Magnetite-Incorporated 1D Carbon Nanostructure Hybrids for Electromagnetic Interference Shielding.

The increasing reliance on electronic technologies has elevated the urgency of effective electromagnetic interference (EMI) shielding materials. This review explores the development and potential of magnetite-incorporated one-dimensional (1D) carbon nanostructure hybrids, focusing on their unique properties and synthesis methods. By combining magnetite's magnetic properties with the electrical conductivity and mechanical strength of carbon nanostructures such as carbon nanotubes (CNTs) and carbon fibers (CFs), these hybrids offer superior EMI shielding performance. Various synthesis techniques, including solvothermal synthesis, in situ growth, and electrostatic self-assembly, are discussed in detail, highlighting their impact on the structure and properties of the resulting composites. This review also addresses the challenges in achieving homogeneous dispersion of nanofillers and the environmental and economic considerations of large-scale production. The hybrid materials' multifunctionality, including enhanced mechanical strength, thermal stability, and environmental resistance, underscores their suitability for advanced applications in aerospace, electronics, and environmental protection. Future research directions focus on optimizing synthesis processes and exploring new hybrid configurations to further improve electromagnetic properties and practical applicability.

Checklist of marine macroalgae in two contiguous Marine Protected Areas in the south-western Atlantic.

Background: The Costa das Algas Environmental Protection Area (EPA) and the Santa Cruz Wildlife Refuge (WR), located in the Espírito Santo Continental Shelf, Brazil, are outstanding marine protected areas due to their high biodiversity, particularly of macroalgae. Together, these two relatively small protected areas (1,150 and 177 km2, respectively) harbour about a quarter of all macroalgal species recorded in Brazil.The checklist presented herein updates the algal flora of these two protected areas with data obtained until 2019. Two hundred and sixty-five macroalgal taxa were recorded, most of which with vouchers. Checklists based on the collections of each protected area were published on: "Catálogo de Plantas das Unidades de Conservação do Brasil" (https://catalogo-ucs-brasil.jbrj.gov.br/). New information: Besides specimens collected between 2018 and 2019, the algal flora presented herein includes previous records from different Brazilian herbaria (e.g., SP, SPF, ALCB). Herbaria records may include species that do not occur in intertidal reefs (e.g., Laminaria). Overall, 249 macroalgal taxa and one marine angiosperm were recorded in the Costa das Algas EPA (87 new records) and 136 macroalgal taxa and one marine angiosperm in the Santa Cruz WR (46 new records). All taxa are native to Brazil and nine are endemic to Brazil. Our results provide a taxonomic foundation to support management, long-term monitoring and conservation in these protected areas.

Does environmental regulation promote enterprise environmental protection investments? A quasi-natural experiment from river chief system in the Yangtze river delta of China.

The investment decisions of enterprises are affected by environmental regulations designed to protect the environment, so environmental regulations may change companies' investment behavior in environmental protection. This study focuses on the River Chief System (RCS)1, an innovative environmental regulation related to river governance which officially launched in China in 2014. Based on data collected from heavy-polluting companies in the Yangtze River Delta, we use the difference-in-differences model (DID Model)2 and focus on RCS's impacts on micro-environmental protection investments. Our findings reveal that the RCS is conducive to expanding the scale of enterprises' environmental protection investments. Industrial structural upgrades appear to have a masking effect wherein the one-sided pursuit of industrial structural upgrades may slow economic growth and cause enterprises to reduce the scale of environmental investments. We recommend that the allocation of environmental investment should be based on the characteristics of local markets and public participation, and maintain a balance between secondary and tertiary industries, government and business incentives.

Improve carbon emission efficiency: What role does the ESG initiatives play?

Driven by the "dual carbon" goal, it is essential to investigate whether companies can enhance carbon emission efficiency by improving Environmental, Social, and Governance (ESG) performance. This study investigates the relationship between ESG ratings and carbon emission efficiency among Chinese A-share listed companies. The study reveals that a higher ESG rating significantly improves carbon efficiency. Mechanism studies indicate that the effect of ESG mainly comes from easing financing constraints, promoting green innovation, and strengthening supervision. Additionally, the study finds that the impact of ESG on carbon emission efficiency is more pronounced in non-heavy polluting and non-state-owned enterprises. Economic policy uncertainty diminishes the positive effects of ESG initiatives on carbon efficiency, while enhanced governmental concerns to environmental significantly bolsters these impacts. This paper offers empirical insights that can inform adjustment of policies concerning ESG performance and carbon emission.

Research on the Application of New Building Recycled Insulation Materials for Walls.

In this paper, a new type of recycled polyurethane material is used as a new type of wall insulation material, and the new building insulation wall made of this paper has high efficiency thermal insulation and energy-saving characteristics and also has certain environmental significance. The thermal conductivity of the new building cold insulation recycled polyurethane material is 0.023 W/(m·K), and the thermal conductivity of the new building insulation wall prepared is 0.297 W/(m·K). Compared with traditional double-sided plastered porous wall tiles, it can save 85.4% of energy consumption per square meter, with higher thermal insulation characteristics and economic benefits. The preparation of a new type of building insulation wall proposed in this paper provides a new and green way for wall insulation.

Harnessing coal and coal waste for environmental conservation: A review of photocatalytic materials.

Fossil fuels, especially coal, have played a pivotal role in driving technological and economic advancements over the past century, though accompanied by numerous environmental challenges. Rapid progress in green and sustainable energy sources, including tidal, wind, and solar energy, coupled with growing environmental concerns, the conventional coal industry is experiencing a sustained decline in both size and financial viability. This situation necessitates the urgent adoption of advanced approaches to coal utilization. Beyond serving as an energy source, coal and its by-products, known as coal waste, can serve as valuable resources for the development of advanced materials, including photocatalysts. The advancement of photocatalytic materials derived from coal and coal waste can capitalize on these natural carbon and mineral sources, providing a viable solution to numerous environmental challenges. Currently, research in this domain remains in its early stages, with existing studies primarily focusing on specific types of photocatalysts or particular aspects of the fabrication process. Therefore, available coal-based and coal waste-based photocatalytic materials were systematically examined and categorized into six types according to their composition and dimensional/structural characteristics. Each type of photocatalytic material was introduced, along with common fabrication and characterization technologies. Representative works were discussed in detail to highlight the unique features of different types of coal-based and coal waste-based photocatalytic materials. Furthermore, the promising applications of these materials in environmental protection and pollution treatment were summarized, while also addressing the challenges and prospects in this research field. This review comprehensively overviews the fundamental knowledge and recent advancements in photocatalytic materials derived from coal and coal waste, with the goal of catalyzing the development of next generation photocatalysts and contributing to the transformation of the conventional coal industry.

Environmental judicial reform and corporate investment behavior - Based on a quasi-natural experiment of environmental courts.

Ensuring the effectiveness of environmental legislation and regulations necessitates enhancing the professional caliber of the environmental judiciary. Utilizing a multi-period difference-in-differences model, we explore the impact of environmental judicial reforms, exemplified by the establishment of environmental courts, on corporate investment behavior. We find that firms in regions with established environmental courts significantly increase their environmental investments and productive investments, while financial investments remain unaffected. Mechanism testing reveals that the environmental court affects corporate investment by strengthening local government environmental enforcement and promoting public environmental participation. Furthermore, the marginal effect of environmental courts is more pronounced in regions with fewer environmental regulations and lower economic development levels, as well as in state-owned enterprises. Compared to collegiate benches, environmental resources judicial tribunals exert a greater influence on corporate investment behavior. This study adds to the micro-economic analysis of environmental judiciary by providing empirical evidence on how formal institutional frameworks impact corporate investment behavior.

Does it pay for firms to adopt environmental protection devices? An empirical examination in Cameroon.

The decision to adopt environmental protection policies within companies is faced with the fear of negative repercussions on performance. The aim of this paper is to analyse the effect of adopting environmental protection measures on the performance of VSEs in the tertiary sector in Cameroon. The use of linear models and matching methods such as Propensity Score Matching (PSM) and Multivariate Distance Matching (MDM) reveals a positive influence on performance. However, not all environmental protection measures produce such an effect. When the channel of influence is checked, structural equation models of the path analysis type show that costs are a non-negligible transmission channel. However, a difference in the mechanism of action depending on the device adopted is found. An analysis of the heterogeneity of the effect of adopting environmental protection measures shows that the effect is not identical according to the number of years in business and the size of the company. The results of building a region-sectoral instrument applied to the IV method attest to the robustness of our results. The study encourages companies to behave in an environmentally friendly way and confirms the need for public authorities to support them without forcing them to do so.

Positive impacts of green finance on environmental protection investment: Evidence from green finance reform and innovations pilot zone.

After long-term development, the global economic level has improved significantly, but environmental issues generated by early extensive development seriously threaten the survival of human beings. China, in particular, urgently needs to promote sustainable development through green finance policies. For this reason, this paper regards the 2017 eight pilot zones in five provinces for green finance reform and innovations (GFRIs) as a quasi-natural experiment, and explores whether it can encourage investment in environmental protection in heavily polluting enterprises by using difference-in-differences-in-differences (DDD) model. The paper finds that: First, GFRIs can bolster investment in environmental protection in heavy polluting enterprises. The results remain consistent after several robustness checks, covering the placebo test, PSM-DID test and so on. Second, mechanism tests find that the policy promotes environmental protection investment by alleviating financing constraints and cutting financing costs. Third, heterogeneity analysis shows that the promotion effect of GFRIs on environmental protection investment is more pronounced for provinces with higher percentages of secondary industry GDP, large-scale enterprises, and enterprises with better ESG management. This paper demonstrates the beneficial influence of GFRIs on promoting the transformation of heavy polluting enterprises and provides suggestions for the improvement of such policies.

Investigation of environmental ethics, spiritual health, and its relationship with environmental protection behaviors in nursing students.

Objective: To investigate the relationship between environmental ethics, spiritual health, and environmental behavior among nursing students. Methods: In this cross-sectional study, 200 iranian students from the Chabahar Nursing School were selected using a simple random sampling method. The data collection tool included a questionnaire on demographic information, knowledge, attitudes and behaviors towards the environment, environmental ethics, and spiritual health. Partial least squares structural equation modeling (PLS-SEM) was utilized to evaluate the conceptual framework in this study. Results: The mean score for environmental ethics among nursing students was 65.73±10.61 out of 100. Most of the students (47%) had desirable environmental ethics. The knowledge structure (ß=0.46) predicted attitude. The attitude structure also predicted environmental behavior (ß=0.28) and spiritual health (ß=0.31). Ultimately, the results showed that spiritual health and environmental ethics predict environmental behavior directly and indirectly (p<0.001). Conclusion: Spiritual health and environmental ethics were strong predictors of environmental behavior. Therefore, it is necessary to take into account not only students' spiritual health but also their ethical behaviors to promote environmental protection behaviors in the future.

Ladle slag-based binder for the solidification/stabilization of heavy-metal-rich industrial waste.

Heavy metal pollution from industrial sources is a major environmental and health hazard on a global scale. This study introduces a solidification/stabilization method of industrial waste using a waste-based, ettringite-rich solid binder from ladle slag and gypsum for the immobilization of an industrial waste material with extremely high contents of several heavy metals. The importance of sulfate and water content on the immobilization efficiency and the use of citric acid to increase the processing time of the binder were studied. The leaching of Pb, Hg, Se, As, Cd, Cu, and Ni was measured, and X-ray powder diffraction, field-emission scanning electron microscopy, and field-emission electron probe microanalysis combined with wavelength-dispersive X-ray spectroscopy were used to analyze the structure of the hardened binder and the location of the heavy metals within. The study shows that the ladle slag/gypsum binder is suitable for the solidification/stabilization of heavy-metal-rich solid industrial waste. Hg, As, Cd, Cu, and Ni were fully immobilized in all scenarios covered in the study, whereas Pb and Se showed more complicated behaviors. The main immobilization method was encapsulation, and partial Se incorporation into ettringite was observed. The presence of citric acid increased the processing time of the binder without harming the immobilization, unless combined with low sulfate content.

How does environmental regulations affect digital green innovation of high-pollution enterprises? Empirical evidence from China.

Digital green innovation (DGI) is crucial for high-pollution enterprises to improve green performance. However, there is a paradox regarding the impact of environmental regulations on DGI, primarily due to the varied effects of diverse regulatory tools. To resolve this paradox, based on Neoclassical Economics and the Porter Hypothesis, we empirically examine the influence of heterogeneous environmental regulations on DGI using a sample of high-pollution enterprises in China. The conclusions indicate that environmental protection tax has a pushing-forward effect on DGI, while environmental protection subsidy has a crowding-out effect. Moreover, enterprises' resource base and technological innovation capability positively moderate the impact of environmental protection tax. External pressure, internal incentives, pandering to governments, and managerial opportunism have mediating effects. Our research offers a new perspective to resolve the paradox of the effect of environmental regulations on DGI, explores potential mechanism as well as boundary condition, and proposes a new way of measuring DGI of enterprises with patents. Accordingly, we offer valuable policy recommendations about the formulation of environmental regulations, the facilitation of DGI, and the advancement of China's ecological civilization.

Spatial and temporal distribution characteristics of dust concentration based on satellite in mining area.

The spatial and temporal distribution patterns of dust concentration in the Pingshuo mining area and urban area were analyzed utilizing satellite data. The results indicate that the correlation coefficients of the average PM2.5 and PM10 concentration retrieved by satellite in Shuozhou City are 0.88 and 0.63, respectively, and the satellite inversion data demonstrate high reliability. The spatial distribution of dust concentration in the Pingshuo Mine area is elevated during winter and spring, with significant dust accumulation in winter. The pollution phenomenon in the Pingshuo mining area was pronounced from January to March, and the air quality deteriorated significantly. The correlation analysis of dust concentration between the city and the mining area reveals a marked spatial discontinuity at the boundary between the city and the mining area, indicating that the mining area is not the primary cause of the increase of dust concentration in the urban area, and changes in dust concentration within the mining area exert no significant impact on the urban area. The research results possess significant implications for dust control in both the mining and urban areas.

Driving Factors Influencing the Decision to Purchase Plant-Based Beverages: A Sample from Türkiye.

In recent years, the trend toward plant-based beverages has continued to grow rapidly. This study aimed to assess the effects of sociodemographic characteristics and knowledge about plant-based beverages, subjective norms, perceived price, environmental protection, animal welfare, availability, and trust on attitudes and buying behavior toward these products. This study was conducted online using a two-part questionnaire prepared by considering the literature. This study included 935 participants, and our findings confirmed that the variable of environmental protection affects the attitude toward these products (ß= 0.095; p = 0.007). Furthermore, gender, income level, lactose intolerance, and bloating due to cow's or sheep's milk influenced actual buying behavior (p < 0.05; p < 0.001). These findings indicate that people's increased environmental protection awareness will positively influence attitudes towards plant-based beverages and that individuals who do not experience lactose intolerance and bloating due to cow's or goat's milk will have lower actual buying behavior. It was also determined that individuals with lower incomes bought more plant-based beverages. In conclusion, plant-based beverage marketers need to take into account individuals' sociodemographic characteristics and environmental protection awareness when planning their marketing strategies.

Performance improvement of polyethersulfone membranes with Ti3AlCN MAX phase in the treatment of organic and inorganic pollutants.

In this work, the hydrophobic polyethersulfone (PES) membrane was modified by incorporating Ti3AlCN MAX phase. Synthesis of Ti3AlCN MAX phase was performed using the reactive sintering method. The scanning electron microscopy (SEM) images showed a 3D compressed layered morphology for the synthesized MAX phase. The Ti3AlCN MAX phase was added to the casting solution, and the mixed-matrix membranes were fabricated by the non-solvent induced phase inversion method. The performance and antifouling features of bare and modified membranes were explored by pure water flux, flux recovery ratio (FRR), and fouling resistance parameters. Through the modification of membranes by introducing the Ti3AlCN MAX phase, the enhancement of these features was observed, in which the membrane containing 1 wt% of MAX phase showed 17.7 L/m2.h.bar of permeability and 98.6% for FRR. Also, the separation efficiency of all membranes was evaluated by rejecting organic and inorganic pollutants. The Ti3AlCN MAX membranes could reject 96%, 95%, and 88% of reactive blue 50, Rose Bengal, and azithromycin antibiotics, respectively, as well as 98%, 80%, 86%, and 36% of Pb2+, As5+, Na2SO4, and NaCl, respectively. Finally, the outcomes indicated the Ti3AlCN MAX phase was an excellent and efficient novel additive for modifying the PES membrane.

Sludge reduction and hydrogen production in a microbial photoelectrochemical cell with a g-C3N4/CQDs/BiOBr composite photocathode.

Hydrogen (H2) remains a pivotal clean energy source, and the emergence of Solar-powered Microbial Photoelectrochemical Cells (MPECs) presents promising avenues for H2 production while concurrently aiding organic matter degradation. This study introduces an MPEC system employing a g-C3N4/CQDs/BiOBr photocathode and a bioanode, successfully achieving simultaneous H2 production and sludge reduction. The research highlights the effective formation of a Z-type heterojunction in the g-C3N4/CQDs/BiOBr photocathode, substantially enhancing the photocurrent response under light conditions. Operating at - 0.4 V versus RHE, it demonstrated a current density of - 3.25 mA·cm-2, surpassing that of g-C3N4/BiOBr (-2.25 mA·cm-2) by 1.4 times and g-C3N4 (-2.04 mA·cm-2) by 1.6 times. When subjected to visible light irradiation and a 0.8 V applied bias voltage, the MPEC system achieved a current density of 1.0 mA·cm-2. The cumulative H2 production of the MPEC system reached 8.9 mL, averaging a production rate of 0.13 mL·h-1. In the anode chamber, the degradation rates of total chemical oxygen demand (TCOD), soluble chemical oxygen demand (SCOD), total suspended solids (TSS), volatile suspended solids (VSS), proteins, polysaccharides, and volatile fatty acids (VFA) in the sludge were recorded at 57.18%, 82.64%, 64.98%, 86.39%, 42.81%, 67.34%, and 29.01%, respectively.

Synthesis of Gemini-type imidazoline quaternary ammonium salt using by-product fatty acid as corrosion inhibitor for Q235 steel.

Gemini-type imidazoline quaternary ammonium salt is a new type of environmentally friendly corrosion inhibitor has been widely used in engineering materials. However, most of them are hazardous/toxic compounds derived from petroleum-based products, which did harm to environment. In this work, an environmentally friendly Gemini-shaped imidazoline quaternary ammonium salt corrosion inhibitor (G211) was synthesized using cheap fatty acid recycled from dimer acid industry as feedstock. The corrosion inhibition effects of G211 on Q235 steel in 1 M HCl solution were investigated through weight loss experiments, potential polarization curves, and alternating current impedance spectroscopy experiments. The results show that the inhibition rate of G211 as a mixed-type inhibitor is up to 94.4% and the concentration drop as low as 500 ppm at 25 â„ƒ. The adsorption of G211 on Q235 surface follows Langmuir adsorption isothermal curve. The chemical composition of the Q235 steel surface was analyzed through scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Furthermore, the possible corrosion inhibition mechanism of G211 on the surface of Q235 steel is proposed. This article not only presents an outstanding solution for safeguarding Q235 steel against corrosion but also introduces a feasible method for high-value utilization of monomer acid (MA).

Mobility of Zn and Cu in Bentonites: Implications for Environmental Remediation.

The aim of this study was to evaluate the mobility of copper (Cu) and zinc (Zn) and their impact on the properties of bentonites and unfrozen water content. Limited research in this area necessitates further analysis to prevent the negative effects of metal interactions on bentonite effectiveness. Tests involved American (SWy-3, Stx-1b) and Slovak (BSvk) bentonite samples with Zn or Cu ion exchange. Sequential extraction was performed using the Community Bureau of Reference (BCR) method. Elemental content was analyzed via inductively coupled plasma optical emission spectrometry (ICP-OES). Unfrozen water content was measured using nuclear magnetic resonance (1H-NMR) and differential scanning calorimetry (DSC). Results showed a significant influence of the main cation (Zn or Cu) on ion mobility, with toxic metal concentrations increasing mobility and decreasing residual fractions. Mobile Zn fractions increased with larger particle diameters, lower clay content, and shorter interplanar spacing, while the opposite was observed for Cu. Zn likely accumulated in larger clay pores, while Cu was immobilized in the bentonite complex. The stability of Zn or Cu ions increased with higher clay content or specific surface area. Residual Zn or Cu fractions were highest in uncontaminated bentonites with higher unfrozen water content, suggesting the potential formation of concentrated solutions in sub-zero temperatures, posing a threat to the clay-water environment, especially in cold regions.

Optimal Preparation and Performance Study of Eco-Friendly Composite Chemical Dust Suppressants: A Case Study in a Construction Site in Chengdu.

To mitigate dust pollution generated during various stages of construction activities and reduce the environmental and health hazards posed by airborne dust, this study utilized hydroxyethyl cellulose, glycerol, and isomeric tridecyl alcohol polyoxyethylene ether as raw materials to formulate a composite chemical dust suppressant. The properties of the dust suppressant were characterized through analysis. Employing single-factor experiments, the optimal proportions of the binder, water-retaining agent, and surfactant for the composite dust suppressant were determined. Subsequently, a response surface model was established, and, after analysis and optimization, the optimal mass ratios of each component in the composite dust suppressant were obtained. Under optimal ratios, the physicochemical properties and wind erosion resistance of the composite dust suppressant were analyzed. Finally, the practical application of the suppressant was validated through on-site trials at a construction site. This study revealed that the optimal formulation for the dust suppressant was as follows: 0.2% hydroxyethyl cellulose, 2.097% glycerol, 0.693% isomeric tridecyl alcohol polyoxyethylene ether, and the remainder was pure water. The suppressant is non-toxic, non-corrosive, environmentally friendly, and exhibits excellent moisture retention and bonding properties compared to water. The research findings provide valuable insights for addressing dust pollution issues on construction sites.

Conservation of the Rare and Endangered Vascular Plants in the Mining and Tourism Area: Khibiny Mountains, Murmansk Region, Russia.

The Khibiny Mountains (hereafter called Khibiny Mts.) are one of the most urbanized and industrialized regions in the Russian Arctic. There are combined a developed mining complex, elaborate infrastructure, a well-known tourist resort, and a large population, all amidst an exceptionally rich biodiversity of plants. In this study, we analyzed the current knowledge of the spatial distribution of rare and endangered vascular plants and vegetation and the impacts of human activities on these ecosystems. Approximately 28% of the protected vascular plant species in the Murmansk Region were registered within the confines of the Khibiny Mts. In particular, although only a handful of protected species had a widespread presence, most rare species were confined to the southern reaches of the mountain range, with only a select few extending into other parts. Papaver lapponicum was the only species that thrived across the entire territory, including industrial areas. The studied territory contained nine specially protected areas spanning 123,220 hectares. Nature monuments adjacent to mining sites and urban centers play an important role in preserving regional biodiversity. However, the expansion of the mining industry, alongside deforestation and wildfires, poses considerable threats to the biodiversity of the Khibiny Mts. A comprehensive biodiversity conservation strategy implemented in this region balances the local and expansive territorial protection of rare species and habitats, ensuring environmental preservation while facilitating social and economic progress, a noteworthy example of environmental protection in the Arctic.