RESUMEN
Understanding the relationships between structure and properties of aluminosilicate glasses is of interest in magmatic studies as well as for glass applications as mechanical or optical components. Glass properties may be tailored by the incorporation of additional elements, and here we studied the effect of phosphate incorporation on refractive index and the degree of ionic bonding in aluminosilicate glasses. The studied glasses in the system SiO2-Al2O3-Na2O-P2O5 had a metaluminous composition (Al:Na = 1) with the content of SiO2 ranging from 50 to 70 mol% and of P2O5 from 0 to 7.5 mol%. Refractive index was measured at four wavelengths from visible to near-infrared and found to decrease both with increasing P2O5 content (at the expense of NaAlO2) and with increasing SiO2 content (by substitution of SiO4 for AlO4 groups). This trend correlated with a decrease in density while, additionally, the formation of Al-O-P bonds with an SiO2-like structure may account for this change. The degree of ionic bonding, assessed via optical basicity and oxygen polarisability, decreased with increasing P2O5 and SiO2 content. Despite the complexity of the studied glasses, oxygen polarisability and optical basicity were found to follow Duffy's empirical equation for simple oxide glasses. In the high frequency infrared and Raman spectra, band shifts were observed with increasing P2O5 and SiO2 content. They indicated changing average bond strength of the glass network and showed a linear correlation with optical basicity.
RESUMEN
A newly designed all-solid step-index Yb-doped aluminosilicate large mode area fiber for achieving high peak power at near diffraction limited beam quality with local adiabatic tapering is presented. The 45µm diameter fiber core and pump cladding consist of active/passively doped aluminosilicate glass produced by powder sinter technology (REPUSIL). A deliberate combination of innovative cladding and core materials was aspired to achieve low processing temperature reducing dopant diffusion during fiber fabrication, tapering and splicing. By developing a short adiabatic taper, robust seed coupling is achieved by using this Yb-doped LMA fiber as final stage of a nanosecond fiber Master Oscillator Power Amplifier (MOPA) system while maintaining near diffraction limited beam quality by preferential excitation of the fundamental mode. After application of a fiber-based endcap, the peak power could be scaled up to 375 kW with high beam quality and a measured M2 value of 1.3~1.7.
RESUMEN
In this work, a Fabry-Perot cavity based on a new silica tube design is proposed. The tube presents a cladding with a thickness of ~14 µm and a hollow core. The presence of four small rods, of ~20 µm diameter each, placed in diametrically opposite positions ensure the mechanical stability of the tube. The cavity, formed by splicing a section of the silica tube between two sections of single mode fiber, is characterized in strain and temperature (from room temperature to 900 °C). When the sensor is exposed to high temperatures, there is a change in the response to strain. The influence of the thermal annealing is investigated in order to improve the sensing head performance.
