RESUMEN
The asymmetric unit of the title hydrazone compound, C(15)H(10)BrClN(2)O(4), contains two independent mol-ecules. The dihedral angles between the benzene rings are 38.7â (3)° in one mol-ecule and 24.3â (3)° in the other. Both mol-ecules exist in trans conformations with respect to the C=N double bonds of the central methyl-idene units. Intra-molecular O-Hâ¯N contacts are observed in both mol-ecules, forming S(6) rings. In the crystal, mol-ecules are linked through N-Hâ¯O hydrogen bonds into chains along the a axis.
RESUMEN
The asymmetric unit of the title compound, C(14)H(12)BrN(3)O(2), contains two independent mol-ecules in which the dihedral angles between the benzene ring and the pyridine ring are 24.4â (6) and 23.7â (6)°. The mol-ecules exist in a trans configuration with respect to the central methyl-idene units. In the crystal, mol-ecules are linked through inter-molecular N-Hâ¯O hydrogen bonds, forming chains along the a axis.
RESUMEN
In the title hydrazone compound, C(14)H(10)FN(3)O(3), the dihedral angle between the two substituted benzene rings is 13.7â (3)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, mol-ecules are linked through inter-molecular N-Hâ¯O hydrogen bonds, forming chains along the a axis.
RESUMEN
The hydrazone mol-ecule of the title compound, C(15)H(13)N(3)O(4)·CH(4)O, is nearly planar, with a dihedral angle between the two benzene rings of 1.2â (4)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, the benzohydrazide and methanol mol-ecules are linked through inter-molecular O-Hâ¯O, O-Hâ¯N and N-Hâ¯O hydrogen bonds, forming chains along the a axis.
RESUMEN
In the title compound, C(15)H(13)N(3)O(4), the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two benzene rings is 6.8â (2)°. The C-N-NH-C torsion angle is 3.4â (3)°. The mol-ecule possesses an intra-molecular N-Hâ¯O hydrogen bond. In the crystal structure, adjacent mol-ecules are linked through inter-molecular C-Hâ¯O hydrogen bonds, forming dimers.
RESUMEN
In the title compound, C(16)H(16)N(2)O(3), the benzohydrazide group is not planar and the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 26.9â (2)°. In the crystal structure, the mol-ecular packing is stabilized by intra-molecular O-Hâ¯N and inter-molecular N-Hâ¯O hydrogen bonds. The inter-molecular hydrogen bonding forms chains parallel to the b axis.
RESUMEN
In the title compound, C(16)H(15)BrN(2)O(3), there are two independent mol-ecules (A and B) in the asymmetric unit. The major difference between the two mol-ecules is the dihedral angle formed by the aromatic rings [72.6â (2) and 18.8â (2)° for A and B, respectively]. The benzohydrazide groups are not planar and the mol-ecules exist in trans configurations with respect to the methyl-idene units. The mol-ecular packing is stabilized by two inter-molecular N-Hâ¯O hydrogen bonds, forming chains parallel to the c axis. Only the A mol-ecules of the asymmetric unit are held together by π-π inter-actions [centroid-centroid distance = 3.714â (3)â Å].
RESUMEN
The title compound, C(14)H(12)N(2)O(3)·CH(4)O, consists of a Schiff base mol-ecule and a methanol mol-ecule of crystallization. The Schiff base mol-ecule is nearly planar, the dihedral angle between the planes of the two benzene rings being 7.2â (2)°. The mol-ecule exists in the trans configuration with respect to the methyl-idene unit. In the crystal structure, the Schiff base and methanol mol-ecules are linked through O-Hâ¯O, N-Hâ¯O and O-Hâ¯N hydrogen bonds, forming a three-dimensional network.
RESUMEN
The mol-ecule of the title compound, C(14)H(11)N(3)O(4), is approximately planar, the dihedral angle between the planes of the two substituted benzene rings being 2.54â (7)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal structure, mol-ecules are linked through inter-molecular O-Hâ¯O, N-Hâ¯O and C-Hâ¯O hydrogen bonds, forming layers parallel to (101). The O/N-Hâ¯O and C-Hâ¯O inter-actions form a pair of bifurcated acceptor bonds involving the cabon-yl/nitro O atom, generating an R(2) (1)(6) motif.
RESUMEN
In the title compound, C(15)H(12)ClN(3)O(4), the benzohydrazide group is not planar and the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 0.4â (3)°. In the crystal structure, mol-ecules are linked by inter-molecular N-Hâ¯O hydrogen bonds, forming chains parallel to the c axis.
RESUMEN
In the title compound, C(16)H(15)BrN(2)O(3), the benzohydrazide group is not planar and the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 75.6â (2)°. In the crystal structure, mol-ecules are linked by inter-molecular N-Hâ¯O hydrogen bonds involving carbonyl and amine functionalities, to form chains parallel to the c cell axis.