Photocatalyzed hydrodecarboxylation of fatty acids: a prospective method to produce drop-in biofuels.

A direct and practical method for photocatalyzed hydrodecarboxylation of fatty acids is reported herein. The catalytic system consists of a commercially available acridinium salt as the photocatalyst and thiophenol as the Hydrogen Atom Transfer (HAT) co-catalyst. Results evidenced that Cn-1 alkanes were obtained in yields up to 77%. Furthermore, the protocol was employed for a complex mixture of fatty acids bio-derived from a real sample of licuri oil to obtain hydrocarbons in the range of C9-C17 with high selectivity and excellent conversion (>90%). This work provides a powerful strategy for producing drop-in biofuels under mild conditions. Finally, an energetic assessment of our proposed protocol (∼22.9 kW h) reveals the benefit of a sustainable production of renewable hydrocarbons.

Nickel-catalyzed reductive decarboxylation of fatty acids for drop-in biofuel production.

An operationally simple and highly selective method for the decarboxylation of fatty acids under remarkably mild conditions is described herein. The activation of the aliphatic carboxylic acids by esterification with N-hydroxyphthalimide (NHPI) enabled efficient deoxygenation to synthesize n-alkanes in up to 67% yield, employing inexpensive PMHS as a hydrogen source, NiCl2·6H2O, bipyridine, and zinc in THF. In contrast to the conventional thermo-catalytic approaches, this protocol does not require high temperature and high pressure of hydrogen gas to deoxygenate biomass-derived carboxylic acids, thus representing an attractive alternative for producing drop-in biofuels.