Humic acid-coated hydrated ferric oxides-polymer nanocomposites for heavy metal removal in water.

Water pollution by toxic heavy metals poses a threat to the environment and human bodies. Herein, a novel hydrated ferric oxide nanoparticle (HFO) based hybrid adsorbent was fabricated for the removal of toxic Cu(II), Cd(II) and Pb(II) from water. HFOs were immobilized into a porous resin D-201, and then this nanocomposite HFO-D201 was coated with humic acid (HA) to enhance the binding sites of target metals. Both HFOs and HA contribute to the sequestration of heavy metals. The as-synthesized hybrid adsorbent HA-HFO-D201 exhibited excellent performance on the removal of Cu(II), Cd(II), and Pb(II) in a pH range of 3-9, while no Fe leaching was observed. The presence of natural organic matter (20 mg C/L) has limited influences on the adsorption, and more than 85% of the target metals can be removed after treatment. HA-HFO-D201 showed preferable adsorption toward Cu(II) and Pb(II) (1 mg/L) from the background Ca2+ solution at much higher concentrations (100 mg/L), while the retention of Cd(II) (1 mg/L) decreased to some extent. Fixed-bed column experiments exhibited that the treatment capacities of HA-HFO-D201 are 90 bed volumes (BV) for Cd(II), 410 BV for Pb(II) and > 800 BV for Cu(II) of simulated contaminated water to meet the WHO drinking water standard. Meanwhile, depleted HA-HFO-D201 can be readily regenerated by a chelating agent Na2EDTA for repeated use. The hybrid adsorbent HA-HFO-D201 has excellent potential to remove heavy metals in water treatment systems.

Effective and simultaneous removal of organic/inorganic arsenic using polymer-based hydrated iron oxide adsorbent: Capacity evaluation and mechanism.

In this study, resin-based hydrated iron oxide (HFOR) composites were prepared and used as a functional adsorbent for the simultaneous removal of p-Arsanilic acid (p-ASA) and arsenate (As (V)). The effects of solution pH and coexisting substances on the adsorption of different arsenic species were also investigated. Results showed that the coexisting substances slightly affected the adsorption process of two arsenic species. Analysis of the adsorption behavior, isotherm equilibrium, and adsorption kinetics, as well as that results of the X-ray photoelectron spectroscopy, zeta potential, and other analytical methods revealed that the satisfactory adsorption performance of HFOR can be attributed to the electrostatic interactions induced by the positively charged groups and the coordination of the hydrated iron oxide nanoparticles, which exhibited excellent specific adsorption for both arsenic species. Moreover, HFOR showed high acid and alkali resistance and reusability, as well as a constant co-removal performance for different arsenic species in five consecutive operating cycles (55 mg As/g of As(V) and 18 mg/g of p-ASA). Results of continuous running fixed-bed column experiments confirmed that HFOR enabled excellent simultaneous adsorption for p-ASA and As(V).

Polymeric ion exchanger supported ferric oxide nanoparticles as adsorbents for toxic metal ions from aqueous solutions and acid mine drainage.

BACKGROUND: Acid mine drainage (AMD) is a worldwide industrial pollution of grave concern. AMD pollutes both water sources and the environment at large with dissolved toxic metals which are detrimental to human health. This paper reports on the preparation of polymeric ion exchange resins decorated with hydrated iron oxides and their application for the ecological removal of toxic metals ions from AMD. METHODS: The hydrated iron oxide particles were incorporated within commercial chelating ion exchange resins using the precipitation method. The synthesised hybrid resins were then characterized using appropriate spectroscopic and solid-state techniques. The metal ion levels were measured using the inductively coupled plasma-optical emission spectrometer (ICP-OES). The optimization of contact time, pH, and adsorbent dosage were conducted to enhance the efficiency of adsorption of toxic metals onto the hybrid organic/inorganic nanosorbents. Kinetics and adsorption isotherms were constructed to study the adsorption mechanisms of the adsorbents. RESULTS: The results showed that the dispersed Fe-O is hydrated and amorphous within the hybrid materials. The adsorption kinetics followed the pseudo-second-order shown by the high R2 values. The hybrid adsorbents were finally tested on environmental AMD samples and were able to remove toxic metals Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn at various removal degrees. CONCLUSION: Solution pH played a crucial role in the adsorption of toxic metals on hybrid iron oxide adsorbents. The hybrid TP-260 HFO had higher affinity for toxic metals than other prepared adsorbents thus has a potential for acidic mine water pollution remediation. The adsorbed Al(III) can be recovered using NaCl-NaOH binary solution from the loaded resins.