Rational construction of MOF derived α-Fe2O3/g-C3N4 composite for effective photocatalytic degradation of organic pollutants and electrocatalytic oxygen evolution reaction.

In recent years, researchers have been actively investigating metal oxide-based materials with narrow bandgaps due to their potential applications toward wastewater treatment and oxygen evolution reactions (OER). In this study, we successfully synthesized g-C3N4 (GCN), Fe2O3, and Fe2O3/g-C3N4 (FGCN) using thermal polymerization and hydrothermal methods. We characterized the physicochemical and structural properties of these materials through various analytical techniques including XRD, FT-IR, UV-DRS, XPS, FE-SEM, and HR-TEM analyses, confirming the effective construction of the FGCN composite catalyst. We evaluated the photocatalytic activity of Fe2O3, GCN, and FGCN composite catalysts by assessing their ability to degrade rhodamine B (RhB) and crystal violet (CV) by exposing them to sunlight for 150 min. Among these catalysts, the FGCN composite demonstrated excellent photocatalytic performance, achieving 93 % and 95 % degradation of RhB and CV, respectively, under 150 min of sunlight exposure. The developed Fe2O3/g-C3N4@Nickel foam (FGCN@NF) composite catalyst exhibits remarkable OER performance, with a reduced Tafel slope of 64 mV/dec and a low overpotential of 290 mV at a current density of 10 mA/cm2 and shows excellent durable performance over a long time (15 h). Total Organic Carbon (TOC) analysis confirmed the mineralization of both dyes. The photocatalytic performance remained largely unchanged after five consecutive experiments, demonstrating excellent reusability and photostability. Trapping experiments revealed that O2●- is the main species responsible for the photocatalytic decomposition of various dyes by the FGCN composite catalyst. Therefore, the development of a versatile photo/electrocatalytic system that can efficiently promote energy conversion in environmental applications has attracted great attention.

Fabrication of Bi2O3/Bismuth Titanates Modified with Metal-Organic Framework-In2S3/CdIn2S4 Materials for Electrocatalytic H2 Production and Its Photoactivity.

Compositional and structural elucidation of the materials is important to know their properties, chemical stability, and electro-photoactivity. The heterojunction electrocatalyst and photocatalyst activity could open a new window for solving the most urgent environmental and energy problems. Here, for the first time, we have designed and fabricated Bi2O3/bismuth titanates modified with MOF-In2S3/CdIn2S4 materials by a stepwise process. The detailed structural elucidation and formation of mixed composite phases were studied in detail. It has been found that the formed composite was efficiently utilized for the electrocatalytic H2 production reaction and the photocatalytic degradation of tetracycline. XRD patterns for the metal-organic framework-In2S3 showed a main compound of MOF, and it was assigned to a MIL-53 MOF phase, with a monoclinic structure. The addition of CdCl2 onto the MOF-In2S3 phase effectively produced a CdIn2S4 flower platform on the MOF rods. The uniform dispersion of the bismuth titanates in MOF-In2S3/CdIn2S4 materials is detected by mapping of elements obtained by dark-field HAADF-STEM. Finally, the predictions of how to integrate experiments and obtain structural results more effectively and their common development in new heterojunctions for electro-/photocatalytic applications are presented.

Synthesis of Solar Light Active Reduced Graphene Oxide-ZnS Nanomaterial for Photocatalytic Degradation and Antibacterial Applications.

Good water quality is essential for life; therefore, decolorizing and detoxifying organic dye wastes (textile effluents) have gained immense environmental importance in recent years. Thus, the degradation of wastewater has become a potential need for our environment. This research aims to synthesize and investigate a ceramic-based nanomaterial catalyst for the degradation of dye solution under exposure to sunlight. A reduced graphene oxide-ZnS (rGO-ZnS) nanomaterial was qualitatively synthesized using a solvothermal method. The prepared nanomaterial was characterized using XRD, SEM, HR-TEM, EDX, XPS, and FT-IR techniques. The photocatalytic activity of the rGO-ZnS nanomaterial was checked using oxidative photocatalytic degradation of naphthol blue black dye (NBB) under direct sunlight irradiation. Here, the rGO/ZnS composite showed a significant photocatalytic performance to degraded NBB (93.7%) under direct solar light. Chemical Oxygen Demand (COD) measurements confirmed the mineralization of the dye. The influence of different radical scavengers on NBB degradation was studied. Optimum conditions for efficient degradation were determined. The antibacterial property of the prepared catalyst was studied.

Highly Efficient Solar-Light-Active Ag-Decorated g-C3N4 Composite Photocatalysts for the Degradation of Methyl Orange Dye.

In this study, we utilized calcination and simple impregnation methods to successfully fabricate bare g-C3N4 (GCN) and x% Ag/g-C3N4 (x% AgGCN) composite photocatalysts with various weight percentages (x = 1, 3, 5, and 7 wt.%). The synthesized bare and composite photocatalysts were analyzed to illustrate their phase formation, functional group, morphology, and optical properties utilizing XRD, FT-IR, UV-Vis DRS, PL, FE-SEM, and the EDS. The photodegradation rate of MO under solar light irradiation was measured, and the 5% AgGCN composite photocatalyst showed higher photocatalytic activity (99%), which is very high compared to other bare and composite photocatalysts. The MO dye degradation rate constant with the 5% AgGCN photocatalyst exhibits 14.83 times better photocatalytic activity compared to the bare GCN catalyst. This photocatalyst showed good efficiency in the degradation of MO dye and demonstrated cycling stability even in the 5th successive photocatalytic reaction cycle. The higher photocatalytic activity of the 5% AgGCN composite catalyst for the degradation of MO dye is due to the interaction of Ag with GCN and the localized surface plasmon resonance (SPR) effect of Ag. The scavenger study results indicate that O2●- radicals play a major role in MO dye degradation. A possible charge-transfer mechanism is proposed to explain the solar-light-driven photocatalyst of GCN.

Meglumine as a green, efficient and reusable catalyst for synthesis and molecular docking studies of bis(indolyl)methanes as antioxidant agents.

An efficient and convenient Meglumine catalyzed procedure for the synthesis of bis(indolyl) methanes at ambient temperature under aqueous conditions in high yields. The catalytic reaction proceeds very smoothly. Clean reaction, ease of product isolation/purification, easily available reactants, metal free and environmentally friendly reaction conditions are the notable advantages of the present methodology. All the entitled compounds were characterized by IR, 1H, 13C NMR, mass spectra and evaluated for their antioxidant (DPPH, H2O2 and NO scavenging methods). They exhibited potent in vitro antioxidant activity dose-dependently. The binding interactions and molecular docking studies for entitled compounds were studied against 3MNG protein. 4d exhibited marked binding affinity with excellent docking score of -7.6 K.cal/mol and emerged as a lead compound.