Tropopause-Level NOx in the Asian Summer Monsoon.

Deep convection within the Asian summer monsoon (ASM) transports surface level air into the upper troposphere-lower stratosphere (UTLS). This work aims to understand the distribution of NO2, NO, and NOx in the UTLS ASM anticyclone from satellite measurements. Observations of NO2 from the Optical Spectrograph and InfraRed Imager System, the Atmospheric Chemistry Experiment - Fourier Transform Spectrometer (ACE-FTS), and the Stratospheric Aerosol and Gas Experiment III on the International Space Station are considered. The PRATMO photochemical box model is used to quantify the NOx photochemistry, and to derive the NOx concentration using OSIRIS NO2 and O3 observations. The satellite data show a relative minimum in NO2 over the ASM in the summer months, while the corresponding NO and NOx anomalies are elevated, mainly due to low O3 and cold temperatures within the ASM. The observations within the ASM show reasonable agreement to simulations from the Whole Atmosphere Community Climate Model.

On the stratospheric chemistry of midlatitude wildfire smoke.

SignificanceLarge wildfires have been observed to inject smoke into the stratosphere, raising questions about their potential to affect the stratospheric ozone layer that protects life on Earth from biologically damaging ultraviolet radiation. Multiple observations of aerosol and NO2 concentrations from three independent satellite instruments are used here together with model calculations to identify decreases in stratospheric NO2 concentrations following major Australian 2019 through 2020 wildfires. The data confirm that important chemistry did occur on the smoke particle surfaces. The observed behavior in NO2 with increasing particle concentrations is a marker for surface chemistry that contributes to midlatitude ozone depletion. The results indicate that increasing wildfire activity in a warming world may slow the recovery of the ozone layer.

A balloon-borne imaging Fourier transform spectrometer for atmospheric trace gas profiling.

The upper troposphere and lower stratosphere (UTLS) region is a highly variable region of the atmosphere and critical for understanding climate. Yet, it remains undersampled in the observational satellite record. Due to recent advances in interferometer and infrared detection technologies, imaging Fourier transform spectrometer (FTS) technology has been identified as a feasible remote sensing approach to obtain the required precision and spatial resolution of atmospheric trace gas composition in the UTLS. Building on the success of instruments such as the Michelson Interferometer for Passive Atmospheric Sounding and gimbaled limb observer for radiance imaging of the atmosphere, the limb imaging Fourier transform spectrometer experiment (LIFE) instrument, of which this paper details the design and performance, is a balloon-borne infrared imaging FTS developed as an early prototype of a low earth orbit satellite instrument. LIFE is constructed primarily with commercially available off-the-shelf components, with a design emphasis on greatly reducing the complexity of the instrument, particularly the cooling requirements, with a minimal reduction in information gain on the target atmospheric greenhouse gases of water vapor, methane, ozone, and nitrous oxide. The developed instrument was characterized through a series of thermal and vacuum tests and validated through a successful demonstration balloon flight during the 2019 Strato-Science campaign in Canada. In the calibration of the data from the balloon flight, an issue was identified regarding a lack of knowledge in the emissivity of the on-board blackbody calibration sources. These systematic effects were minimized through the application of an emissivity ratio determined from the characterization tests where a wider range of known blackbody temperatures were available. Despite this identified calibration issue, the results demonstrate that the instrument is capable of meeting primary performance requirements for trace gas retrievals of the target atmospheric species.

High resolution mapping of nitrogen dioxide with TROPOMI: First results and validation over the Canadian oil sands.

TROPOMI, on-board the Sentinel-5 Precursor satellite is a nadir-viewing spectrometer measuring reflected sunlight in the ultraviolet, visible, near-infrared, and shortwave infrared spectral range. From these spectra several important air quality and climate-related atmospheric constituents are retrieved at an unprecedented high spatial resolution, including nitrogen dioxide (NO2). We present the first retrievals of TROPOMI NO2 over the Canadian Oil Sands, contrasting them with observations from the OMI satellite instrument, and demonstrate its ability to resolve individual plumes and highlight its potential for deriving emissions from individual mining facilities. Further, the first TROPOMI NO2 validation is presented, consisting of aircraft and surface in-situ NO2 observations, as well as ground-based remote-sensing measurements between March and May 2018. Our comparisons show that the TROPOMI NO2 vertical column densities are highly correlated with the aircraft and surface in-situ NO2 observations, and the ground-based remote-sensing measurements with a low bias (15-30 %) over the Canadian Oil Sands. PLAIN LANGUAGE SUMMARY: Nitrogen dioxide (NO2) is a pollutant that is linked to respiratory health issues and has negative environmental impacts such as soil and water acidification. Near the surface the most significant sources of NO2 are fossil fuel combustion and biomass burning. With a recently launched satellite instrument (TROPOspheric Monitoring Instrument; TROPOMI) NO2 can be measured with an unprecedented combination of accuracy, spatial coverage, and resolution. This work presents the first TROPOMI NO2 measurements near the Canadian Oil Sands and shows that these measurements have an outstanding ability to detect NO2 on a very high horizontal resolution that is unprecedented for satellite NO2 observations. Further, these satellite measurements are in excellent agreement with aircraft and ground-based measurements.