 900 °C could be completely altered by modifying the laser-induced surface microstructures and the surface compositions. The molten Ce turned superlyophilic with its contact angle (CA) below 10° on the only laser-microstructured surfaces, while it exhibited lyophobicity with a CA of about 135° on the laser-microstructured plus oxidized ones, which demonstrated remarkably enhanced resistance against the melt with only tiny adhesion in this circumstance. In contrast, the CA of molten Ce on Ta substrate surfaces only changed from ∼25 to ∼95° after oxidization without laser microstructuring. We proved that modulating the substrate surface microstructures via laser together with oxidization was capable of efficiently controlling various molten metals' wetting behaviors even at very high temperatures. These findings not only enrich the understanding of molten metal high-temperature wettability but also enable a novel practical approach to control the wetting states for relevant applications.

Large-scale assembly of isotropic nanofiber aerogels based on columnar-equiaxed crystal transition.

Ice-templating technology holds great potential to construct industrial porous materials from nanometers to the macroscopic scale for tailoring thermal, electronic, or acoustic transport. Herein, we describe a general ice-templating technology through freezing the material on a rotating cryogenic drum surface, crushing it, and then re-casting the nanofiber slurry. Through decoupling the ice nucleation and growth processes, we achieved the columnar-equiaxed crystal transition in the freezing procedure. The highly random stacking and integrating of equiaxed ice crystals can organize nanofibers into thousands of repeating microscale units with a tortuous channel topology. Owing to the spatially well-defined isotropic structure, the obtained Al2O3·SiO2 nanofiber aerogels exhibit ultralow thermal conductivity, superelasticity, good damage tolerance, and fatigue resistance. These features, together with their natural stability up to 1200 °C, make them highly robust for thermal insulation under extreme thermomechanical environments. Cascading thermal runaway propagation in a high-capacity lithium-ion battery module consisting of LiNi0.8Co0.1Mn0.1O2 cathode, with ultrahigh thermal shock power of 215 kW, can be completely prevented by a thin nanofiber aerogel layer. These findings not only establish a general production route for nanomaterial assemblies that is conventionally challenging, but also demonstrate a high-energy-density battery module configuration with a high safety standard that is critical for practical applications.

Self-Driven Droplet Motions Below their Icing Points.

Liquid fluidity is a most key prerequisite for a broad range of technologies, from energy, fluid machineries, microfluidic devices, water, and oil transportation to bio-deliveries. While from thermodynamics, the liquid fluidity gradually diminishes as temperature decreases until completely solidified below icing points. Here, self-driven droplet motions are discovered and demonstrated occurring in icing environments and accelerating with both moving distances and droplet volumes. The self-driven motions, including self-depinning and continuous wriggling, require no surface pre-preparation or energy input but are triggered by the overpressure spontaneously established during icing and then continuously accelerated by capillary pulling of frosts. Such self-driven motions are generic to a broad class of liquid types, volumes, and numbers on various micro-nanostructured surfaces and can be facilely manipulated by introducing pressure gradients spontaneously or externally. The discovery and control of self-driven motions below icing points can greatly broaden liquid-related applications in icing environments.

Boosting water evaporation via continuous formation of a 3D thin film through triple-level super-wicking routes.

Capillary-fed thin-film evaporation via micro/nanoscale structures has attracted increasing attention for its high evaporation flux and pumpless liquid replenishment. However, maximizing thin-film evaporation has been hindered by the intrinsic trade-off between the heat flux and liquid transport. Here, we designed and fabricated nanostructured micro-steam volcanoes on copper surfaces featuring triple-level super-wicking routes to overcome this trade-off and boost water evaporation. The triple-level super-wicking routes enable the continuous formation of a 3D thin film for highly efficient evaporation by continuous self-driven liquid replenishment and extending the thin-film region. The micro-steam volcanoes increased the surface area by 225%, improving the evaporation rate by 141%, with a rapid self-pumping water transport speed up to 80 mm s-1. A remarkable solar-driven water evaporation rate of 3.33 kg m-2 h-1 under one sun vertical incidence was achieved, which is among the highest reported values for metal-based evaporators. When attached to electric-heating plates, the evaporator realized an electrothermal evaporation rate of 12.13 kg m-2 h-1. Moreover, it can also be used for evaporative cooling with enhanced convective heat transfer, reaching a 36.2 °C temperature reduction on a heat source with a heat flux of 6 W cm-2. This study promises a general strategy for designing thin-film evaporators with high efficiencies, low costs, and multi-functional compatibilities.

Passive Anti-Icing Performances of the Same Superhydrophobic Surfaces under Static Freezing, Dynamic Supercooled-Droplet Impinging, and Icing Wind Tunnel Tests.

Overcoming ice accretion on external aircraft wing surfaces plays a crucial role in aviation, and developing environmentally friendly passive anti-icing surfaces is considered to be a promising strategy. Superhydrophobic surfaces (SHSs) have attracted increasing attention due to their potential advantages of keeping the airframe dry without causing additional aerodynamic losses. However, the passive anti-icing performances of SHSs reported to date varied a lot under different icing test conditions. Therefore, a systematic investigation is necessary to elucidate the icing conditions where SHSs can remain effective and pave the way for SHSs toward practical anti-icing applications. Herein, we designed and fabricated a typical type of SHS featuring dual-scale hierarchical structures with arrayed micromountains (with both spacings and heights of tens of micrometers) covered by single-scale sandy-corrugation-like periodic structures (with both spacings and heights of only several micrometers) (termed SS1). Its anti-icing performances under three representative icing conditions, including static water freezing, dynamic supercooled-droplet impinging, and icing wind tunnel conditions, were comparatively investigated. The SS1 SHS maintained a lower static ice-adhesion strength (<60 kPa even after 50 deicing cycles at temperatures as low as -25 °C), which was attributed to a cumulative cracking effect facilitating the ice detachment. Within the laboratory dynamic icing tests, the SS1 SHSs with micromountain heights of 20-30 µm performed optimally in the antiadhesion of supercooled droplets (at an impinging velocity of 3.4 m/s and temperatures of -5 to -25 °C). In spite of the significant anti-icing performances of the SS1 SHSs in both static and dynamic laboratory tests, they could hardly sustain reliable passive anti-icing performances in harsher icing wind tunnel tests with supercooled droplets impinging their surfaces at velocities of up to 50 m/s at a temperature of -5 °C for 10 min. This study can inspire the development of improved SHSs for achieving satisfactory anti-icing performances in real-aviation conditions.

Crack-Initiated Durable Low-Adhesion Trilayer Icephobic Surfaces with Microcone-Array Anchored Porous Sponges and Polydimethylsiloxane Cover.

Reducing unfavorable ice accretion on surfaces exposed in cold environment requires effective passive anti-icing/deicing techniques. Icephobic surfaces are widely applied on various infrastructures due to their low ice adhesion strength and flexibility, whereas their poor mechanical durability, common liquid infusion, weak resistance to contamination, and low bonding strength to substrates are the major remaining challenges. According to the fracture mechanics of ice layer, initiating cracks at the ice-solid interfaces via the proper design of internal structures of icephobic materials is a promising way to icephobicity. Herein, a crack initiating icephobic surface with porous PDMS sponges sandwiched between a protective, dense PDMS layer and a textured metal microstructure was proposed and fabricated. The combination of high- and low- stiffness PDMS layers anchored by the structured metal surface give the sandwich-like structure excellent icephobicity with both high durability and low ice adhesion (5.3 kPa in the icing-deicing cycles). The porosity and the elastic modulus of the PDMS sponges and the periodicity of the metal surface structures can both be tailored to realize enhanced icephobicity. The sandwich-like icephobic surface remained insignificantly changed under solid particle impacting and the durability characterized via linear abrasion tests was elevated compared with PDMS coating on flat metal surfaces. Additionally, the trilayer icephobic surface possesses durability, low ice adhesion strength, and improved resistance to contamination and is applicable on various surfaces.

Superhydrophobic microstructures for better anti-icing performances: open-cell or closed-cell?

Based on geometrical characteristics, all surface microstructures are categorized into two types: closed-cell and open-cell structures. Closed-cell structures are well-known to have more stable and durable superhydrophobicity at room temperatures. However, in low-temperature environments where massive environmentally induced physical changes emerge, whether closed-cell surfaces can maintain good anti-icing performances has not yet been confirmed, and thus how to design optimal superhydrophobic anti-icing microstructures is rarely reported. Here, we apply an ultrafast laser to fabricate superhydrophobic surfaces with tunable patterned micro-nanostructures from a complete closed-cell to different ratios and to a complete open-cell. We discover that droplets on closed-cell structures completely degrade to the high-adhesion Wenzel state after icing and melting cycles while those on the open-cell structures well recover to the original Cassie-Baxter state. We propose an improved ideal gas model to clarify the mechanisms that the decreased air pocket pressure and the air dissolution on closed-cell structures induce easy impalement during icing and the difficult recovery during melting, paving the way for optimizing the anti-icing structure design. The optimized open-cell surfaces exhibit over 33 times lower ice adhesion strengths (1.4 kPa) and long-term icephobic durability (<20 kPa after 33 deicing cycles) owing to the increased air pocket pressure at low temperatures. Significant dewetting processes during condensation endow the open-cell structures with more remarkable high-humidity resistance and anti-frosting properties. Our study reveals the general design principle of superhydrophobic anti-icing structures, which might guide the design of superhydrophobic anti-icing surfaces in practical harsh environments.

Saving 80% Polypropylene in Facemasks by Laser-Assisted Melt-Blown Nanofibers.

The ongoing coronavirus (COVID-19) pandemic requires enormous production of facemasks and related personal protection materials, thereby increasing the amount of nondegradable plastic waste. The core material for facemasks is melt-blown polypropylene (PP) fiber. Each disposable facemask consumes ∼0.7 g of PP fibers, resulting in annual global consumption and disposal of more than 1 150 000 tons of PP fibers annually. Herein, we developed a laser-assisted melt-blown (LAMB) technique to manufacture PP nanofibers with a quality factor of 0.17 Pa-1 and significantly reduced the filter's weight. We demonstrated that a standard surgical facemask could be made with only 0.13 g of PP nanofibers, saving approximately 80% of the PP materials used in commercial facemasks. Theoretical analysis and modeling were also conducted to understand the LAMB process. Importantly, nanofibers can be easily scaled up for mass production by upgrading traditional melt blown line with scanning laser-assisted melt-blown (SLAMB).

Direct Patterning of Colloidal Nanocrystals via Thermally Activated Ligand Chemistry.

Precise patterning with microscale lateral resolution and widely tunable heights is critical for integrating colloidal nanocrystals into advanced optoelectronic and photonic platforms. However, patterning nanocrystal layers with thickness above 100 nm remains challenging for both conventional and emerging direct photopatterning methods, due to limited light penetration depths, complex mechanical and chemical incompatibilities, and others. Here, we introduce a direct patterning method based on a thermal mechanism, namely, the thermally activated ligand chemistry (or TALC) of nanocrystals. The ligand cross-linking or decomposition reactions readily occur under local thermal stimuli triggered by near-infrared lasers, affording high-resolution and nondestructive patterning of various nanocrystals under mild conditions. Patterned quantum dots fully preserve their structural and photoluminescent quantum yields. The thermal nature allows for TALC to pattern over 10 µm thick nanocrystal layers in a single step, far beyond those achievable in other direct patterning techniques, and also supports the concept of 2.5D patterning. The thermal chemistry-mediated TALC creates more possibilities in integrating nanocrystal layers in uniform arrays or complex hierarchical formats for advanced capabilities in light emission, conversion, and modulation.

Micro-Nano-Nanowire Triple Structure-Held PDMS Superhydrophobic Surfaces for Robust Ultra-Long-Term Icephobic Performance.

Anti-icing superhydrophobic surfaces have attracted tremendous interests due to their repellency to water and extremely low ice affinity, whereas the weak durability has been the bottleneck for further applications. Surface durability is especially important in long-term exposure to low-temperature and high-humidity environments. In this study, a robust micro-nano-nanowire triple structure-held PDMS superhydrophobic surface was fabricated via a hybrid process: ultrafast-laser-prepared periodic copper microstructures were chemically oxidized, followed by modification of PDMS. The hedgehog-like surface structure was composed of microcones, densely grown nanowires, and tightly combined PDMS. The capillary force difference in micro-nanostructures drove PDMS solutions to distribute evenly, bonding fragile nanowires to form stronger composite cones. PDMS replaced the commonly used fragile fluorosilanes and protected nanowires from breaking, which endowed the surfaces with higher robustness. The ductile PDMS-nanowire composites possessed higher resiliency than brittle nanowires under a load of 1 mN. The surface kept superhydrophobic and ice-resistant after 15 linear abrasion cycles under 1.2 kPa or 60 icing-deicing cycles under -20 °C or 500 tape peeling cycles. Under a higher pressure of 6.2 kPa, the contact angle (CA) was maintained above 150° until the abrasion distance exceeded 8 m. In addition, the surface exhibited a rare spontaneously optimized performance in the icing-deicing cycles. The ice adhesion strength of the surface reached its lowest value of 12.2 kPa in the 16th cycle. Evolution of surface roughness and morphology were combined to explain its unique U-shaped performance curves, which distinguished its unique degradation process from common surfaces. Thus, this triple-scale superhydrophobic surface showed a long-term anti-icing performance with high deicing robustness and low ice adhesion strength. The proposed nanostructure-facilitated uniform distribution strategy of PDMS is promising in future design of durable superhydrophobic anti-icing surfaces.

Anisotropic Hemiwicking Behavior on Laser Structured Prismatic Microgrooves.

The wicking phenomenon, including wicking and hemiwicking, has attracted increasing attention for its critical importance to a wide range of engineering applications, such as thermal management, water harvesting, fuel cells, microfluidics, and biosciences. There exists a more urgent demand for anisotropic wicking behaviors since an increasing number of advanced applications are significantly complex. For example, special-shaped vapor chambers and heating atomizers in some electronic cigarettes need liquid replenishing with various velocities in different directions. Here, we report two-dimensional anisotropic hemiwicking behaviors with elliptical shapes on laser structured prismatic microgrooves. The prismatic microgrooves were fabricated via one-step femtosecond laser direct writing, and the anisotropic hemiwicking behaviors were observed when utilizing glycerol, glycol, and water as the test liquid. Specifically, the ratios of horizontal wicking distance in directions along short and long axes were tan 0°, tan 15°, tan 30°, and tan 45° for samples with cross-angles of 0°, 30°, 60°, and 90°, respectively. The vertical water wicking front displayed corresponding angles under the guidance of laser structured prismatic microgrooves. Theoretical analysis shows that the wicking distance is mainly dependent on the cross-angle θ and surface roughness, in which the wicking distance is proportional to cos(θ/2). Driven by the capillary pressure forming in the narrow microgrooves, the liquid initially filled the valleys of microgrooves and then surrounded and covered the prismatic ridges with laser-induced nanoparticles. The abundant nanoparticles increased the surface roughness, leading to the enhancement of wicking performance, which was further evidenced by the larger wicking speed of the sample with more nanoparticles. The mechanism of anisotropic hemiwicking behaviors revealed in this work paves the way for wicking control, and the proposed prismatic microgrooved surfaces with two-dimensional anisotropic hemiwicking performance and superhydrophilicity could serve in a broad range of applications, especially for the advanced thermal management with specific heat load configurations.

Diagnostic Accuracy of Serum Amyloid A in Acute Appendicitis: A Systematic Review and Meta-Analysis.

Background: Serum amyloid A has been widely reported as a useful biochemical marker in the diagnoses of acute appendicitis. The aim of this study was to appraise the diagnostic accuracy of serum amyloid A in the diagnosis of acute appendicitis. Methods: A systematic search of several databases was conducted. The search time was from the beginning of the databases creation to March 1, 2021, and the languages were restricted to English and Chinese. Clinical studies using serum amyloid A for the diagnosis of acute appendicitis were included. The overall sensitivity and specificity were calculated by using a bivariable mixed effects model. Heterogeneity was tested using I2 statistics. This study has been registered on the International Prospective Register of Systematic Reviews (PROSPERO; no. CRD42021241343). Results: Five studies comprising 668 participants were eligible for inclusion. The overall sensitivity and specificity of serum amyloid A in diagnosing acute appendicitis were 0.87 (95% confidence interval [CI], 0.79-0.92) and 0.74 (95% CI, 0.59-0.85), respectively. The positive and negative likelihood were 3.3 (95% CI, 2.1-5.4) and 0.18 (95% CI, 0.11-0.28), respectively. The area under the summary receiver operating characteristic curves was 0.89 (95% CI, 0.86-0.91). The heterogeneity was significant (I2 = 82%; 95% CI [63%-100%]). Conclusions: Serum amyloid A has good diagnostic accuracy for acute appendicitis. It is expected that serum amyloid A could be helpful in the early clinical diagnosis of acute appendicitis.

Spontaneous dewetting transitions of droplets during icing & melting cycle.

Anti-icing superhydrophobic surfaces have been a key research topic due to their potential application value in aviation, telecommunication, energy, etc. However, superhydrophobicity is easily lost during icing & melting cycles, where the water-repellent Cassie-Baxter state turns to the sticky Wenzel state. The reversible transition during icing & melting cycle without external assistance is challenging but vital for reliable anti-icing superhydrophobic performance, such a topic has rarely been reported. Here we demonstrate a spontaneous Wenzel to Cassie-Baxter dewetting transition during icing & melting cycle on well-designed superhydrophobic surfaces. Bubbles in ice droplets rapidly impact the micro-nano valleys under Marangoni force, prompting the continuous recovery of air pockets during melting processes. We establish models to confirm the bubbles movement broadens the dewetting conditions greatly and present three criteria for the dewetting transitions. This research deepens the understanding of wettability theory and extends the design of anti-icing superhydrophobic surfaces.

Nanosecond Laser Cleaning Method to Reduce the Surface Inert Layer and Activate the Garnet Electrolyte for a Solid-State Li Metal Battery.

The garnet-type electrolyte Li6.4La3Zr1.4Ta0.6O12 (LLZTO) has been widely researched for its high ionic conductivity and excellent stability against the Li anode. However, the garnet electrolyte is susceptible to CO2 and H2O in air to form a Li2CO3 insulating layer leading to poor wettability with the Li anode, which hinders its practical application. Herein, we introduced a simple method to effectively reduce the Li2CO3 layer on the garnet electrolyte surface by laser cleaning and made the garnet surface back with lithiophilicity. The resulting Li/garnet interfacial resistance decreased to 76.4 Ω·cm2 at 30 °C and 3.1 Ω·cm2 at 80 °C. The assembled Li symmetric cell with the as-laser-treated electrolyte steadily cycled for 300 h under 0.1 and 0.2 mA·cm-2 at 80 °C. The solid-state battery coupled with the composite LiFePO4 cathode and the Li anode exhibited stable long-term cycling performance for over 100 cycles with a capacity retention of 84.8%. This work provided a novel method to reduce the surface inert layer and make the garnet electrolyte reveal the intrinsic lithiophilicity by laser cleaning process with high efficiency, which helped address the challenges for the application of garnet-based solid-state batteries.

Directional anchoring patterned liquid-infused superamphiphobic surfaces for high-throughput droplet manipulation.

High-throughput experiments involving isolated droplets based on patterned superwettable surfaces are important for various applications related to biology, chemistry, and medicine, and they have attracted a large amount of interest. This paper provides a directional anchoring liquid-infused superamphiphobic surface (DAS), via combining concepts based on the droplet-anchoring behavior of beetle backs with patterned wettability, the directional adhesion of butterfly wings, and the slippery liquid-infused surfaces (SLISs) of pitcher plants. Regularly arranged ">"-shaped SLIS patterns were created on a superamphiphobic (SAM) background through ultrafast-laser-based technology. Improved directional anchoring abilities with a sliding angle difference of 77° were achieved; this is the largest sliding angle difference in a one-dimensional direction achieved using an artificial surface, to the best of the authors' knowledge. Thanks to the directional anchoring abilities, the DAS coupled droplet 'anchoring' and 'releasing' abilities. Furthermore, a high-throughput droplet manipulation device was designed, on which a micro-droplet array with a large number of droplets can be 'captured', 'transferred', or 'released' in a single step. With the addition of lubricant, the DAS can work continuously for even more than 30 cycles without cross-contamination between different droplets. The DAS also shows good stability under an ambient atmosphere and can maintain its functionality when manipulating corrosive droplets. The DAS and corresponding high-throughput droplet manipulation method are excellent candidates for practical applications.

Triple-Scale Superhydrophobic Surface with Excellent Anti-Icing and Icephobic Performance via Ultrafast Laser Hybrid Fabrication.

Passive anti-icing or icephobic superhydrophobic surfaces have attracted great interest due to their potential multifaceted implications for the prevention and/or easy removal of undesired ice in many applications. However, a superhydrophobic surface with both excellent anti-icing and icephobic performances has rarely been reported due to difficulties in sustaining a good Cassie state stability. This is the case especially under high humidity and freezing environment conditions. In the present study, a new triple-scale micro/nanostructured superhydrophobic surface with both excellent anti-icing and icephobic properties has been designed via a hybrid method, combining ultrafast laser ablation and chemical oxidation. The novel surface structure is composed of periodical microcone arrays covered with densely grown nanograsses and dispersedly distributed microflowers. This surface exhibits an excellent Cassie state stability with its critical Laplace pressure reaching up to 1450 Pa, which is essential for good anti-icing and icephobic performances. The anti-icing feature of the prepared superhydrophobic surface is achieved by a rapid rolling-off of the impacting droplets. Moreover, an excellent resistance to the impact of high humidity has been achieved via hierarchical condensation, coalescence-induced jumping, and upward moving. A good delay of the heterogeneous nucleation at the solid-liquid interface under freezing condition has been registered as well, due to the presence of stable air pockets within the surface structures. In addition, the ice adhesion strength of the prepared superhydrophobic surface can be as low as 1.7 kPa, which is the lowest value when compared with the state-of-the-art superhydrophobic surfaces. Such a low ice adhesion strength allows the ice to be easily removed by its own weight and demonstrates an excellent icephobic performance. The repeated icing-deicing tests indicate a decent deicing robustness of the synthesized superhydrophobic surface. Thus, this triple-scale superhydrophobic surface exhibits a good anti-icing and icephobic performance with an excellent Cassie state stability, high humidity resistance, and good deicing durability. We hypothesize that the proposed fabrication strategy and associated basic findings will shed new light on the design of robust ice-resistant superhydrophobic surfaces and contribute to a better understanding of the relationship between superhydrophobicity and ice resistance.