Fully-automated on-line solid phase extraction coupled to high-performance liquid chromatography-tandem mass spectrometric analysis at sub-ng/L levels of selected estrogens in surface water and wastewater.

A fully-automated on-line solid phase extraction liquid chromatographic/electrospray ionization tandem mass spectrometric method for the analysis of estrone (E1), 17-ß-estradiol (ß-E2), 17-α-ethinylestradiol (EE2), 17-α-estradiol (α-E2) and estriol (E3) in surface water and wastewater was developed. The method showed a very good linearity from 250 ng/L down to compound specific quantification limits, which were included between 0.25 and 2.00 ng/L. These limits were obtained with 2.5 mL aliquots of injected sample and the total analysis time per sample was slightly less than 10 min. Under these conditions, detection limits were 0.15 ng/L for E1, 0.31 ng/L for ß-E2, 0.52 ng/L for EE2, 0.59 ng/L for α-E2 and 0.95 ng/L for E3. The method reliability was tested on different kinds of real samples spiked with the estrogens, obtaining recoveries approximately included between 71 and 95%. The application to samples collected in rivers, lakes and wastewater treatment plants evidenced the presence of the investigated compounds at sub-ng/L or low ng/L concentration levels.

Membrane filtration and sonication for industrial wastewater reuse.

This paper presents an experimental study aimed at estimating the efficiency of the innovative process of ultrafiltration (UF) combined with sonication (Son.) for the refinement of treated effluent to be reused in wet textile processes. Such a novel approach, which has not yet been employed on a full industrial scale, has been experienced at pilot scale on the secondary effluent of the Baciacavallo wastewater treatment plant (WWTP), which treats part of the effluent from one of the largest textile industry districts in Italy. The combined treatment efficiency was assessed both on ozonated and non-ozonated Baciacavallo secondary effluent. The membrane filtration process was optimized in terms of running time, backwash, chemical addition and cleaning procedures. The sonication treatment was optimized on laboratory-scale with synthetic solutions (demineralized water added with dyestuffs) in terms of hydroxyl radicals formation rate, frequency, acoustic power, hydrogen peroxide addition, contact time and pH. The optimal conditions have been applied on the pilot-scale sonicator which was used in combination with the UF treatment. According to the experimental results, the best configuration within the Baciacavallo WWTP was the sonication of non-ozonated wastewater followed by the UF. The combined treatment guaranteed the compliance with the target values for wastewater reuse in wet textile industries. This study is part of the Research Project PURIFAST (Purification of industrial and mixed wastewater by combined membrane filtration and sonochemical technologies) LIFE + ENV/IT/000439.

Total and hexavalent chromium removal in a subsurface horizontal flow (h-SSF) constructed wetland operating as post-treatment of textile wastewater for water reuse.

In this study we investigated total and hexavalent chromium removal in an h-SSF constructed wetland (CW) planted with Phragmites australis and operating as post-treatment of effluent wastewater from an activated sludge plant serving the textile industrial district of Prato (Italy). Two measurement campaigns were carried out in 2006 and 2008-2010 in which more than 950 inlet and outlet samples were analyzed. When inlet and outlet concentrations were compared one to the other, the latter were found to be significantly lower than the former (p < 0.001); during the entire period of investigation, removal of hexavalent chromium equal to about 70% was achieved. Outlet concentrations ranged between values lower than the quantification limit (0.5 microg L(-1)) and 4.5 microg L(-1), and in all cases were therefore lower than the limit indicated for hexavalent chromium in the Italian regulation for water reuse (5 microg L(-1)). The comparison of the removal efficiencies achieved for hexavalent and trivalent chromium during the two campaigns suggested that the removal of the former can be sustained in the long term, while for the latter, the treatment efficiency is more sensitive to the age of the CW, being that it is it based on trivalent chromium retention in the reed bed.

Reuse of industrial wastewater for the irrigation of ornamental plants.

This paper describes the results of experimental activities carried out for verifying the possibility of reusing reclaimed wastewater originated from textile (70%) and domestic (30%) activities for the irrigation of container-grown ornamental shrubs. Aspects that concern the refinery treatment of reclaimed wastewater and the effect of irrigation on some ornamental plant species were investigated. An experimental site consisting of a refinery treatment pilot plant (filtration and disinfection) and an agronomic experimental area was set-up. The combined treatment of PAA and UV, used for the disinfection, showed to be very effective for inactivation of E. coli with most of PAA and UV dose combinations able to assure total inactivation. The plants (Buxus, Photinia, Pistacia and Viburnum), sprinkle and drip irrigated with well water (WW), reclaimed wastewater (RW) and a water mixed (MW) between reclaimed wastewater and well water (1:1 by vol), showed interesting results. A similar growth among different treatments was achieved for Buxus and Pistacia, while Viburnum and Photinia plants showed a higher sensibility to MW and RW. Photinia, in particular, turned out to be very sensitive to sprinkle irrigation with the reclaimed water, while the drip irrigation had no such bad effects, as reported in previous works.