Multi-stage adsorption of methyl orange on the nitrogen-rich biomass-derived carbon adsorbent: DFT and MD evaluation.

Dyes that are released into the environment may have negative effects on living organisms. To address this issue, a biomass-derived carbon adsorbent made from Enteromorpha was tested for its ability to remove methyl orange (MO) from wastewater. The adsorbent was found to be effective in removing MO, with a 1:4 impregnation ratio producing an adsorbent that could remove 96.34% of MO from a 200 mg/L solution using only 0.1 g of adsorbent. At higher concentrations, the adsorption capacity increased up to 269.58 mg/g. Through molecular dynamics simulations, it was discovered that after mono-layer adsorption reached saturation, the remaining MO molecules in solution formed hydrogen bonds with the adsorbed MO, which led to further aggregation on the adsorbent surface and increased adsorption capacity. Additionally, theoretical investigations revealed that the adsorption energy of anionic dyes increased with Nitrogen-doped carbon materials, with the pyrrolic-N site having the highest adsorption energy for MO. The carbon material derived from Enteromorpha showed promise in treating wastewater containing anionic dyes, thanks to its high adsorption capacity and strong electrostatic interaction with the sulfonic acid groups of MO.

Highly efficient adsorption of Bisphenol A using NaHCO3/CO2 activated carbon composite derived from shrimp shell@cellulose.

In this study, the efficiency of activated carbon (AC) synthesized from the shrimp shell plus cellulose (SS@C) was optimized toward Bisphenol A (BPA) adsorption. Low-cost, renewable, and non-toxic shrimp shells mixed with cellulose were carbonized, followed by activation via CO2 and NaHCO3 to produce SS@C-AC. The results revealed that SS@C-AC samples were a porous composite with mesoporous structures comprising a relatively high specific surface area (935.20 m2/g) with a mean pore size of around 3.8 nm and mesoporous volume of 1.83E-02 cm3/g. The influences of initial concentrations, pH values, and adsorption on BPA were investigated systematically. Isotherm model and kinetics study of the adsorption of BPA on SS@C-AC exhibited that the obtained data were in agreement with the Langmuir adsorption isotherm model while there is no difference between PFO and PSO kinetic results for BPA concentrations in the range 25-100 mg/L. The impregnation ratio of 1.5 NaHCO3 and an activation time of 90 min at 800°C were the optimum conditions under which BPA removal of 81.78% was obtained.

Study on two-step hydrothermal liquefaction of macroalgae for improving bio-oil.

In this work, the conversion of Enteromorpha clathrata into bio-oil through hydrothermal liquefaction (HTL) was investigated under different preparation conditions. A two-step reaction method was compared with single-step reaction. At a high temperature, bio-oil produced through the two-step hydrothermal reaction displayed slight changes in yield, but solid residue rate was low. The liquid-to-material ratio of the optimal preparation condition was 40/4 (mL/g). Bio-oil produced in each experiment at this ratio was further analyzed using GC/MS. Furthermore, density functional theory (DFT) quantitative calculation was used in analyzing and proving the possible reaction path of the conversion of furan compounds to aromatic compounds during a direct high-temperature liquefaction process. Results revealed that the two-step method can ensure a high bio-oil yield, while preventing the occurrence of side reactions caused by long-term high-temperature reactions, and improve the bio-oil quality.

Study on the co-operative effect of kitchen wastewater for harvest and enhanced pyrolysis of microalgae.

Microalgae biofuels have received extensive attention as a new generation of renewable energy. However, the cost of cultivation and harvest limits the large-scale use of microalgae. An innovative method for harvesting microalgae through flocculation using kitchen wastewater (KWW) and further co-pyrolysis to enhance the crude bio-oil production was proposed. Flocculation efficiency of KWW for Scenedesmus obliquus showed the highest value of 94.09%. Compared with centrifugation and chemical flocculation (CF), the thermogravimetric curve of the sample after KWW flocculation showed different pattern. In addition, bio-oil yield of microalgae harvested through KWW flocculation was also the highest among the three studied harvest methods, reaching 55.59%. Gas chromatographic mass spectrometry (GC-MS) analysis of bio-oil showed that addition of KWW could promote the production of esters and hydrocarbons in comparison to the microalgae harvested by centrifugation or CF.