Exploiting Oriented Field Projectors to Open Topological Gaps in Plasmonic Nanoparticle Arrays.

In the last years there have been multiple proposals in nanophotonics to mimic topological condensed matter systems. However, nanoparticles have degrees of freedom that atoms lack of, like dimensions or shape, which can be exploited to explore topology beyond electronics. Elongated nanoparticles can act like projectors of the electric field in the direction of the major axis. Then, by orienting them in an array the coupling between them can be tuned, allowing to open a gap in an otherwise gapless system. As a proof of the potential of the use of orientation of nanoparticles for topology, we study 1D chains of prolate spheroidal silver nanoparticles. We show that in these arrays spatial modulation of the polarization allows to open gaps, engineer hidden crystalline symmetries and to switch on/off or left/right edge states depending on the polarization of the incident electric field. This opens a path toward exploiting features of nanoparticles for topology to go beyond analogues of condensed matter systems.

Advances and Prospects in Topological Nanoparticle Photonics.

Topological nanophotonics is a new avenue for exploring nanoscale systems from visible to THz frequencies, with unprecedented control. By embracing their complexity and fully utilizing the properties that make them distinct from electronic systems, we aim to study new topological phenomena. In this Perspective, we summarize the current state of the field and highlight the use of nanoparticle systems for exploring topological phases beyond electronic analogues. We provide an overview of the tools needed to capture the radiative, retardative, and long-range properties of these systems. We discuss the application of dielectric and metallic nanoparticles in nonlinear systems and also provide an overview of the newly developed topic of topological insulator nanoparticles. We hope that a comprehensive understanding of topological nanoparticle photonic systems will allow us to exploit them to their full potential and explore new topological phenomena at very reduced dimensions.

Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers.

The development of synthetic strategies to engineer π-conjugated polymers is of paramount importance in modern chemistry and materials science. Here we introduce a synthetic protocol based on the search for specific vibrational modes through an appropriate tailoring of the π-conjugation of the precursors, in order to increase the attempt frequency of a chemical reaction. First, we design a 1D π-conjugated polymer on Au(111), which is based on bisanthene monomers linked by cumulene bridges that tune specific vibrational modes. In a second step, upon further annealing, such vibrational modes steer the twofold cyclization reaction between adjacent bisanthene moieties, which gives rise to a long pentalene-bridged conjugated ladder polymer featuring a low bandgap. In addition, high resolution atomic force microscopy allows us to identify by atomistic insights the resonance form of the polymer, thus confirming the validity of the Glidewell and Lloyd´s rules for aromaticity. This on-surface synthetic strategy may stimulate exploiting previously precluded reactions towards π-conjugated polymers with specific structures and properties.