The international reference system for beta-particle emitting radionuclides: Validation through the pilot study CCRI(II)-P1.Co-60.

The Bureau International des Poids et Mesures (BIPM) is developing a new transfer instrument to extend its centralized services for assessing the international equivalence of radioactive standards to new radionuclides. A liquid scintillation counter using the triple/double coincidence ratio method is being studied and tested in the CCRI(II)-P1.Co-60 pilot study. The pilot study, involving 13 participating laboratories with primary calibration capabilities, validated the approach against the original international reference system based on ionization chambers, which has been in operation since 1976. The results are in agreement and an accuracy suitable for purpose, below 5×10-4, is achieved. The pilot study also reveals an issue when impurities emitting low-energy electrons are present in the standard solution, which have a different impact on liquid scintillation counting compared to other primary measurement methods.

Liquid scintillation counting of electrons from internal conversion for quantifying 109Cd activity using a 3-photomultiplier tube system and a specific spectral unfolding.

As part of the international key comparison CCRI(II)-K2.Cd-109.2021, the BIPM has implemented a specific method to measure the activity of 109Cd solution - a key radionuclide in the calibration of gamma-ray spectrometers. The counting of electrons from internal conversion was carried out using a liquid scintillation counter based on 3-photomultiplier tubes. In this technique, a major part of the uncertainty comes from the overlap between the conversion electrons peak and the peak at lower energy from the other products of the decay. As a result, the energy resolution that the liquid scintillation system can achieve is the most critical challenge to achieving a precise measurement. The study demonstrates the advantage of producing a sum of the signal from the three photomultipliers to enhance the energy resolution and limit the peak overlap. In addition, the spectrum has been processed by a specific unfolding approach to properly separate the spectral components. Thanks to the method introduced in this study, an activity estimation has been realized with a relative standard uncertainty of 0.5%.

Test of a digitizer to process the pulse signal from the 3 photomultiplier tubes of a TDCR liquid scintillation counter.

The BIPM is developing a new service for international key comparisons in radionuclide metrology. The system, called ESIR, is based on a liquid scintillation counter using the Triple-to-Double Coincidence Ratio (TDCR) technique. The aim is to produce an international reference that can be reproduced over several decades of time in order to compare the calibration capabilities of National Metrology Institutes (NMIs). The maintainability of the electronics performing the signal processing is a challenge. To ensure the long-term sustainability of the electronics, the strategy is to set up redundant systems including at least one digital electronics module. The analogue modules developed in the 1990s and 2000s are less and less maintained and digital electronics are increasingly available on the market. In this context, a digitizer was tested and its suitability for the TDCR measurements compared to the currently used module based on an analogue front-end. This first implementation directly linking the photomultiplier anode to the CAEN digitizer without any analogue preconditioning shows a significant loss of detection efficiency and a lower signal to noise ratio observed on distributions of single photoelectrons. Although the TDCR method can correct for these efficiency losses, the loss of symmetry between the channels is too great to provide a sufficiently robust measurement. The use of low-pass filters upstream of the ADC will be considered to make this digital measurement system more reliable.

HPGe/BGO Compton suppression system: Monte Carlo study of radiation monitoring system for failed fuel detection in sodium-cooled fast reactors.

Fuel failures detection and monitoring is a key issue in sodium-cooled fast reactor operation. This detection is based on monitoring the signal of fission products using dedicated radiation monitoring systems based on gamma spectrometry or neutron counting. In this context, the French Alternative Energies and Atomic Energy Commission (CEA) investigates and developpes a Compton suppression system composed by a high-purity germanium diode, a bismuth germanate scintillator and a dedicated digital signal processing allowing filtering coincidences. This approach enables the Compton noise to be filtered without impacting the useful signal from short-lived radioisotopes. Through a calculation scheme based on a validated MCNP6 model of the detector. It was demonstrated that the sodium degassing is a mandatory option reducing the minimal detectable activities of fission products by a factor of up to 27. The Compton suppression system leads to an additional minimization of minimum detectable activities up to a factor of 4 enabling the ease measurement of the 89Kr safety indicator.

On the photomultiplier-tube asymmetry in TDCR systems.

The responses of the three photomultiplier tubes (PMTs) in a triple-to-double coincidence ratio (TDCR) liquid scintillation (LS) system are often not identical. Such asymmetries can have a significant influence on activity determinations. The problem is often solved by means of a minimization algorithm which can easily be applied when analytical methods are used for the efficiency calculation, as is usually done for pure beta emitters. However, for radionuclides with more complex decay schemes, the counting efficiencies are often calculated with stochastic methods and the computation of the required corrections becomes very challenging. This paper presents a new numerical method to overcome the asymmetry problem for such complex decays and a comprehensive study on 55Fe is described in detail. For the measurements, the asymmetry was varied by means of grey filter films which were placed in front of one of the photomultiplier tubes. In the case of the pure electron-capture (EC) radionuclide 55Fe, the asymmetry can also be taken into account with a very simple correction which is derived assuming monoenergetic emissions. This work is also of great importance for the planned extension of the International Reference System (SIR) at the BIPM which will be used for international comparisons in radionuclide metrology.

N-(2-Ethylhexyl)carbazole: A New Fluorophore Highly Suitable as a Monomolecular Liquid Scintillator.

The synthesis, photophysical properties, and applications in scintillation counting of N-(2-ethylhexyl)carbazole (EHCz) are reported. This molecule displays all of the required characteristics for an efficient liquid scintillator (emission wavelength, scintillation yield), and can be used without any extra fluorophores. Thus, its scintillation properties are discussed, as well as its fast neutron/gamma discrimination. For the latter application, the material is compared with the traditional liquid scintillator BC-501 A, and other liquid fluorescent molecules classically used as scintillation solvents, such as xylene, pseudocumene (PC), linear alkylbenzenes (LAB), diisopropylnaphthalene (DIN), 1-methylnaphthalene (1-MeNapht), and 4-isopropylbiphenyl (iPrBiph). For the first time, an excimeric form of a molecule has been advantageously used in scintillation counting. A moderate discrimination between fast neutrons and gamma rays was observed in bulk EHCz, with an apparent neutron/gamma discrimination potential half of that of BC-501 A.