Mixing Rules for Left-Handed Disordered Metamaterials: Effective-Medium and Dispersion Properties.

Left-handed materials are known to exhibit exotic properties in controlling electromagnetic fields, with direct applications in negative reflection and refraction, conformal optical mapping, and electromagnetic cloaking. While typical left-handed materials are constructed periodic metal-dielectric structures, the same effect can be obtained in composite guest-host systems with no periodicity or structural order. Such systems are typically described by the effective-medium approach, in which the components of the electric permittivity tensor are determined as a function of individual material properties and doping concentration. In this paper, we extend the discussion on the mixing rules to include left-handed composite systems and highlight the exotic properties arising from the effective-medium approach in this framework in terms of effective values and dispersion properties.

Towards High-Efficiency Photon Trapping in Thin-Film Perovskite Solar Cells Using Etched Fractal Metadevices.

Reflective loss is one of the main factors contributing to power conversion efficiency limitation in thin-film perovskite solar cells. This issue has been tackled through several approaches, such as anti-reflective coatings, surface texturing, or superficial light-trapping metastructures. We report detailed simulation-based investigations on the photon trapping capabilities of a standard Methylammonium Lead Iodide (MAPbI3) solar cell, with its top layer conveniently designed as a fractal metadevice, to reach a reflection value R<0.1 in the visible domain. Our results show that, under certain architecture configurations, reflection values below 0.1 are obtained throughout the visible domain. This represents a net improvement when compared to the 0.25 reflection yielded by a reference MAPbI3 having a plane surface, under identical simulation conditions. We also present the minimum architectural requirements of the metadevice by comparing it to simpler structures of the same family and performing a comparative study. Furthermore, the designed metadevice presents low power dissipation and exhibits approximately similar behavior regardless of the incident polarization angle. As a result, the proposed system is a viable candidate for being a standard requirement in obtaining high-efficiency perovskite solar cells.

Towards Highly Efficient Nitrogen Dioxide Gas Sensors in Humid and Wet Environments Using Triggerable-Polymer Metasurfaces.

We report simulations on a highly-sensitive class of metasurface-based nitrogen dioxide (NO2) gas sensors, operating in the telecom C band around the 1550 nm line and exhibiting strong variations in terms of the reflection coefficient after assimilation of NO2 molecules. The unit architecture employs a polymer-based (polyvinylidene fluoride-PVDF or polyimide-PI) motif of either half-rings, rods, or disks having selected sizes and orientations, deposited on a gold substrate. On top of this, we add a layer of hydrophyllic polymer (POEGMA) functionalized with a NO2-responsive monomer (PAPUEMA), which is able to adsorb water molecules only in the presence of NO2 molecules. In this process, the POEGMA raises its hidrophyllicity, while not triggering a phase change in the bulk material, which, in turn, modifies its electrical properties. Contrary to absorption-based gas detection and electrical signal-based sensors, which experience considerable limitations in humid or wet environments, our method stands out by simple exploitation of the basic material properties of the functionalized polymer. The results show that NO2-triggered water molecule adsorption from humid and wet environments can be used in conjunction with our metasurface architecture in order to provide a highly-sensitive response in the desired spectral window. Additionally, instead of measuring the absorption spectrum of the NO2 gas, in which humidity counts as a parasitic effect due to spectral overlap, this method allows tuning to a desired wavelength at which the water molecules are transparent, by scaling the geometry and thicknesses of the layers to respond to a desired wavelength. All these advantages make our proposed sensor architecture an extremely-viable candidate for both biological and atmospheric NO2 gas-sensing applications.

Spectral Response and Wavefront Control of a C-Shaped Fractal Cadmium Telluride/Silicon Carbide Metasurface in the THz Bandgap.

We report theoretical investigations on the spectral behavior of two fractal metasurfaces, performed in the 3-6 THz frequency window (5-10 µm equivalent wavelength window), under illumination with both linear and circular polarization state fields. Both metasurfaces stem from the same tree-like structure, based on C-shaped elements, made of cadmium telluride (CdTe), and deposited on silicon carbide (SiC) substrates, the main difference between them being the level of structural complexity. The simulated spectral behavior of both structures indicates the tunability of the reflection spectrum by varying the complexity of the tree-like structure.

An Extended k-Surface Framework for Electromagnetic Fields in Artificial Media.

The complete understanding of the electromagnetic field characteristics in artificially created bulk or thin media is essential to the efficient harnessing of the multitude of linear and nonlinear effects resulting from it. Due to the fact that recently developed artificial metastructures exhibit controllable electric and magnetic properties that are completely different from natural ones, the spectrum of behavior resulting from subjecting such media to electromagnetic fields has to be revisited. In this paper, we introduce a k-surface framework that offers complete information on the dispersion properties of media with designer electric and magnetic responses with positive and negative values, as well as for the coupling between the two. The extension from the classic k-surface case resides in the consideration of magnetic and bianisotropic materials with positive and negative permittivity and permeability values, as well as the introduction of the chirality coefficient.To illustrate the applicability of our framework, we have investigated the conditions to obtain collinear second harmonic generation in the case of artificial media with positively and negatively valued electric and magnetic responses. As expected, the phase matching tuning curves, defined as the intersections between the k-surfaces at both frequencies, are significantly modified with respect to the classic ones.

Non-Layered Gold-Silicon and All-Silicon Frequency-Selective Metasurfaces for Potential Mid-Infrared Sensing Applications.

We report simulations on the spectral behavior of non-layered gold-silicon and all-silicon frequency-selective metasurfaces in an asymmetric element configuration in the mid-infrared spectral window of 5-5.8 µm. The non-layered layout is experimentally feasible due to recent technological advances such as nano-imprint and nano-stencil lithography, and the spectral window was chosen due to the multitude of applications in sensing and imaging. The architecture exhibits significant resonance in the window of interest as well as extended tunability by means of variation of cell element sizes and relative coordinates. The results indicate that the proposed metasurface architecture is a viable candidate for mid-infrared absorbers, sensors and imaging systems.

Polyvinylidene Fluoride-Based Metasurface for High-Quality Active Switching and Spectrum Shaping in the Terahertz G-Band.

We report theoretical investigations performed in the terahertz G-band, in the 228-232 GHz spectral window for a piezoelectrically-responsive ring-cone element metasurface composed of polyvinylidene fluoride (PVDF)/Silicon and PVDF/Silica glass. The choosing of this spectral window is motivated by a multitude of applications in terahertz detection and terahertz imaging, that commonly make use of this band. The uniqueness of the envisioned architecture resides in the combination between the readily-available polyvinylidene fluoride polymer and silicon/silica glass substrates, together with the introduction of an extra degree of freedom, in the form of a ring-cone architecture, and the active control of the geometric sizes through the longitudinal piezoelectric effect exhibited by the polymer. The spectral response of the metasurface is dependent on the combination between the polymer elements and the substrate, and ranges from near-zero absorption switching to a resonant behavior and significant absorption. The interaction between the electromagnetic field and the polymer-based metasurface also modifies the phase of the reflected and transmitted waves over a full 2π range, permitting complete control of the electric field polarization. Moreover, we take advantage of the longitudinal piezoelectric effect of PVDF and analyze the spectrum shaping capability of the polymer-based metasurface. Our analysis highlights the capability of the proposed architecture to achieve complete electric field polarization control, near-zero optical switching and resonant behavior, depending on the geometries and sizes of the architecture elements resulting from construction considerations and from the externally applied voltages through the piezoelectric effect.

Bifunctional Metamaterials Using Spatial Phase Gradient Architectures: Generalized Reflection and Refraction Considerations.

We report the possibility of achieving normal-incidence transmission at non-normal incidence angles using thin interfaces made of metasurface structures with an appropriately-designed positive spatial phase distributions. The reported effect represents a consequence of generalized reflection and refraction, which, although having been studied for discovering exotic effects such as negative refraction, to the best of our knowledge fails to address normal incidence conditions in positive phase distribution and its underlying consequences. Normal-incidence conditions can be angle-tuned by modifying the vales of the phase distribution gradients. Furthermore, for configurations around the normal-incidence angles, the metasurface will exhibit a bifunctional behavior-either divergent or convergent. All these properties are essential for applications such as optical guiding in integrated optics, wave front sensing devices, polarization controllers, wave front-to-polarization converters, holographic sensors, and spatially-resolved polarization measurement.

Dynamic behavior of nematic liquid crystal mixtures with quantum dots in electric fields.

The dynamic behavior of a mixture consisting of liquid crystalline 4-cyano-4'-pentylbiphenyl (5CB) and CdSe/ZnS quantum dots in electric fields was theoretically studied. The model was based on elastic continuum theory considering the interaction of the nematic molecules with the surrounding molecules, with the quantum dots and with the electric field. Experimental data obtained by dynamic measurements on a sample containing 0.89% (mass fraction) of CdSe/ZnS quantum dots revealed a decrease of the relaxation time compared to pure 5CB.

Electrical properties of a liquid crystal dispersed in an electrospun cellulose acetate network.

Electro-optical devices that work in a similar fashion as PDLCs (polymer-dispersed liquid crystals), produced from cellulose acetate (CA) electrospun fibers deposited onto indium tin oxide coated glass and a nematic liquid crystal (E7), were studied. CA and the CA/liquid crystal composite were characterized by multiple investigation techniques, such as polarized optical microscopy, dielectric spectroscopy and impedance measurements. Dielectric constant and electric energy loss were studied as a function of frequency and temperature. The activation energy was evaluated and the relaxation time was obtained by fitting the spectra of the dielectric loss with the Havriliak-Negami functions. To determine the electrical characteristics of the studied samples, impedance measurements results were treated using the Cole-Cole diagram and the three-element equivalent model.