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Aryl fluorosulfates are versatile building blocks in organic synthesis and have gained increasing attention in SuFEx (Sulfur Fluoride Exchange) click chemistry. They are easily and conveniently prepared from phenols using sulfuryl fluoride SO2F2 as a low-cost sulfonyl fluoride provider. Recently, they served as less toxic and more atom economical alternatives to triflates in an impressive number of carbon-carbon and carbon-heteroatom cross-coupling reactions. In this review, we summarize the current advances and developments in applying aryl fluorosulfates as electrophilic partners in cross-coupling reactions.
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In the current twenty years, industrial applications of ionic liquids (ILs) have been of paramount attention due to their indisputable positive characteristics like negligible volatility and chemical/thermal stability. These brilliant advantages open new horizons towards environmentally friendly application of ILs in several industrial activities like membrane-based CO2 separation, electrolyte, bioprocessing, targeted drug delivery and solar panels. The principal intention of this article is to prepare a comprehensive review on the potential efficiency of IL-based absorbents to separate CO2 acidic contaminant from industrial gaseous streams compared to alkanolamine absorbents as the benchmark. For this purpose, a techno-economic evaluation is presented to compare the cost-effectiveness of ILs compared to alkanolamine absorbents. Finally, major environmental impacts of the ILs applications in industries are discussed and future perspectives towards solving the operational challenges are presented in detail.
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Líquidos Iónicos , Dióxido de CarbonoRESUMEN
Using the microwave-assisted method, novel Fe3O4/Zn-metal organic framework magnetic nanostructures were synthesized. The crystallinity, thermal stability, adsorption/desorption isotherms, morphology/size distribution, and magnetic hysteresis of synthesized Fe3O4/Zn-metal organic framework magnetic nanostructures were characterized by XRD patterns, TGA curve, BET adsorption/desorption technique, SEM image, and VSM curve, respectively. After confirming the Fe3O4/Zn-metal organic framework magnetic nanostructures, its antimicrobial properties against Gram-positive bacterial, Gram-negative bacterial, and fungal strains based on minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC), and minimum fungicidal concentration (MFC) values were studied. The MIC values in antimicrobial activity for Gram-positive and Gram-negative bacterial strains, between 16-128 µg/ml, and for fungal strain, 128 µg/ml were observed. The results showed that the high specific surface area of Fe3O4/Zn-metal organic framework magnetic nanostructures caused the antimicrobial power of nanoparticles to be high, and the observed antimicrobial effects were higher than some known commercial antimicrobial drugs. Another advantage of the specific surface area of Fe3O4/Zn-metal organic framework magnetic nanostructures was its high catalytic properties in the three-component reaction of isatin, malononitrile, and dimedone. New spiro [indoline-pyranopyrimidines] derivatives were synthesized with high efficiency. The catalytic activity results of Fe3O4/Zn-metal organic framework magnetic nanostructures showed that, in addition to recyclability, derivatives could be synthesized in less time than previously reported methods. The results of investigating the catalytic activity of Fe3O4/Zn-metal organic framework magnetic nanostructures showed that the spiro [indoline-pyranopyrimidines] derivatives were synthesized in the time range of 10-20 min with an efficiency of over 85%. As a final result, it can be concluded that the microwave synthesis method improves the unique properties of magnetic nanostructures, especially its specific surface area, and has increased its efficiency.
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PURPOSE: The purpose of this study is the prevention of Candida colonies on PMMA Denture Base by altering the surface and incorporations of Nanoparticles. MATERIALS AND METHODS: The Pub Med/Medline was searched to identify 100 relevant studies published from 2011 to 2020. The search strategy employed the following keywords related to "use of Nanoparticles in dentistry", "Antimicrobial agents and PMMA", "Candidiasis and nanomaterials", "Prevention of oral Candidiasis", "Incorporation of antimicrobial agents in acrylic dentures," "nanoparticles as therapeutic agents for denture stomatitis", "Nanodentistry" or "Nanotechnology" or "Nanocomposite" or "Nanodrugs" or "Nanomaterials". RESULTS: Most of the studies shows that modified PMMA denture base resin containing different antimicrobial coatings and incorporation of metal oxides Nanoparticles and other nanomaterials showed antifungal activity in vitro; however some materials in higher concentration showing altered physical and mechanical properties possibly due to aggregation of Nanoparticles in the lattice of PMMA molecules. CONCLUSION: Metal oxides nanomaterials revealed cytotoxicity to Candida and other microbes present in oral biofilm including PMMA denture surface. Nano toxicity may attribute to direct interaction of nanoparticles with cell membrane, hindrance in protein synthesis and early adhesion & interfere with physiology of pathogens.
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A fundamental objective of an aesthetic treatment is the patient's satisfaction and that the outcome of the treatment should meet the patient's expectation of enhancing his/her facial aesthetics and smile. A patient constantly doubting the end result of the treatment, which is an irreversible procedure, can be motivated and educated through Digital Smile Designing (DSD) technique. DSD is a technical tool which is used to design and modify the smile of patients digitally and help them to visualize it beforehand by creating and presenting a digital mockup of their new smile design before the treatment physically starts. It helps in visual communication and involvement of the patients in their own smile design process, thus ensuring predictable treatment outcome and increasing case acceptance. This article reviews the aspects of digital smile designing in aesthetic dental practice pertaining to its use, advantages, limitations and future prospects.
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Oral diagnosis and treatment planning is of utmost importance in pediatric dentistry. Although intraoral and conventional radiographic procedures have been used extensively since decades, there two-dimensional representation has raised many questions. Cone beamed computed tomography with 3-D technology is a replacement for conventional 2-D imaging and has a wide application among child patients in pediatric dentistry. This article therefore deals with current facts and myths about clinical situations where CBCT is indicated in pediatric patients.
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Mucosal fenestration is a clinical finding in which a portion of the tooth root is denuded of the overlying alveolar bone and gingiva or oral mucosa, thus exposing the root to the oral cavity. If left untreated, they may be a source of infection by giving entry to oral pathogen, leading to further progression of periodontal disease. Depending on their site of presence, they may also be a reason of esthetic concern to some patients. This paper reports one such infrequent case of mucosal fenestration of lower incisor region that was well treated by an interdisciplinary approach and regenerative therapy.
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Neutral zone technique is long being used for the management of severely resorbed mandibular ridges. Various materials are used in recording neutral zone, which have their own advantages and disadvantages. This article discusses the use of Polyether impression material which is simpler and more practical.
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Fifty patients having psoriasis were studied with a view to assess and comparc the efficacy of PUVASOL (oral psoralin with ultraviolet/sun-ray exposure) therapy with that of the, combined regime of PUVASOL and a topical. cream containing, urea coal- trar, dithranol salicylic acid and Th. two forms of therapy were m-25 patients each, and observations were made over a period of 90 days. PUVASOL combined with topical medicat on was found to be more effective, than PUVASOL alone. The side effects were also more' marked in the combined therapy group, but were manageable by regulating the doses.
