Removal of Cr(VI) from water by in natura and magnetic nanomodified hydroponic lettuce roots.

Biosorption is a viable and environmentally friendly process to remove pollutants and species of commercial interest. Biological materials are employed as adsorbents for the retention, removal, or recovery of potentially toxic metals from aqueous matrices. Hexavalent chromium is a potential contaminant commonly used in galvanoplasty and exhibits concerning effects on humans and the environment. The present work used in natura lettuce root (LR) and nanomodified lettuce root (LR-NP) for Cr(VI) adsorption from water medium. The nanomodification was performed by coprecipitation of magnetite nanoparticles on LR. All materials were morphologically and chemically characterized. The conditions used in removing Cr(VI) were determined by evaluating the pH at the point of zero charge (pHPZC = 5.96 and 6.50 for LR and LR-NP, respectively), pH, kinetics, and sorption capacity in batch procedures. The maximum sorption capacity of these materials was reached at pH 1.0 and 30 min of adsorbent-adsorbate contact time. The pseudo-second-order kinetic equation provided the best adjustments with r2 0.9982 and 0.9812 for LR and LR-NP, respectively. Experimental sorption capacity (Qexp) results were 4.51 ± 0.04 mg/g, 2.48 ± 0.57 mg/g, and 3.84 ± 0.08 mg/g for LR, NP, and LR-NP, respectively, at a 10 g/L adsorbent dose. Six isothermal models (Langmuir, Freundlich, Sips, Temkin, DR, and Hill) fit the experimental data to describe the adsorption process. Freundlich best fit the experimental data suggesting physisorption. Despite showing slightly lower Qexp than LR, LR-NP provides a feasible manner to remove the Cr(VI)-containing biosorbent from the medium after sorption given its magnetic characteristic.

Hexavalent chromium removal from water: adsorption properties of in natura and magnetic nanomodified sugarcane bagasse.

Biosorption has become a viable and ecological process in which biological materials are employed as adsorbents for the removal of potentially toxic metals, such as hexavalent chromium, from aqueous matrices. This work proposed the use of in natura (SB) and nanomodified sugarcane bagasse (SB-NP) with ferromagnetic nanoparticles (Fe3O4) to adsorb Cr(VI) from water. These materials were analyzed by X-ray Spectroscopy (XRD), Scanning Electron Microscopy (SEM), and Fourier Transform Infrared Spectroscopy (FTIR) to investigate their morphology and interaction with Cr(VI). It was observed the efficient impregnation of magnetite on the SB surface and the presence of functional groups such as O-H, C-H, C=O, C-O-C, C-O, and Fe-O (characteristic of magnetite). The best conditions for Cr(VI) removal in aqueous medium were determined by assessing the pH at the point of zero charge (pHPZC = 6.1 and 5.8 for SB and SB-NP, respectively), adsorption pH and kinetics, and adsorption capacity. Batch procedures were performed using increasing concentrations of Cr(VI), 10-100 mg/L at pH 1.0, and 30 min of contact time. The adsorbent dose was 10 mg/L, and the experimental adsorption capacities (SCexp) for SB, NP, and SB-NP were 1.49 ± 0.06 mg/g, 2.48 ± 0.57 mg/g, and 1.60 ± 0.08 mg/g, respectively. All Cr contents were determined by flame atomic absorption spectrometry (FAAS). The pseudo-2nd-order kinetic equation provided the best adjustments with r2 0.9966 and 0.9931 for SB and SB-NP, respectively. Six isotherm models (Langmuir, Freundlich, Sips, Temkin, Dubinin-Radushkevich, and Hill) were applied to the experimental data, and Freundlich, Dubinin-Radushkevich (D-R), and Temkin were the models that best described the experimental sorption process. The binding energy values (E) provided by the D-R model were 0.11 ± 0.25, 0.09 ± 0.20, and 0.08 ± 0.25 kJ/mol, for NP, SB-NP, and SB, respectively, and denote a physical interaction for the studied adsorbate-adsorbent system. The nanomodification of the biomass slightly improved the efficiency for the sorption of Cr(VI) and facilitated the removal of Cr(VI)-containing biosorbents from water medium.