RESUMEN
Surface deposition of magnesium ferrite nanoparticles (MgFe2O4 NPs) with bimetallic gold/silver (Au/Ag) nanoparticles was conducted using the seed-mediated growth method to obtain magnetic-metallic composite catalysts for use in the catalytic reduction of nitroaromatics. Two types of amine-functionalized MgFe2O4 and MgFe2O4@SiO2 NPs were used as magnetic supports for the surface deposition process. The combination of several characterization analyses (i.e., XRD, XPS, TEM, SEM, EDS, and VSM) confirmed the successful syntheses of the MgFe2O4/Au/Ag and MgFe2O4@SiO2/Au/Ag NPs. The catalytic reduction of 4-nitrophenol using sodium borohydride as a reducing agent revealed that the reaction was completed within 2 min by using MgFe2O4/Au/Ag and MgFe2O4@SiO2/Au/Ag NPs as catalysts. The appearance rate constant of the MgFe2O4/Au/Ag NPs was slightly higher than that of the MgFe2O4@SiO2/Au/Ag NPs. In terms of reusability, high conversion (>80%) of the reduction of 4-nitrophenol was still obtained after 7 and 10 consecutive cycles for the MgFe2O4/Au/Ag and MgFe2O4@SiO2/Au/Ag catalysts, respectively. Interestingly, these two catalysts exhibited the highly catalytic conversion of the chosen nitroaromatic derivatives (i.e., 4-nitrobenzaldehyde and 4-nitroaniline). On the whole, the MgFe2O4/Au/Ag and MgFe2O4@SiO2/Au/Ag NPs could be utilized as suitable and sustainable catalysts for the catalytic reduction of nitroaromatics due to several desirable features (i.e., high activity, facile and rapid separation by a magnet, and good reusability).
RESUMEN
Two series of Ag x /Au/Pt y trimetallic nanoparticles (Ag x Au1Pt2 with x ranging from 1-5 and Ag4Au1Pt y with y ranging from 1-3) were prepared by a sequential chemical reduction method that involved the deposition of Pt on preformed Ag/Au core-shell particles by systematically controlling the amount of Ag, Au, and Pt metal precursor solutions. The structural changes (the diameters and increased surface roughness from the defective features) and absorption patterns (the significant reduction of the peak intensities) of the nanoparticles examined with TEM and UV-vis spectroscopy indicated the selective incorporation of Pt on the Ag/Au nanoparticles regardless of their compositions. In addition, a combination of WDX, XRD, and XPS analyses quantitatively and qualitatively confirmed the successful formation of the Ag x Au1Pt2 and Ag4Au1Pt y trimetallic nanoparticles. Subsequently, these series of nanoparticles were deposited on multi-wall carbon nanotubes (MWCNTs) to evaluate their electrocatalytic property in the methanol oxidation reaction (MOR) as a function of their metal compositions. The results showed that the electrocatalytic activities of all Ag4/Au1/Pt y systems were higher than those of typical Pt on the MWCNTs. In particular, the Ag4Au1Pt2 nanoparticles exhibited the highest electrocatalytic property for the MOR, suggesting the importance of the proper combination of metal constituents and structures to regulate the activity in electrocatalytic systems.
RESUMEN
In this work, the core-magnesium ferrite (MgFe2O4) nanoparticles were prepared by hydrothermal technique. Completed gold (Au) shell coating on the surfaces of MgFe2O4 nanoparticles was obtained by varying core/shell ratios via a reduction method. Phase identification, morphological evolution, optical properties, magnetic properties and cytotoxicity to mammalian cells of these MgFe2O4 core coated with Au nanoparticles were examined by using a combination of X-ray diffraction, scanning electron microscopy, transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy, UV-visible spectroscopy (UV-vis), vibrating sample magnetometry and resazurin microplate assay techniques. In general, TEM images revealed different sizes of the core-shell nanoparticles generated from various core/shell ratios and confirmed the completed Au shell coating on MgFe2O4 core nanoparticles via suitable core/shell ratio with particle size less than 100 nm. The core-shell nanoparticle size and the quality of coating influence the optical properties of the products. The UV-vis spectra of complete coated MgFe2O4-Au core-shell nanoparticles exhibit the absorption bands in the near-Infrared (NIR) region indicating high potential for therapeutic applications. Based on the magnetic property measurement, it was found that the obtained MgFe2O4-Au core-shell nanoparticles still exhibit superparamagnetism with lower saturation magnetization value, compared with MgFe2O4 core. Both of MgFe2O4 and MgFe2O4-Au core-shell also showed in vitro non-cytotoxicity to mouse areola fibroblast (L-929) cell line.