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1.
Polymers (Basel) ; 14(10)2022 May 11.
Article in English | MEDLINE | ID: mdl-35631828

ABSTRACT

Geopolymer foams are excellent materials in terms of mechanical loads and fire resistance applications. This study investigated the foaming process of geopolymers and foam stability, with a focus on the fire resistance performance when using polystyrene as the base layer. The main purpose is to define the influence of porosity on the physical properties and consequently to find applications and effectiveness of geopolymers. In this study, lightweight materials are obtained through a process called geopolymerization. Foaming was done by adding aluminum powder at the end of the geopolymer mortar preparation. The interaction between the aluminum powder and the alkaline solution (used for the binder during the mixing process) at room temperature is reactive enough to develop hydrogen-rich bubbles that increase the viscosity and promote the consolidation of geopolymers. The basic principle of thermodynamic reactions responsible for the formation of foams is characterized by hydrogen-rich gas generation, which is then trapped in the molecular structure of geopolymers. The geopolymer foams in this study are highly porous and robust materials. Moreover, the porosity distribution is very homogeneous. Experimental assessments were performed on four specimens to determine the density, porosity, mechanical strength, and thermal conductivity. The results showed that our geopolymer foams layered on polystyrene boards (with optimal thickness) have the highest fire resistance performance among others. This combination could withstand temperatures of up to 800 °C for more than 15 min without the temperature rising on the insulated side. Results of the best-performing geopolymer foam underline the technical characteristics of the material, with an average apparent density of 1 g/cm3, a volume porosity of 55%, a thermal conductivity of 0.25 W/mK, and excellent fire resistance.

2.
Polymers (Basel) ; 13(5)2021 Feb 28.
Article in English | MEDLINE | ID: mdl-33670951

ABSTRACT

This paper presents an experimental research on the mechanical properties of the hybrid composite thin-plates of the short basalt fibers (CBFs)/carbon textile-reinforced geomortar. The effect of fiber contents and lengths of CBFs on the flexural behavior of carbon textile-reinforced geopolymer specimens (TRGs) was investigated by the four-point flexural strength and Charpy impact test. The experimental results of hybrid TRGs, on the one hand, were compared with reference TRGs, without CBF addition; on the other hand, they were compared with the results of our previous publication. According to the mixing manner applied, fresh geomortar indicated a marked reduction in workability, increasing the CBF loading. Furthermore, using CBFs with lengths of 12 mm and 24 mm makes it easy to form the fiber clusters in geomortar during mixing. According to all the CBF loadings used, it was found that TRGs showed a significant improvement in both static and dynamic flexural strength. However, the failure mode of these TRGs is similar to that of the reference TRGs, described by the process of fiber debonding or simultaneously fiber debonding and collapse. In comparison with our prior work results, neither the CBF dose levels nor the fiber lengths used in this work have yielded a positive effect on the failure manner of TRGs. According to the results of the Charpy impact test, this reveals that the anchoring capacity of textile layers in geomortar plays an important role in specimens' strength.

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