Best management practices for minimizing undesired effects of thermal remediation and soil washing on soil properties. A review.

The use of remediated soils as end-of-life materials raises some challenges including policy and regulation, permits and specifications, technological limitations, knowledge and information, costs, as well as quality and performance associated with using them. Therefore, a set of procedures must be followed to preserve the quality and fundamental properties of soil during a remediation process. This study presented a comprehensive review regarding the fundamental impacts of thermal desorption (TD) and soil washing (SW) on soil characteristics. The effects of main operating parameters of TD and SW on the physical, chemical, and biological properties of soil were systematically reviewed. In TD, temperature has a more remarkable effect on physic-chemical and biological characteristics of soil than heating time. Therefore, decrease in temperature within a suitable range prevents unreversible changes on soil properties. In SW, more attention should be paid to extraction process of contaminants from soil particles. Using the right dosage and type of chelating agents, surfactants, solvents, and other additives can help to avoid problems with recovery or treatment using conventional methods. In addition, this review introduced a framework for implementing sustainable remediation approaches based on a holistic approach to best management practices (BMPs), which, besides reducing the risks associated with different pollutants, might provide new horizons for decreasing the unfavourable impacts of TD and SW on soil.

Mechanistic modeling of peracetic acid wastewater disinfection using computational fluid dynamics: Integrating solids settling with microbial inactivation kinetics.

While the impact of suspended solids on chemical disinfection kinetics has been widely recognized, a detailed modeling framework for assessing their contribution on disinfection efficiency in municipal contact tanks is yet unavailable. In this paper, we conducted experimental and modeling studies to mechanistically describe the interplay between suspended solids (not removed by gravity settling in secondary clarifiers) and disinfection performance of an emerging disinfectant, peracetic acid, operated in a municipal contact tank. Specifically, we developed an integrated computational fluid dynamics (CFD) model to simultaneously predict the fate and transport of suspended solids, Escherichia coli and peracetic acid in a hypothetical reactor using an exposure-based (i.e., CT-based) inactivation rate expression. The integrated CFD model, calibrated against laboratory data, was used to gain insights on the vertical distribution and local PAA decay effect associated with solids settling and their impact on disinfectant decay and microbial inactivation. Results indicated that: (a) solids settling in contact tanks is a significant phenomenon that cannot be neglected, which can substantially impact disinfection efficiency under low flow conditions; (b) vertical solids distribution and stratification in contact tanks can strongly affect Escherichia coli inactivation by peracetic acid, as highlighted by the CFD modeling studies; (c) Escherichia coli settling is experimentally measurable, and strongly correlated with solids settling. These phenomena can be successfully integrated into a CFD model to obtain a comprehensive description of the PAA disinfection process in presence of changes in secondary effluent quality and flow, a situation typically encountered in municipal contact tanks operated in full scale wastewater treatment plants.