Green Copolymers and Nanocomposites from Myrcene and Limonene Using Algerian Nano-Clay as Nano-Reinforcing Filler.

In this work, we report a new facile method for the preparation of myrcene-limonene copolymers and nanocomposites using a Lewis acid as a catalyst (AlCl3) and organo-modified clay as a nano-reinforcing filler. The copolymer (myr-co-lim) was prepared by cationic copolymerization using AlCl3 as a catalyst. The structure of the obtained copolymer is studied and confirmed by Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, and Differential Scanning Calorimetry. By improving the dispersion of the matrix polymer in sheets of the organoclay, Maghnite-CTA+ (Mag-CTA+), an Algerian natural organophilic clay, was used to preparenanocomposites of linear copolymer (myr-co-lim). In order to identify and assess their structural, morphological, and thermal properties, the effect of the organoclay, used in varyingamounts (1, 4, 7, and 10% by weight), and the preparation process were investigated. The Mag-CTA+ is an organophylic montmorillonite silicate clay prepared through a direct exchange process in which they were used as green nano-reinforcing filler. The X-ray diffraction of the resulting nanocomposites revealed a considerable alteration in the interlayer spacing of Mag-CTA+. As a result, interlayer expansion and myr-co-lim exfoliation between layers of Mag-CTA+ were observed. Thermogravimetric analysis provided information on the synthesized nanocomposites' thermal properties. Fourier transform infrared spectroscopy and scanning electronic microscopy, respectively, were used to determine the structure and morphology of the produced nanocomposites (myr-co-lim/Mag). The intercalation of myr-co-lim in the Mag-CTA+ sheets has been supported by the results, and the optimum amount of organoclay needed to create a nanocomposite with high thermal stability is 10% by weight. Finally, a new method for the preparation of copolymer and nanocomposites from myrcene and limonene in a short reaction time was developed.

Synthesis and Characterization of Copolymers and Nanocomposites from Limonene, Styrene and Organomodified-Clay Using Ultrasonic Assisted Method.

In the present work, we report a simple synthesis method for preparation of copolymers and nanocomposites from limonene and styrene using clay as a catalyst. The copolymerization reaction is carried out by using a proton exchanged clay as a catalyst called Mag-H+. The effect of temperature, reaction time and amount of catalyst were studied, and the obtained copolymer structure (lim-co-sty) is characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (1H-NMR) and differential scanning calorimetry (DSC). The molecular weight of the obtained copolymer is determined by gel permeation chromatography (GPC) and is about 4500 g·mol-1. The (lim-co-sty/Mag 1%, 3%, 7% and 10% by weight of clay) nanocomposites were prepared through polymer/clay mixture in solution method using ultrasonic irradiation, in the presence of Mag-CTA+ as green nano-reinforcing filler. The Mag-CTA+ is organophilic silicate clay prepared through a direct exchange process, using cetyltrimethylammonuim bromide (CTAB). The prepared lim-co-sty/Mag nanocomposites have been extensively characterized by FT-IR spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM) and transmission electronic microscopy (TEM). TEM analysis confirms the results obtained by XRD and clearly show that the obtained nanocomposites are partially exfoliated for the lower amount of clay (1% and 3% wt) and intercalated for higher amounts of clay (7% and 10% wt). Moreover, thermogravimetric analysis (TGA) indicated an enhancement of thermal stability of nanocomposites compared with the pure copolymer.

Optical and structural properties of composites films based on Ce3+ -doped yttrium aluminium garnet nanoparticles embedded in polystyrene.

In the present work, attempts have been made to prepare scintillating nanoparticle composite films of Ce3+ -doped Y3 Al5 O12 (YAG:Ce) embedded in a polystyrene (PS) polymer. A YAG:Ce phosphor has been previously synthesized using the sol-gel method. YAG:Ce-PS composite films of 250 ± 30 µm thickness were prepared using a solvent casting procedure with different PS/solvent concentration and a different mass ratio between nanoparticles of YAG:Ce and PS. X-ray diffraction analysis confirmed that the YAG:Ce powders were successfully prepared. Using thermogravimetric analyses and differential scanning calorimetry, we found that the glass transition temperature (Tg) and thermal degradation were shifted to higher temperatures for composite films relative to pure PS. Photoluminescence showed the yellow emission of the Ce3+ -doped YAG phosphors, which was attributed to the 5d→4f transition of Ce3+ ion and the intensity of the emissions changed with the mass ratio of the YAG:Ce nanoparticles incorporated in the polymer and with the concentration of the polymer solution.

First data of statistic and ecological behavior of orthoptera insects in arid region (Southern West of Algeria).

The activity developed in vast areas of northwest africa causes serious invasions of different species of orthoptera insect which poses a great danger to agriculture and thus to nutrition of peoples and animals in general. In (Algeria), FAO considers the regions of naama, tindouf, adrar and bechar in Algeria as the theater of signaling of swarms and intervention. In this article, we want to shed light on the peculiarities of this insect (orthoptera), its statistics, its species and the families it belongs to in the arid region called naama (southwestern Algeria). The study of orthoptera in the arid region of naama (southern west of Algeria) conducted at three stations (Mecheria, Ben ammar) and the wetland of (Ain ben khelil) during the period from august 2015 until august 2017 allowed to identify nineteen (19) species divided into two sub-orders ensifera and caelifera. They are divided into five families (Tettigonidae, Gryllidae Pamphagidae, Acrididae, and Pyrgomorphidae). Acrididae family is the largest with five species. Oedipodinae subfamily is the most numerous genera and species it includes four (4) different types genders and seven species (7). The highest diversity index of the shannon-weaver is obtained at the wetland ain ben khelil is 2.12 bits, followed by the station of ben ammar with 2.06 bits and station of mecheria remains in third with 1.89 bit values of fairness are close to one corresponding to populations in balance entered them. The determination of species, genders and families of this population is based on several morphological criteria such as the shape of the pronotum, and the color of membranous wings and the shape of the hind legs.

Why orthoptera fauna resist of pesticide? First experimental data of resistance phenomena.

Orthoptera are capable of threat of agriculture, human health and resists to all pesticides used. This problem is become an objectif of many research's. Pesticide resistance is the adaptation of insects to this materials resulting in decreased susceptibility to that chemical. In other hand, insects develop a resistance through natural selection such chemically transformation, physiological phenomena and genetic. In our study, natural chitin was extracted from cuticle of orthoptera insect (southern of Algeria) using a chemical strategy consists on hydrochloric acid, sodium hydroxide and hydrogen peroxide. The average yield of extracted chitin (96.95% w) indicates that the cuticles of orthoptera are a rich source of chitin. Cuticle exhibit a heterogeneous morphology characterized by a compact structure with well-defined fibrous. For extracted chitin and after demineralization, we can appreciate important changes in the surface of material. We observed round shaped black spots indicated that they are composed almost exclusively by K2O and CaO (cuticle) in the other hand we observed several white taches behind black spots, here we suggest that white taches present chitin extracted. The most resistant orthoptera are the ones to survive and transform their properties by chemical process such as transformation of chitin to chitosan and physiological development such as age. In this study, we have found that the first generation has a great resistance to insecticides. After insecticide application we observed a descendant's resistance decreased a larger because sensitive insects have been selectively killed. After repeated applications resistant insects may comprise the minority. Finally we can said, insecticide resistance can be found in many types and we can conclude that physiological resistance and chemical resistance coexist together and cannot separate. In the physiological resistance, the insect populations may develop the ability to avoid or reduce lethal insecticide exposure. In contrast, chemical resistance refers to modification mechanisms, including reduced cuticle penetration and decreased or increased target site sensitivity. The extracted chitin sample and chitosan were characterized by several characterizations such as X-ray diffraction, scanning electron microscopy SEM, FTIR and 1HRMN spectroscopy.