Application of coal fly ash based ceramic membranes in wastewater treatment: A sustainable alternative to commercial materials.

The continued increase in the global population has resulted in increased water demand for domestic, agricultural, and industrial purposes. These activities have led to the generation of high volumes of wastewater, which has an impact on water quality. Consequently, more practical solutions are needed to improve the current wastewater treatment systems. The use of improved ceramic membranes for wastewater treatment holds significant prospects for advancement in water treatment and sanitation. Hence, different studies have employed ceramic membranes in wastewater treatment and the search for low-cost and environmentally friendly starting materials has continued to engender research interests. This review focuses on the application of coal fly ash in membrane technology for wastewater treatment. The processes of membrane fabrication and the various limitations of the material. Several factors that influence the properties and performance of coal fly ash ceramic membranes in wastewater treatment are also presented. Some possible solutions to the limitations are also proposed, while cost analysis of coal fly ash-based membranes is explored to evaluate its potential for large-scale applications.

Fouling, performance and cost analysis of membrane-based water desalination technologies: A critical review.

While water is a key resource required to sustain life, freshwater sources and aquifers are being depleted at an alarming rate. As a mitigation strategy, saline water desalination is commonly used to supplement the available water resources beyond direct water supply. This is achieved through effective advanced water purification processes enabled to handle complex matrix of saline wastewater. Membrane technology has been extensively evaluated for water desalination. This includes the use of reverse osmosis (RO) (the most mature membrane technology for desalination), pervaporation (PV), electrodialysis (ED), membrane distillation (MD), and membrane crystallization (MCr). Though nanofiltration (NF) is not mainly applied for desalination purposes, it is included in the reviewed processes because of its ability to reach 90% salt rejection efficiency for water softening. However, its comparison with other technologies is not provided since NF cannot be used for removal of NaCl during desalination. Remarkably, membrane processes remain critically affected by several challenges including membrane fouling. Moreover, capital expenditure (CAPEX) and operating expenditure (OPEX) are the key factors influencing the establishment of water desalination processes. Therefore, this paper provides a concise and yet comprehensive review of the membrane processes used to desalt saline water. Furthermore, the successes and failures of each process are critically reviewed. Finally, the CAPEX and OPEX of these water desalination processes are reviewed and compared. Based on the findings of this review, MD is relatively comparable to RO in terms of process performance achieving 99% salt rejections. Also, high salt rejections are reported on ED and PV. The operation and maintenance (O&M) costs remain lower in ED. Notably, the small-scale MD OPEX falls below that of RO. However, the large-scale O&M in MD is rarely reported due to its slow industrial growth, thus making RO the most preferred in the current water desalination markets.

Numerical Modelling Assisted Design of a Compact Ultrafiltration (UF) Flat Sheet Membrane Module.

The increasing adoption of ultra-low pressure (ULP) membrane systems for drinking water treatment in small rural communities is currently hindered by a limited number of studies on module design. Detailed knowledge on both intrinsic membrane transport properties and fluid hydrodynamics within the module is essential in understanding ULP performance prediction, mass transfer analysis for scaling-up between lab-scale and industrial scale research. In comparison to hollow fiber membranes, flat sheet membranes present certain advantages such as simple manufacture, sheet replacement for cleaning, moderate packing density and low to moderate energy usage. In the present case study, a numerical model using computational fluid dynamics (CFD) of a novel custom flat sheet membrane module has been designed in 3D to predict fluid flow conditions. The permeate flux through the membrane decreased with an increase in spacer curviness from 2.81 L/m2h for no (0%) curviness to 2.73 L/m2h for full (100%) curviness. A parametric analysis on configuration variables was carried out to determine the optimum design variables and no significant influence of spacer inflow or outflow thickness on the fluid flow were observed. The numerical model provides the necessary information on the role of geometrical and operating parameters for fabricating a module prototype where access to technical expertise is limited.

Facile synthesis and application of cellulosic coagulant from banana peels in cadmium-spiked water.

Cellulosic coagulant with low crystallinity and surface charge of -19.2 mV were extracted from wet banana peels (WBE) using kitchen-blending method. Functionalization with ferric chloride and aluminium chloride yielded higher surface charge of -23.8 mV (mWBE). Both WBE and mWBE coagulants were used to target cadmium ions from aqueous solution. Coagulants and the floccules (WBEA and mWBEA) were characterized by XRD, FT-IR, zeta sizer nano series, and SEM/EDs. The amount of cadmium ion coagulated was determined using ICP-OES. The FTIR analysis revealed the functional groups involved in the coordination and subsequent removal of the metals ions around 1634 cm-1, ascribed to the C = O vibrational band of carbonyl group. Microscopic analysis revealed that the mWBE is porous and exhibited microfibers with rod-like morphology. The effects of parameters such as the initial concentration, coagulant dosage and solution pH were investigated. Coagulation results showed that 10 mg of WBE and mWBE could remove about 80% and 90% of the Cd2+ ions respectively. However; the difference in the performance of both materials does not justify the essence of surface modification. Therefore, WBE is considered more efficient and environmentally friendly. Notwithstanding, the performance of these coagulants in real environmental samples will confirm their robustness.