1.
Org Lett
; 12(22): 5178-81, 2010 Nov 19.
Artículo
en Inglés
| MEDLINE
| ID: mdl-20979412
RESUMEN
The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of tripyrrolidinophosphoric acid triamide (TPPA) is presented. Kinetic studies indicate that the SmI(2)/TPPA complex possesses reactivity greater than the complex formed between samarium diiodide and 4 equiv of HMPA. Examples of the use of SmI(2)/TPPA in synthesis are presented.