RESUMEN
A new rapid protocol for 226Ra separation and preconcentration in natural water samples was developed before its determination by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). For this purpose, the commercially available Ra specific resin AnaLig® Ra-01 was used. This resin shows a high selectivity for radium in a large range of acid concentrations and no affinity or possible elution of 226Ra interfering elements. The distribution coefficients of Ra and other elements over a wide range of acid (HCl and HNO3) concentrations were obtained. Due to the high radium selectivity, the new developed protocol uses only 50â¯mg of dry resin and its performance was evaluated using 100â¯mL of three natural waters with different ionic strengths, spiked with a known quantity of 226Ra. Radium was successfully separated and preconcentrated yielding recoveries ranging between 72% and 86%. In parallel with the characterisation of the resin sorption properties, a detailed study of polyatomic interferences was performed on our ICP-MS allowing to identify the prominent elements favouring interferences at m/zâ¯=â¯226. Furthermore, a 226Ra sensitivity comparison between different ICP-MS instruments and configurations was done in order to determine high sensitivity conditions for radium analysis.