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Chemosphere ; 138: 438-46, 2015 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-26160300

RESUMEN

Ambient levels and variability of major atmospheric halocarbons, i.e. CFC-12, CFC-11, CFC-113, CCl4, CH3CCl3, C2HCl3, and C2Cl4 in a major metropolis (Taipei, Taiwan) were re-investigated after fourteen years by flask sampling in 2012. Our data indicates that the variability expressed as standard deviations (SD) of CFC-113 and CCl4 remained small (2.0 ppt and 1.9 ppt, respectively) for the 10th-90th percentile range in both sampling periods; whereas the variability of CFC-12, CFC-11, C2HCl3, and C2Cl4 measured in 2012 became noticeably smaller than observed in 1998, suggesting their emissions were reduced over time. By comparing with the background data of a global network (NOAA/ESRL/GMD baseline observatories), the ambient levels and distribution of these major halocarbons in Taipei approximated those at a background site (Mauna Loa) in 2012, suggesting that the fingerprint of the major halocarbons in a used-to-be prominent source area has gradually approached to that of the background atmosphere.


Asunto(s)
Contaminantes Atmosféricos/análisis , Ciudades , Monitoreo del Ambiente , Adhesión a Directriz/estadística & datos numéricos , Hidrocarburos Halogenados/análisis , Cooperación Internacional , Atmósfera/química , Ozono/química , Taiwán
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