Preparation and characterization of imidacloprid lignin-polyethylene glycol matrices coated with ethylcellulose.

Imidacloprid, a systemic insecticide that has a water solubility of 610 mg L(-1), has been formulated in lignin-polyethylene glycol matrices by a melting process. This formulation was coated in a Wurster type fluidized-bed equipment using ethylcellulose and dibutyl sebacate. Imidacloprid has been entrapped, with an entrapment efficiency higher than 87% in all cases. Thermogravimetric analysis, differential scanning calorimetry, and Fourier transformed infrared spectroscopy studies indicate the stability and compatibility of polymers and imidacloprid. Scanning electron microscopy images show a homogeneous film of ethylcellulose in coated formulations. From T(50) values (the time taken for 50% of the active ingredient to be released into water), the release rate of imidacloprid is controlled by changing the thickness of the coating film and modifying its surface properties by adding a plasticizer. T(50) values, ranging from 3.02 to 168.6 h, allow supplying the appropriate amount of imidacloprid in each specific agronomic practice to increase the efficiency of this bioactive material and minimize the risk of environmental pollution.

Prevention of chloridazon and metribuzin pollution using lignin-based formulations.

The herbicides chloridazon and metribuzin, identified as groundwater pollutants, were incorporated in lignin-based granules with different sizes to obtain controlled release formulations (CRFs) and reduce water pollution risk. Kinetics release tests in water and soil showed that the release rate of both from CRFs diminished in comparison to technical products. A linear correlation was obtained between the time taken for 50% of the active ingredient to be released (T(50)) into water and granule size of the CRFs. Besides, a linear correlation was reached between T(50) values in water and soil. Mobility experiments carried out in calcareous soil show that the use of lignin-based CRFs reduces the presence of both herbicides in the leachate compared to the technical grade products. The set of experiments developed in this research can be useful to design, prepare and evaluate formulations with CR properties which can reduce the pollution derived from the use of herbicides.

Use of ethylcellulose to control chlorsulfuron leaching in a calcareous soil.

Controlled release formulations (CRFs) have been researched to reduce the water-polluting risk derived from the use of conventional formulations of chlorsulfuron. Coated chlorsulfuron granules were produced in a Wuster-type fluidized-bed equipment using two different amounts of ethylcellulose. The highest one was modified by the addition of a plasticizer such as dibutyl sebacate. The encapsulation efficiency and morphological properties of coated granules having been studied, the chlorsulfuron kinetic release in water was studied. In addition, the mobility of chlorsulfuron in a calcareous soil was finally carried out. High encapsulation efficiency was obtained, being nearly 100% in all cases. SEM pictures show a homogeneous film in coated CRFs; thickness oscillates between 23.32 microm for the system prepared with a 10% of ethylcellulose and 32.61 microm for the system prepared with a 20% ethylcellulose plus plasticizer. The rate of chlorsulfuron release from coated CRFs is diminished in all cases in relation to chlorsulfuron commercial formulation, the latter being completely dissolved in <1 h, but it took at least 50 days to release 90% of chlorsulfuron from the formulation coated with a 20% ethylcellulose plus plasticizer. Using a generic equation, the time taken for 50% of the active ingredient to be released into water (t(50)) was calculated. From the analysis of the t(50) values, it can be deduced that the release rate of chlorsulfuron can be mainly controlled by changing the thickness of the coating film, by modifying the surface properties of the coating film, and by adding a plasticizer. Mobility experiments carried out in calcareous soil show that the use of coated CRFs reduces the presence of chlorsulfuron in the leachate compared to commercial formulation.