Silane and fluorine free facile hydrophobicization of water hyacinth biomass for oil-water separations.

As the adverse effects of using plastics and perfluorinated alkyl substances become more apparent, there is a growing need for sustainable hydrophobic products. Cellulose and its derivatives are the most abundant and widely used polymers, and cellulose-based products have great potential in industries where plastics and other hydrophobic polymers are used, such as stain-resistant fabrics, food packaging, and oil-water separation applications. In this study, we extracted cellulose from water hyacinth (WH) biomass, known for its negative environmental impact, and converted it into hydrophobic cellulose. This addresses the issue of managing WH waste and creating an environmentally friendly hydrophobic material. Initially, aldehyde groups were introduced through oxidation with periodate, followed by direct octadecyl amine (ODA) grafting onto dialdehyde cellulose (DAC) via a Schiff base condensation. The resulting ODA modified cellulose (ODA-C) was dispersed in ethanol and used to coat various materials, including cotton fabric, cellulose filter paper, and packaging paper. The modified materials showed excellent hydrophobicity as measured by their water contact angles (WCAs), and the application of the coating was demonstrated for oil-water separation, stain-resistant hydrophobic fabric, and paper-based packaging materials. FTIR, XRD, and WCA analysis confirmed the successful modification of cellulose. A high separation efficiency of 99% was achieved for diesel/water separation using modified filter paper (MoFP), under gravity. On application of the coating, cotton fabric became hydrophobic and resisted staining from dye, and paper-based packaging materials became more robust by becoming water-resistant. Overall, the facile synthesis, low cost, high efficiency, and use of environmentally friendly sustainable materials make this a promising strategy for hydrophobically modifying surfaces for a wide range of applications while reducing the menace of water hyacinth.

An integrated biorefinery approach for the valorization of water hyacinth towards circular bioeconomy: a review.

Water hyacinth (WH) has become a considerable concern for people across the globe due to its environmental and socio-economic hazards. Researchers are still trying to control this aquatic weed effectively without other environmental or economic losses. Research on WH focuses on converting this omnipresent excessive biomass into value-added products. The potential use of WH for phytoremediation and utilizing waste biomass in various industries, including agriculture, pharmaceuticals, and bioenergy, has piqued interest. The use of waste WH biomass as a feedstock for producing bioenergy and value-added chemicals has emerged as an eco-friendly step towards the circular economy concept. Here, we have discussed the extraction of bio-actives and cellulose as primary bioproducts, followed by a detailed discussion on different biomass conversion routes to obtain secondary bioproducts. The suggested multi-objective approach will lead to cost-effective and efficient utilization of waste WH biomass. Additionally, the present review includes a discussion of the SWOT analysis for WH biomass and the scope for future studies. An integrated biorefinery scheme is proposed for the holistic utilization of this feedstock in a cascading manner to promote the sustainable and zero-waste circular bio-economy concept.