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Langmuir ; 20(7): 2652-9, 2004 Mar 30.
Artículo en Inglés | MEDLINE | ID: mdl-15835133

RESUMEN

The temperature-dependent variation of local environment and reorientation dynamics of the small amphiphile 2-phenylethanol in lamellar phase dispersions of the dichain cationic surfactants, 2,3-diheptadecyl ester ethoxypropyl-1,1,1-trimethylammonium chloride (DHTAC) and dioctadecyldimethylammonium chloride (DODMAC), and the nonionic surfactant, tetra(ethylene glycol) n-dodecyl ether (C12E4), have been determined using avoided level crossing muon spin resonance spectroscopy (ALC-muSR). For cosurfactant radicals the hydrophobic or hydrophilic character of the surrounding media can be determined from their magnetic resonance signatures. Comparison of the three different bilayer-forming surfactant systems shows that the ALC-muSR technique is able to distinguish both major and subtle differences in the partitioning of the cosurfactant radicals between the different systems.


Asunto(s)
Membranas Artificiales , Mesones , Alcohol Feniletílico/química , Tensoactivos/química , Espectroscopía de Resonancia por Spin del Electrón/métodos , Radicales Libres/química , Estructura Molecular , Propiedades de Superficie , Temperatura , Agua/química
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