Asunto(s)
Enfermedades Asintomáticas/epidemiología , Enfermedades Autoinmunes/epidemiología , Hipotiroidismo/epidemiología , Síndrome Metabólico/epidemiología , Obesidad/epidemiología , Enfermedades de la Tiroides/epidemiología , Adulto , Enfermedades Autoinmunes/etiología , China/epidemiología , Femenino , Humanos , Hipotiroidismo/etiología , Masculino , Síndrome Metabólico/complicaciones , Persona de Mediana Edad , Obesidad/complicaciones , Factores de Riesgo , Enfermedades de la Tiroides/etiología , Adulto JovenRESUMEN
Fe-Co-N-C electrocatalysts have proven superior to their counterparts (e.g. Fe-N-C or Co-N-C) for the oxygen reduction reaction (ORR). Herein, we report on a unique strategy to prepare Fe-Co-N-C-x (x refers to the pyrolysis temperature) electrocatalysts which involves anion-exchange of [Fe(CN)6 ]3- into a cationic CoII -based metal-organic framework precursor prior to heat treatment. Fe-Co-N-C-900 exhibits an optimal ORR catalytic performance in an alkaline electrolyte with an onset potential (Eonset : 0.97â V) and half-wave potential (E1/2 : 0.86â V) comparable to that of commercial Pt/C (Eonset =1.02â V; E1/2 =0.88â V), which outperforms the corresponding Co-N-C-900 sample (Eonset =0.92â V; E1/2 =0.84â V) derived from the same MOF precursor without anion-exchange modification. This is the first example of Fe-Co-N-C electrocatalysts fabricated from a cationic CoII -based MOF precursor that dopes the Fe element via anion-exchange, and our current work provides a new entrance towards MOF-derived transition-metal (e.g. Fe or Co) and nitrogen-codoped carbon electrocatalysts with excellent ORR activity.