RESUMEN
Adsorbents play a vital role in responding to marine oil spills, yet effectively cleaning up viscous oil spills remains a technical challenge. Herein, we present a superhydrophobic oil-adsorbing felt prepared using melt-blown technology and functionally enhanced with a photoelectric composite CNT/PANI coating for effectively cleaning up high-viscosity oil spills. By virtue of its superior solar/Joule heating ability and thermally conductive fiber network, p-CNT/PANI@PP notably reduced crude oil viscosity and enhanced the oil diffusion coefficient within pores. Leveraging primarily solar heating and supplemented by Joule heating, p-CNT/PANI@PP demonstrates an impressive in-situ adsorption rate of up to 560 g/h for ultra-high-viscosity crude oil (c.a. 138000 mPa·s), alongside an adsorption capacity of 15.57 g/g. This measure enables efficient viscosity reduction and continuous day-and-night recovery of viscous crude oil, addressing the challenges posed by seasonal fluctuations in seawater temperature and adverse weather conditions. Moreover, a conveyorized collector integrated with an oil-adsorbing felt realizes continuous recovery of viscous oil spills with speed control to tackle varying thicknesses of oil film. Given the top-down material design, superior functionality, and applicability to applications, this work provides a comprehensive and feasible solution to catastrophic large-area viscous oil spills.
RESUMEN
Rapid and efficient recovery of oil spill is the key link for oil spill remediation, and also a great challenge. Here, the organogelator-polymerized porous matrix composed of adsorbents and organogelators can provide a new strategy for solving this problem. The gelling mechanism of aluminum 12-hydroxystearate (Al HSA) to form spherical nano micelles in solvents was investigated via UV-vis, FT-IR, and XRD. A creative method for aluminum soap-lignin gelator (OTS-AL/Al HSA) syntheses was put forward through the saponification of 12-hydroxystearic acid (HSA) and lignin via epichlorohydrin (ECH) crosslinking. By adjusting the ECH content, the growth of Al HSA nanoparticles (15-40 nm) on lignin can be realized, and the accordingly increased roughness endowed gelator with better hydrophobicity (WCA of 134.6°) before octadecyltrichlorosilane (OTS) modification. Thanks to the porous structures, the gelator powder exhibited a high sorption capacity in the range of 3.5-5.2 g g-1 for oils and organic solvents. Rheological studies demonstrated high mechanical strength of gels (>1.6 × 105 pa) and the gelator still retained 70% sorption capacity after 6 gelation-distillation cycles. The gelation characteristics of OTS-AL/Al HSA were attributed to the rapid sorption of oils by lignin and the self-assembly of Al HSA nano micelles on lignin to form an aggregated network structure trapping oils, thus realizing the synergistic effect of oil sorption-gelation.
