Demystifying the decadal shift in the extent of groundwater in the coastal aquifers of Gujarat, India: A case of reduced extent but increased magnitude of seawater intrusion.

Catastrophic increase in urbanisation and industrialisation along the coastal region leads to increased stress on groundwater reservoirs worldwide. As a growing economy, India faces extreme water crises due to rising water demand and escalating salinisation, specifically in the coastal districts. Therefore, this study shows the implication of a comprehensive modelling approach to assess the spatiotemporal changes in hydrogeochemical processes in the coastal aquifer of the Surat district. Using a multi-model assessment approach, the present study focuses on the decadal evolution in groundwater quality of the coastal aquifers of Surat, Gujarat. Fifty-one groundwater samples were collected for 2008, 2012, and 2018 to assess the spatio-temporal shift in groundwater quality. Piper diagram revealed a shift of hydrogeochemical facies from Mg2+-HCO3- type to Ca2+-Mg2+-Cl- type, indicating the increased salinisation over a decade. The result suggests that rock-water interaction, seawater intrusion mechanism, and anthropogenic activities (intensive agricultural activities and improper waste management) govern the hydrogeochemical processes in the coastal aquifer. A shift of dominance of carbonate weathering to silicate weathering with the dissolution of calcite, dolomite, and gypsum, changing the hydrogeochemistry, was observed over the last decades. This shift leads to the increasing hardness of groundwater. The enrichment of nutrients in groundwater during 2018 (NO3- = 2 to 85 mg. L-1) compared to 2008 (NO3- = 1 to 36 mg.L-1) indicates the increasing imprints of agricultural fertilizer application and human organic waste through sewage contamination on the coastal aquifer. The seawater mixing index model demonstrates that extent of seawater intrusion reduced in 2018 compared to 2012, but the magnitude increased near the coastal talukas (SMI =9.5). The present study helps to understand the increasing anthropogenic activities over a decade leading to increased salinisation and groundwater contamination in the aquifer system. This work can help local stakeholders, water resource managers, and the state government manage the groundwater resources and the future potential threat of aquifer contamination.

Potential arsenic-chromium-lead Co-contamination in the hilly terrain of Arunachal Pradesh, north-eastern India: Genesis and health perspective.

In the recent times, multi-metal co-contamination in the groundwater of various parts of the globe has emerged as a challenging environmental health problems. While arsenic (As) has been reported with high fluoride and at times with uranium; and Cr & Pb are also found in aquifers under high anthropogenic impacts. The present work probably for the first time traces the As-Cr-Pb co-contamination in the pristine aquifers of a hilly terrain that are under relatively less stress from the anthropogenic activities. Based on the analyses of twenty-two (n = 22) groundwater (GW) samples and six (n = 6) sediment samples, it was found that Cr being leached from the natural sources as evident from 100% of samples with dissolve Cr exceeding the prescribed drinking water limit. Generic plots suggests rock-water interaction as the major hydrogeological processes with mixed Ca2+-Na+-HCO3- type water. Wide range of pH suggests localized human interferences, as well as indicative of both calcite and silicate weathering processes. In general water samples were found high only with Cr and Fe, however all sediment samples were found to contain As-Cr-Pb. This implies that the groundwater is under-risk of co-contamination of highly toxic trio of As-Cr-Pb. Multivariate analyses indicate that the changing pH as the causative factor for Cr leaching into the groundwater. This is a new finding for a pristine hilly aquifers, and we suspect such condition may also be present in other parts of globe, and thus precautionary investigations are needed to prevent this catastrophic situation to arise, and to alert the community in advance.

Seawater intrusion decreases the metal toxicity but increases the ecological risk and degree of treatment for coastal groundwater: An Indian perspective.

Contaminant vulnerability in the critical zones like groundwater (GW)-seawater (SW) continuum along the entire Gujarat coast was investigated for the first time through an extensive water monitoring survey. The prime focus of the study was to evaluate whether or not: i) seawater intrusion induced metal load translates to toxicity; ii) in the coastal groundwater, metal distribution follows the pattern of other geogenic and anthropogenic contaminants like NO3- and F-; and iii) what future lies ahead pertaining to metal fate in association with saturation conditions of the coastal aquifers. The spatial distribution of contaminants depicts that the Gulf of Khambhat area is highly contaminated. Ecological risk assessment (ERA) indicates that the Gujarat coast is experiencing a high ecological risk compared to the southeast coast of India. Investigation results revealed that metals, pH, NO3, and CO3 are more vulnerable at the SW-GW mixing interface. An increase in pH is reflected in fewer ionic species of metals in the GW. Salinity ingress due to seawater intrusion (SWI) reduces the toxicities of all trace metals except Cu, attributed to the increase of Ca in GW, leading to dissociation of CuCO3. Reactive species are dominant for Zn and Cd; and M-CO3 ligands are dominant for Cu and Pb owing to the undersaturation of dolomite and calcite in the aquifer system. SWI tends to increase the metal load but the toxicity of metals varies with the density of industries, anthropogenic activities, changes in the mixing-induced saturation conditions, and intensive salt production across the coast. Multivariate analysis confirmed that the hydrogeochemical processes change due to GW-SW mixing and dictates over natural weathering. The ecological risk index (ERI) for the Arabian sea is experiencing moderate (300 ≥ ERI>150) to high ecological risk (ERI >600). Children population is likely to encounter a high health risk through ingestion and dermal exposure than adults. Overall, the study emphasizes the complexity of toxicity-related health impacts on coastal communities and suggests the dire need for frequent water monitoring along the coastal areas for quick realization of sustainable development goals.

Arsenic in the groundwater of the Upper Brahmaputra floodplain: Variability, health risks and potential impacts.

The upper Brahmaputra floodplain (UBF) is highly enriched with geogenic contaminants, mostly the Arsenic (As), owing to its sensitive geomorphology, aquifer groundwater (GW) dynamics, huge sediment deposition along with natural and anthropogenic disturbance significantly accelerate the As leaching rate into the groundwater, leading to an increase the health risk. Concerning the above active processes in the Lakhimpur district of UBF, current work aims to investigate seasonal dynamics of As contamination and associated health hazard for local community. To carry out this study, 51 GW samples analyzed which reveal the seasonal variation in As concentrations with the minimum average concentration in the monsoon season (4.7 µg.L-1) and the maximum in the post-monsoon season (18.5 µg.L-1) with 50% of the samples exceeding permissible limits. The differences in the local geological conditions and the GW flow may contribute to the spatial variations in mean As concentration in the study area. Also, the active GW recharge process identified in post-monsoon season accelerates the As leaching in the area's aquifers. Further, results indicate higher As levels associated with a pH range of 6-7 favours As desorption from minerals under reducing conditions. The hazard index indicates that the children population has high carcinogenic risk compared to adult populations. Furthermore, the study highlights the social risk potential arising from public health crises due to As exposure. Overall, results indicate high As concentrations in region with moderate seasonal variability and demand a dire attention for long-term monitoring to provide sustainable water resources to safeguard the people at risk.

Geochemical ratios mediated understanding of estuarine dynamics in submarine groundwater discharge prevalent basaltic aquifer.

Submarine groundwater discharge (SGD) has been recognized as an integral pathway of hydrological cycle. The role of SGD as a mechanism for material transport from terrestrial to marine ecosystems has also been investigated, considering the large hydrological flux and a massive load of solutes is found to be carried as SGD to the coastal oceans. However, there are challenges in recognizing the process and delineating specific areas which are susceptible to SGD. Considering the unique geochemical signature of groundwaters found in varied lithology, this paper investigates the possibility of using geochemical ratios and their variability in coastal areas as a tracer for the identification of SGD. The Br-/Cl- ratio, prevalently used for identification of seawater-groundwater mixing is investigated. The study raises questions over the viability of Br-/Cl- as a tracer as Br- rich groundwater in the SGD prevalent area may be a cause of elevated Br-/Cl- ratio in the coastal oceans. Furthermore, the peculiar observation of Fe+2 enrichment in coastal seawater also indicated the influence of differential weathering on the subterranean estuarine (STE) sediments releasing Fe+2 as the groundwater in the area is not enriched in groundwater. This observation is very important in the context of rising sea levels as a larger STE due to rising sea levels can cause higher mobilization of Fe+2 in coastal oceans causing a direct influence on the coastal ecosystem.

Muddy (silty-sand) beaches in semi-arid regions attenuate the contaminants flowing into the sea as a submarine groundwater discharge.

Urbanized coastal areas are well-recognized hotspots for the contaminant-enriched groundwater discharge, influencing sensitive coastal ecosystems. The present study investigates how muddy beaches in the semi-arid region alter the contaminant flux flowing into the sea using submarine groundwater discharge (SGD) estimation and hydrogeochemical analysis of coastal waters (groundwater, porewater, and seawater). Fresh SGD carries contaminants such as nutrients and trace metals in the coastal ecosystem, causing increased vulnerability towards eutrophication, harmful algal blooms, and human health. We found that SGD reaching the coast carries immense nutrient flux (155.6 mmol NO3- · day-1; 35 mmol P · day-1 and 12.4 mmol DSi · day-1) and trace metal load ranging from 0.1 to 14.9 mmol · day-1. The nutrient fluxes were higher in the upper saline plume compared to the lower plume. The muddy beach attenuates the nutrients in varying percentages of 9.7 to 22% of NO3-, 1.9 to 25.5% of P due to denitrification and phosphorus absorption, and also caused 19.6% reduction of SO42-. The reduction in SO42- leads to the formation of sulfide (HS-) that promotes the metal precipitation, resulting in the removal of Pb and Cu. This attenuation of nutrients leads to a change in the nutrient ratio (N/P = 7-11) approaching the Redfield ratio, implying the vulnerability of algal bloom at the Dehri beach. Overall, the muddy beach can serve as a natural biogeochemical reactor as it attenuates the nutrient and serves as a source for certain trace metals (Fe, Mn, Zn, and Ni), altering the composition of SGD. Probably this is the first study that emphasizes the attenuation of trace metals in the muddy beaches of a semi-arid region.

Salinity and temperature profiling for the submarine groundwater discharge simulations: Quantification through heat and solute transport model.

Developed coastal regions are the hotspots for contaminated groundwater discharge, affecting sensitive marine ecosystems. The present study aims to identify submarine groundwater discharge (SGD) locations and quantify the contaminant load reaching to the western coast of India (Gujarat coast) using stable isotopes, seepage meter, heat and solute transport model. The coastal aquifers are highly enriched in trace metals due to various active natural processes and anthropogenic activities across the coast. Terrestrial and recirculated SGD was a significant contributor to flow and metal load, which ranged from 1.04 to 181.1 m3.year-1 and 0-77.41 kg.year-1, respectively. The highest estimated SGD in the Gujarat coast was relatively less than the SGD reported in the Bay of Bengal and comparable to the South Chennai coast. The order of metal flux found in the study was Zn > Fe > Cr > Pb > Ni > Cu > Mn, whereas the highest flux of Zn (77.41 kg. year-1) was reported at Fansa beach, which was 7x Fe-flux and 45 x Cr-flux, respectively. Higher micronutrients (Fe and Zn) load in the southern coast leads to increased vulnerability of eutrophication, algal blooms and biotic ligand formation in aquatic species. This enrichment of micronutrients in the coastal ecosystem was evident by the growth of seaweeds on the seabed at SGD identified locations.

Unveiling the extent of salinization to delineate the potential submarine groundwater discharge zones along the North-western coast of India.

The North-West coast of India was notable for the urbanization and semiarid climate, particularly the Gujarat coastal region which was facing water crises and aquifer salinization issue. Under the light of these critical issues, the present study investigates the sources of aquifer salinization and probable location of submarine groundwater discharge (SGD) using an integrated approach of major ion chemistry, statistical techniques, and isotopic signature of groundwater (GW). The evolution of GW reveals that water facies changes from Ca2+-Mg2+-Cl- to Na+-Cl type from the south Gujarat towards the Gulf of Khambhat. Log-normal distribution of Cl- and NO3- divulges that different pollution sources influence the GW quality. Statistical findings supplemented with Isotopic signatures, ionic ratios and cross plots identified four classes of GW, which varies with degree of anthropogenic and seawater influences. Results suggested that seawater intrusion heavily influences 42% of the total GW samples, whereas 58% samples showed the probability of SGD. The study recommends the feasible locations of check dams as a remedial measure for controlling the salinization of coastal aquifer.

Delineation of submarine groundwater discharge and seawater intrusion zones using anomalies in the field water quality parameters, groundwater level fluctuation and sea surface temperature along the Gujarat coast of India.

Nature mediated processes like seawater intrusion (SWI) and its complementary processes like submarine groundwater discharge (SGD) often cause severe water stress on the coastal water resources worldwide. The present work attempts to delineate the SWI and SGD zones along the North-Western coast of India (constituting the entire coastline of Gujarat) which is currently facing severe water crises due to the freshwater salinization and water loss through the coastal aquifer system. In the present work site-specific water characteristics and groundwater level were used as a proxy for identifying the probable zones of SWI and SGD. For the delineation purpose, we have collected 540 water samples distanced at 5-10 km (seawater, porewater and groundwater; 180 each) from the entire coastline of Gujarat. Further, a three-tier validation system has been adopted for delineating the SWI and SGD zones followed by the physical verification of the locations through the integration of (i) Groundwater fluctuation dynamic, (ii) MODIS derived sea surface temperature (SST) anomaly, and (iii) Electrical conductivity (EC) based gradient mapping. The study has identified 9 out of 14 districts being vulnerable to SWI, whereas the remaining five districts from south Gujarat and the Saurashtra coast are suspectable for SGD. The present work will act as a preliminary basis for formulating a framework for the detailed investigation of the mixing process along the coast.

Evaluation, effect and utilization of submarine groundwater discharge for coastal population and ecosystem: A special emphasis on Indian coastline.

Submarine groundwater discharge (SGD) is an important process driven by marine and terrestrial forces. Low tide affects SGD the most, therefore the ideal time to detect SGD is the low tide, especially during spring tide. Techniques to detect and quantify SGD along with the understanding of the related aquifer characteristics is discussed in this study. Scientific community across the world is realizing the importance of studying and mapping SGD because in the scenario of climate change, this part of the global hydrological cycle is an important process and is known to have a significant effect on the marine ecosystem due to nutrient and metal inputs around the region of discharge. Therefore, understanding the processes governing SGD becomes very important. In this review, various components and processes related to SGD (e.g. Submarine Groundwater Recharge, Deep Porewater Upwelling, Recirculated Saline Groundwater Discharge), along with detailed discussion on impacts of SGD for marine ecosystem is presented. Also, it highlights the future research direction and emphasis is put on more research to be done keeping in mind the changing climate and its impacts on SGD.