Isotopic composition and hydrogeochemistry of a periglacial Andean catchment and its relevance in the knowledge of water resources in mountainous areas.

Glacial and periglacial basins contain the largest reserves of fresh water in the world. These areas are extremely sensitive to global warming and climate change. The dry Andes of South America are characterized by large periglacial areas. This study focuses on the water isotopic composition and hydrochemistry of a typical periglacial environment of the Andes, in the Vallecitos catchment (2400-5500 m a.s.l.), Cordillera Frontal, Argentina. Detailed fieldwork was conducted between 2013 and 2017 with 240 samples collected for major ions and physicochemical parameters, and 67 samples analysed for 2H and 18O. The chemical composition of precipitation is typical Ca-HCO3, while streams and groundwaters are Ca-MgSO4 type. The isotope content of precipitation shows a wide dispersion. The snow samples are in general more depleted than the rainfall. Some springs vary their composition seasonally, associated to the melting of perennial snow patches. In general, all samples from the upper basin present depleted isotope contents related to recharge at higher altitudes, whereas samples from the lower basin show more enriched values. Intermediate compositions reflect the melting of snow and degrading ice-rich permafrost. These results will give a better understanding of the dynamics of water to manage water resources.

Spatial distribution of electrical conductivity and stable isotopes in groundwater in large catchments: a geostatistical approach in the Quequén Grande River catchment, Argentina.

Stable isotopes and electrical conductivity in groundwater were used as natural tracers to adjust the hydrogeological conceptual model in one of the largest catchments within the inter-mountainous Pampa plain, Argentina. Geostatistical tools were used to define the model that best fitted the spatial distribution of each tracer, and information was obtained in areas where there was a lack of data. The conventional isotopic analysis allowed the identification of three groundwater groups with different isotopic fingerprints. One group containing 56% of the total groundwater samples suggested a well-mixed system and soil infiltration precipitation as the main recharge source to the aquifer. The other two groups included samples with depleted (25.5%) and enriched (18.5%) isotopic compositions, respectively. The combination of δ(18)O, δ(2)H and electrical conductivities maps suggested ascending regional flows and water transfer from the Quequén Grande River catchment to the Moro creek. The spatial interpretation of these tracers modified the conceptual hydrogeological model of the Quequén Grande River.

The role of evapotranspiration in the groundwater hydrochemistry of an arid coastal wetland (Península Valdés, Argentina).

Coastal wetlands are complex hydrogeological systems, in which saline groundwater usually occurs. Salinity can be attributed to many origins, such as dissolution of minerals in the sediments, marine contribution and evapotranspiration, among others. The aim of this paper is to evaluate the processes that condition the hydrochemistry of an arid marsh, Playa Fracasso, located in Patagonia, Argentina. A study of the dynamics and geochemistry of the groundwater was carried out in each hydrogeomorphological unit, using major ion and isotope ((18)O and (2)H) data, soil profiles descriptions and measurements, and recording of water tables in relation to the tidal flow. Water balances and analytical models based on isotope data were used to quantify the evaporation processes and to define the role of evaporation in the chemical composition of water. The results obtained show that the groundwater salinity of the marsh comes mainly from the tidal inflow, to which the halite and gypsum dissolution is added. These mineral facies are the result of the total evaporation of the marine water flooding that occurs mostly at the spring high tides. The isotope relationships in the fan and bajada samples show the occurrence of evaporation processes. Such processes, however, are not mainly responsible for the saline content of groundwater, which is actually generated by the dissolution of the typical evaporite facies of the arid environment sediments. It is concluded that the evapotranspiration processes condition groundwater quality. This is not only due to the saline enrichment caused by the evapotranspiration of shallow water, but also because such processes are the main drivers of the formation of soluble salts, which are then incorporated into the water by groundwater or tidal flow.

Hydrogeochemical and isotopic characterisation of groundwater in a sand-dune phreatic aquifer on the northeastern coast of the province of Buenos Aires, Argentina.

This contribution presents the hydrochemical and isotopic characterisation of the phreatic aquifer located in the Partido de la Costa, province of Buenos Aires, Argentina. In the sand-dune barrier geomorphological environment, groundwater is mainly a low-salinity Ca-HCO3 and Na-HCO3-type, being in general suitable for drinking, whereas in the continental plain (silty clay sediments), groundwater is a Na-Cl type with high salinity and unsuitable for human consumption. The general isotopic composition of the area ranges from-6.8 to-4.3 ‰ for δ(18)O and from-39 to-21 ‰ for δ(2)H, showing that rainwater rapidly infiltrates into the sandy substrate and reaches the water table almost without significant modification in its isotopic composition. These analyses, combined with other chemical parameters, made it possible to corroborate that in the eastern area of the phreatic aquifer, there is no contamination from marine salt water.

Arsenic and associated trace-elements in groundwater from the Chaco-Pampean plain, Argentina: results from 100 years of research.

The Chaco-Pampean plain, Argentina, is a vast geographical unit (1,000,000 km²) affected by high arsenic (As) concentrations in universal oxidizing groundwater. The socio-economic development of the region is restricted by water availability and its low quality caused by high salinity and hardness. In addition, high As and associated trace-elements (F, U, V, B, Se, Sb, Mo) concentrations of geogenic origin turn waters unsuitable for human consumption. Shallow groundwater with high As and F concentrations (ranges: <10-5300 µg As/L; 51-7,340 µg F/L) exceeding the WHO guideline values (As: 10 µg/L; F: 1,500 µg/L) introduces a potential risk of hydroarsenicism disease in the entire region and fluorosis in some areas. The rural population is affected (2-8 million inhabitants). Calcareous loess-type sediments and/or intercalated volcanic ash layers in pedosedimentary sequences hosting the aquifers are the sources of contaminant trace-elements. Large intra and interbasin variabilities of trace-element concentrations, especially between shallow and deep aquifers have been observed. All areas of the Chaco-Pampean plain were affected in different grades: the Chaco-Salteña plain (in the NNE of the region) and the northern La Pampa plain (in the center-south) have been shown the highest concentrations. The ranges of As and F contents in loess-sediments are 6-25 and 534-3340 mg/kg, respectively in the Salí River basin. Three key processes render high As concentrations in shallow aquifers: i) volcanic glass dissolution and/or hydrolysis and leaching of silicates minerals hosted in loess; ii) desorption processes from the surface of Al-, Fe- and Mn-oxi-hydroxides (coating lithic fragments) at high pH and mobilization as complex oxyanions (As and trace elements)in Na-bicarbonate type groundwaters; and iii) evaporative concentration in areas with semiarid and arid climates. Local factors play also an important role in the control of high As concentrations, highly influenced by lithology-mineralogy, soils-geomorphology, actual climate and paleoclimates, hydraulic parameters, and residence time of groundwaters.