Insights into isotherms, kinetics, and thermodynamics of adsorption of acid blue 113 from an aqueous solution of nutraceutical industrial fennel seed spent.

Research studies have been carried out to accentuate Fennel Seed Spent, a by-product of the Nutraceutical Industry, as an inexpensive, recyclable and operational biosorbent for bioremediation of Acid Blue 113 (AB113) in simulated water-dye samples and textile industrial effluent (TIE). The physical process of adhesion of AB113 on the surface of the biosorbent depends on various parameters, such as the initial amount of the dye, amount and expanse of the biosorbent particles, pH of the solution and temperature of the medium. The data obtained was analyzed using three two-parameter and five three-parameter adsorption isotherm models to glean the adsorbent affinities and interaction mechanism of the adsorbate molecules and adsorbent surface. The adsorption feature study is conducted employing models of Weber-Morris, pseudo 1st and 2nd order, diffusion film model, Dumwald-Wagner and Avrami model. The study through 2nd order pseudo and Avrami models produced complementary results for the authentication of experimental data. The thermodynamic features, ΔG0, ΔH0, and ΔS0 of the adsorption process are acclaimed to be almost spontaneous, physical in nature and endothermic in their manifestation. Surface characterization was carried out using Scanner Electron Microscopy, and identification and determination of chemical species and molecular structure was performed using Infrared Spectroscopy (IR). Maximum adsorption evaluated using statistical optimization with different combinations of five independent variables to study the individual as well as combined effects by Fractional Factorial Experimental Design (FFED) was 236.18 mg g-1 under optimized conditions; pH of 2, adsorbent dosage of 0.500 g L-1, and an initial dye concentration of 209.47 mg L-1 for an adsorption time of 126.62 min with orbital shaking of 165 rpm at temperature 49.95 °C.

Functionality and mechanistic parametric study of the potential of waste plantain peels and commercial bentonite for soybean oil refining.

The consumption of unrefined vegetable oil poses acute and chronic health issues, yet improper disposal of waste plantain peels is not environmentally sustainable. This research investigates the feasibility, mechanism and thermodynamics of waste plantain peels, and commercial bentonite clay for soybean oil refining. Experiment was carried out using masses (1-4 g) of commercial bentonite clay, and unripe plantain peel ash (UPPA) to degummed and neutralized free fatty acid (FFA) contents in crude soybean oil at varying temperatures (50-120 °C), and time (15-35 min) for treatment of soybean oil. FTIR spectroscopy, SEM, and XRF techniques were applied to characterize the sample. The results established that at optimum 4.0 g dosage, the UPPA (97.73%) was more effective in the removal of FFA from oil at 50 °C and 20 min, while the clay (90%) was more effective in the removal of colour pigment from the vegetable oil 100 °C, and 25 min. The optimum efficiency of Clay-Ash-composite (70:30) in adsorbing pigment from soybean oil corresponds to 80%. The impact of changing viscosities, densities, and acid values on the performance of UPPA, clay, and clay-UPPA composite was investigated. Mechanistic studies confirmed the pseudo-second-order kinetics at 5 × 10-2 g/mg min-1 and 1.87 × 10-1 g/mg min-1, with corresponding adsorption capacity of 30.40 mg/g and 4.91 mg/g, at R2 ≤ 0.9982. The UPPA-driven sorption of FFA occurred as a physisorption and exothermic process (- 620.60 kJ/mol), while colour pigment removal occurred by chemisorption and endothermic process (22.40 kJ/mol). The finding recommends UPPA and composite as economically feasible for refining soybean oil.

Experimental investigation of H3PO4 activated papaya peels for methylene blue dye removal from aqueous solution: Evaluation on optimization, kinetics, isotherm, thermodynamics, and reusability studies.

This investigation is centered on the effectiveness of methylene blue (MB), a cationic dye, adsorbed from an aqueous media by H3PO4 activated papaya skin/peels (PSPAC), with initial pH (2-10), contact time (30-180 min), MB dye concentration (varying from 10 to 50 mg/L), and MB dose (0.1-0.5 gm). The findings show that the best optimal conditions for MB dye removal occur at a 6 pH, 0.3 gm dose of PSPAC adsorbent for 10 mg/L MB dye concentration, with 90 min of contact time. To optimize and validate the extraction efficiency of MB dye, a response surface methodology (RSM) study was conducted using a central composite design (CCD) with a regression model showing R2 = 0.9940. FT-IR spectroscopy shows, CO, and O-H stretching functional groups while FE-SEM is assessed to supervise morphological features of the PSPAC adsorbent. The peak adsorption capacity with 46.95 mg/g for the Langmuir isotherm model conveniently satisfies the adsorption process with R2 = 0.9984 while with R2 = 0.999, a kinetic model, pseudo-second-order, confirms MB dye adsorption by PSPAC adsorbent. Moreover, thermodynamic parameters including ΔGᵒ, ΔH°, and ΔS° were computed and found to be spontaneous and exothermic. Furthermore, regeneration studies employed with NaOH (0.1 M) and HCl (0.1 M) solution media show an acceptable MB removal efficiency consecutive up to three cycles. The study highlights that H3PO4 papaya skin/peel (PSPAC) is an effectual, sustainable, reasonably available biosorbent to remove industrial cationic dyes disposal.

Adsorptive removal of acid red 18 dye from aqueous solution using hexadecyl-trimethyl ammonium chloride modified nano-pumice.

Discharging untreated dye-containing wastewater gives rise to environmental pollution. The present study investigated the removal efficiency and adsorption mechanism of Acid Red 18 (AR18) utilizing hexadecyl-trimethyl ammonium chloride (HDTMA.Cl) modified Nano-pumice (HMNP), which is a novel adsorbent for AR18 removal. The HDTMA.Cl is characterized by XRD, XRF, FESEM, TEM, BET and FTIR analysis. pH, contact time, initial concentration of dye and adsorbent dose were the four different parameters for investigating their effects on the adsorption process. Response surface methodology-central composite design was used to model and improve the study to reduce expenses and the number of experiments. According to the findings, at the ideal conditions (pH = 4.5, sorbent dosage = 2.375 g/l, AR18 concentration = 25 mg/l, and contact time = 70 min), the maximum removal effectiveness was 99%. The Langmuir (R2 = 0.996) and pseudo-second-order (R2 = 0.999) models were obeyed by the adsorption isotherm and kinetic, respectively. The nature of HMNP was discovered to be spontaneous, and thermodynamic investigations revealed that the AR18 adsorption process is endothermic. By tracking the adsorption capacity of the adsorbent for five cycles under ideal conditions, the reusability of HMNP was examined, which showed a reduction in HMNP's adsorption effectiveness from 99 to 85% after five consecutive recycles.

A review of novel green adsorbents as a sustainable alternative for the remediation of chromium (VI) from water environments.

The presence of heavy metal, chromium (VI), in water environments leads to various diseases in humans, such as cancer, lung tumors, and allergies. This review comparatively examines the use of several adsorbents, such as biosorbents, activated carbon, nanocomposites, and polyaniline (PANI), in terms of the operational parameters (initial chromium (VI) concentration (Co), temperature (T), pH, contact time (t), and adsorbent dosage) to achieve the Langmuir's maximum adsorption capacity (qm) for chromium (VI) adsorption. The study finds that the use of biosorbents (fruit bio-composite, fungus, leave, and oak bark char), activated carbons (HCl-treated dry fruit waste, polyethyleneimine (PEI) and potassium hydroxide (KOH) PEI-KOH alkali-treated rice waste-derived biochar, and KOH/hydrochloric acid (HCl) acid/base-treated commercial), iron-based nanocomposites, magnetic manganese-multiwalled carbon nanotubes nanocomposites, copper-based nanocomposites, graphene oxide functionalized amino acid, and PANI functionalized transition metal are effective in achieving high Langmuir's maximum adsorption capacity (qm) for chromium (VI) adsorption, and that operational parameters such as initial concentration, temperature, pH, contact time, and adsorbent dosage significantly affect the Langmuir's maximum adsorption capacity (qm). Magnetic graphene oxide functionalized amino acid showed the highest experimental and pseudo-second-order kinetic model equilibrium adsorption capacities. The iron oxide functionalized calcium carbonate (IO@CaCO3) nanocomposites showed the highest heterogeneous adsorption capacity. Additionally, Syzygium cumini bark biosorbent is highly effective in treating tannery industrial wastewater with high levels of chromium (VI).

Polycyclic aromatic hydrocarbons (PAHs) in meat, poultry, fish and related product samples of Iran: a risk assessment study.

Meat, poultry, and seafood such as fish are a valuable source of protein, vitamins and minerals. Considering their high consumption in the human diet, it is necessary to study pollutants (such as PAHs) in them. This present study has focused on the PAHs level and probabilistic risk of health in meat, poultry, fish and related product samples by MSPE-GC/MS technique (magnetic solid-phase extraction with gas chromatography-mass spectrometry). The maximum mean of 16 PAH was detected in smoked fish samples (222.7 ± 13.2 µg/kg) and the minimum mean of 16 PAH was detected in chicken (juje) kebab (112.9 ± 7.2 µg/kg µg/kg). The maximum mean of 4PAHs was detected in tuna fish (23.7 ± 2.4 µg/kg) and the minimum mean of 4PAHs was seen in grilled chicken and sausage samples (non-detected). Our results showed the 4PAHs and B[a]P were lower than the EU (European Union) standard levels (these standard levels were 30 and 5 µg/kg, respectively). Furthermore, the correlation among the type and concentrations of PAHs congeners was investigated through cluster analysis by heat map and principal component analysis. The 90th percentile ILCR (incremental lifetime cancer risk) of PAH compounds in fish, poultry, meat and related products samples was 3.39E-06, which was lower than the maximum acceptable level of risk (10-4). Finally, the highest ILCR was related to hamburger (4.45E-06). Therefore, there is no risk in consuming these foods in Iran, but it is necessary to monitor PAHs concentration in different types of foods.

4-Chlorophenol adsorption from water solutions by activated carbon functionalized with amine groups: response surface method and artificial neural networks.

4-Chlorophenol pollution is a significant environmental concern. In this study, powdered activated carbon modified with amine groups is synthesized and investigated its efficiency in removing 4-chlorophenols from aqueous environments. Response surface methodology (RSM) and central composite design (CCD) were used to investigate the effect of different parameters, including pH, contact time, adsorbent dosage, and initial 4-chlorophenol concentration, on 4-chlorophenol removal efficiency. The RSM-CCD approach was implemented in R software to design and analyze the experiments. The statistical analysis of variance (ANOVA) was used to describe the roles of effecting parameters on response. Isotherm and kinetic studies were done with three Langmuir, Freundlich, and Temkin isotherm models and four pseudo-first-order, pseudo-second-order, Elovich, and intraparticle kinetic models in both linear and non-linear forms. The synthesized adsorbent was characterized using X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) analyses. The results showed that the synthesized modified activated carbon had a maximum adsorption capacity of 316.1 mg/g and exhibited high efficiency in removing 4-chlorophenols. The optimal conditions for the highest removal efficiency were an adsorbent dosage of 0.55 g/L, contact time of 35 min, initial concentration of 4-chlorophenol of 110 mg/L, and pH of 3. The thermodynamic study indicated that the adsorption process was exothermic and spontaneous. The synthesized adsorbent also showed excellent reusability even after five successive cycles. These findings demonstrate the potential of modified activated carbon as an effective method for removing 4-chlorophenols from aqueous environments and contributing to developing sustainable and efficient water treatment technologies.

Recent trends in the applications of sonochemical reactors as an advanced oxidation process for the remediation of microbial hazards associated with water and wastewater: A critical review.

Water is one of the major sources that spread human diseases through contamination with bacteria and other pathogenic microorganisms. This review focuses on microbial hazards as they are often present in water and wastewater and cause various human diseases. Among the currently used disinfection methods, sonochemical reactors (SCRs) that produce free radicals combined with advanced oxidation processes (AOPs) have received significant attention from the scientific community. Also, this review discussed various types of cavitation reactors, such as acoustic cavitation reactors (ACRs) utilizing ultrasonic energy (UE), which had been widely employed, involving AOPs for treating contaminated waters. Besides ACRs, hydrodynamic cavitation reactors (HCRs) also effectively destroy and deactivate microorganisms to varying degrees. Cavitation is the fundamental phenomenon responsible for initiating many sonochemical reactions in liquids. Bacterial degradation occurs mainly due to the thinning of microbial membranes, local warming, and the generation of free radicals due to cavitation. Over the years, although extensive investigations have focused on the antimicrobial effects of UE (ultrasonic energy), the primary mechanism underlying the cavitation effects in the disinfection process, inactivation of microbes, and chemical reactions involved are still poorly understood. Therefore, studies under different conditions often lead to inconsistent results. This review investigates and compares other mechanisms and performances from greener and environmentally friendly sonochemical techniques to the remediation of microbial hazards associated with water and wastewater. Finally, the energy aspects, challenges, and recommendations for future perspectives have been provided.

Removal of toxic lead from aqueous solution using a low-cost adsorbent.

Valorization of waste materials and byproducts as adsorbents is a sustainable approach for water treatment systems. Pottery Granules (PG) without any chemical and thermal modification were used as a low-cost, abundant, and environmentally benign adsorbent against Pb(II), the toxic metal in drinking water. The porous structure and complex mineral composition of PG made it an efficient adsorbent material for Pb(II). The effect of key physicochemical factors was investigated to determine the significance of contact time, PG dose, pH, solution temperature, and coexisting ions, on the process. Pb(II) removal increased by PG dose in the range of 5-15 g/L, and agitation time from 5 to 60 min. Increasing Pb(II) concentration led to a drop in Pb(II) removal, however, adsorption capacity increased significantly as concentration elevated. Pb(II) removal also increased significantly from ~ 45% to ~ 97% by pH from 2 to 12. A ~ 20% improvement in Pb(II) adsorption after rising the solution temperature by 30˚C, indicated the endothermic nature of the process. The sorption was described to be a favorable process in which Pb(II) was adsorbed in a multilayer onto the heterogeneous PG surface. The qmax of 9.47 mg/g obtained by the Langmuir model was superior among many reported low-cost adsorbents. The Pb(II) adsorption was described well by the Pseudo- first-order kinetic model. Na+, Mg2+, Ca2+, Cd2+, and Zn2+ showed a negligible effect on Pb(II) adsorption. However, the presence of Mn2+ and Fe2+ significantly hindered the process efficacy. In conclusion, the use of waste material such as PG against Pb(II) is a viable option from the economic and effectiveness points of view.

Metal-Organic Framework Fluorescence Sensors for Rapid and Accurate Detection of Melamine in Milk Powder.

In this research, a simple, label-free, and ultra-sensitive fluorescent platform based on a metal-organic framework (MOF) has been developed to detect melamine in milk powder. This fluorescence sensor was fabricated from sensitized terbium (Tb)@NH2-MIL-253 (Al) MOF using a hydrothermal method that involved combining the green emission of Tb (λem = 545 nm) with the blue emission of NH2-MIL-253(Al) MOF (λem = 430 nm) under a single excitation wavelength (λex = 335 nm). The fluorescence sensor was then used under optimized conditions (pH = 9.0; sensor concentration = 30 mg/L; response time = 30 s) to quantify melamine in milk powder. The accuracy, sensitivity, and reproducibility of this sensor were established compared to the high-performance liquid chromatography (HPLC) method. The linear range and lower limit of detection (LLOD, computed with 3σ/S) of the sensor were between 40-396.45 nM (equal to 25 µg/kg-0.25 mg/kg) and 40 nM (equal to 25 µg/kg), respectively, which is much less than the maximum residual level (MRL) for the detection of melamine in infant formula (1 mg/kg) and other foods/feeds (2.5 mg/kg). Additionally, the results had good agreement with the HPLC outcomes, suggesting that the NH2-MIL-253(Al) MOF sensing probe has great precision and repeatability. To conclude, the new fluorescence sensor developed in this study can accurately and sensitively detect melamine in food samples, which may be useful for screening for adulteration of milk powders and other foods.

The phenolic components extracted from mulberry fruits as bioactive compounds against cancer: A review.

In Asia, mulberry has long been used to treat various infectious and internal ailments as a traditional medication. The compounds found in it have the potential to improve human health. Because there is no approved and defined evaluation procedure, it has not been formally or scientifically recognized. As a result of these investigations, a new frontier in traditional Chinese medicine has opened up, with the possibility of modernization, for the interaction between active components of mulberry and their biological activities. These studies have used current biotechnological technologies. For ages, mulberry has been used as an herbal remedy in Asia to cure various diseases and internal disorders. It has a high concentration of bioactive chemicals that benefit human health. The most abundant phenolic components extracted from white mulberry leaves are flavonoids (Kuwanons, Moracinflavans, Moragrols, and Morkotins), phenolic acids, alkaloids, and so forth. Flavonoids, benzofurans, chalcones, and alkaloids have been discovered to have cytotoxic effects on human cancer cell lines. There is growing evidence that mulberry fruits can potentially prevent cancer and other aging-related disorders due to their high concentration of bioactive polyphenolic-rich compounds and macro and micronutrients. Anthocyanins are rapidly absorbed after eating, arriving in the plasmalemma within 15-50 min and entirely removed after 6-8 hr. Due to a lack of an approved and consistent technique for its examination, it has yet to be formally or scientifically recognized. The mulberry plant is commercially grown for silkworm rearing, and less attention is paid to its bioactive molecules, which have a lot of applications in human health. This review paper discusses the phenolic compounds of white mulberry and black mulberry in detail concerning their role in cancer prevention.

Insights into chitosan-based cellulose nanowhiskers reinforced nanocomposite material via deep eutectic solvent in green chemistry.

In the present work, the synthesis of cellulose nanowhiskers (CNW)/chitosan nanocomposite films via deep eutectic solvents (DES) changing the chemical structures were carried out. It was observed that a pure chitosan film has broadband at 3180-3400 cm-1, indicating amide and hydroxyl groups. Upon CNW incorporation, the peak gets sharper and stronger and shifts to a greater wavelength. Further, the addition of DES infuses more elements of amide into the nanocomposite films. Moreover, the mechanical properties incorporating CNW filler into a chitosan matrix show an enhancement in tensile strength (TS), Young's modulus (YM), and elongation at break. The TS and YM increase while the elongation decrease as the CNW concentration increases. The YM of biocomposite films is increased to 723 MPa at 25% CNW into chitosan films. Besides, the TS has enhanced to 11.48 MPa at 15% CNW concentration in the biocomposite films. The elongation at break has decreased to 11.7% at 25% CNW concentration. Hence, incorporating CNW into the chitosan matrix via DES can still improve the mechanical properties of the nanocomposite films. Therefore, the application of DES results in a lower YM and TS as the films are hygroscopic. In conclusion, DES can be considered the new green solvent media for synthesizing materials. It has the potential to replace ionic liquids due to its biodegradability and non-toxic properties while preserving the character of low-vapour pressure. Besides that, chitosan can be used as potential material for applications in process industries, such as the biomedical and pharmaceutical industries. Thus, DES can be used as a green solvent and aim to reduce the toxic effect of chemicals on the environment during chemical production.

Occurrence of organophosphorus esters in outdoor air fine particulate matter and comprehensive assessment of human exposure: A global systematic review.

Organophosphate esters (OPEs) are widely used in various industrial items, including plastics, textiles, construction materials, electronics, and auto parts. Several studies have investigated the concentration of OPE compounds in the air, where different compounds have been measured. This systematic review aims to investigate and summarize the relationship between exposure concentrations of OPEs in outdoor air and health risk for different OPE compounds, and correlations between OPE compounds in emission sources. PubMed, Scopus, Embase, Web of Science, and Google Scholar were searched from January 2000 to September 2021 to identify relevant research. The quality of the studies was assessed using the OHAT risk of bias tool. Spearman's correlation and principal component analysis (PCA) were used to analyze the results and correlation between OPE compounds. A total of 7669 manuscripts were found from the search in 5 databases. Finally, 46 studies were included in the systematic review. According to the median concentrations in the studies that were included, Tris(1-chloro-2-propyl) phosphate (TCIPP) (25%), trimethylphenyl phosphate(TMPP) (19%), Tri-iso-butyl phosphate (TiBP) (12%), Triphenyl phosphate (TPHP) (9%) and Tris(2-chloroethyl) phosphate (TCEP) (8%) had the greatest concentrations of OPEs overall. The cumulative contribution of the two main factors, F1 and F2, from the principal component analysis (PCA) results is 49.81%. The EDI value for the compounds is TCEP > TCIPP > TiBP > TMPP > 2-Ethylhexyl diphenyl phosphate (EHDPP) > TPHP > Tri(2-Ethylhexyl) phosphate (TEHP) > Tri-m-cresyl phosphate (mTCP) > Tris(1, 3-dichloro-isopropyl) phosphate (TDCPP) > Tri-n-butyl phosphate (TnBP). The total amount of non-carcinogenic risk (HQ) was for children > infants > adults. The highest value of HQ was for TCEP, TCIPP, and TMPP, respectively. The highest carcinogenic risk value was for TCEP and TMPP.

Purification of aquaculture effluent using Picralima nitida seeds.

Aquaculture effluent treatment is essential to eliminate the undesirable characteristics of water to ensure cleaner production and environmental sustainability. In an effort to develop green coagulant without compromising cost, this research investigated the feasibility of aquaculture effluent (AQEF) pollutant removal using Picralima nitida seeds extract (PNSC) and its bio-coagulation/adsorption kinetic characteristics with the substrate in water. The coagulative decrease was observed in terms of TD (turbidity), TSS (total suspended solids), COD (chemical oxygen demand), BOD (biochemical oxygen demand), and COLR (color) from AQEF. The active coagulant was extracted from the seeds and analyzed for its spectral and morphological characteristics through FTIR and SEM. The influence of PNSC dosage (0.10-0.50 g L-1), pH (2-10), settling time (0-60 min), and temperature (303-323 K) on the removal of contaminants were surveyed. The process kinetics of coagulation-flocculation were also explored. Maximal TD reduction of 90.35%, COD (82.11%), BOD (82.38%); TSS (88.84%), and COLR (65.77%) at 0.2 g PNSC L-1, pH 4, and 303 K was achieved. Analysis of variance (ANOVA) tests proved that pH, temperature, and settling time had a significant effect on pollutant removal. Results fitted Von Smoluchowski's perikinetics theory at the optimum conditions, which gave R2 > 0.900. At perikinetics circumstances, the Kb (reaction rate) and [Formula: see text] (half-life) correspond to 0.0635 Lg-1 min-1 and 1.9 min. More so, sorption results fitted the Lagergren over the Ho model. Additionally, the net cost of using PNSC to handle 1 L of AQEF (including electricity, material, and labor costs) was evaluated to be €4.81. Overall, the PNSC appears reliable and useful in pretreating AQEF for improved biodegradability and superior effluent quality.

Combination of advanced nano-Fenton process and sonication for destruction of diclofenac and variables optimization using response surface method.

Diclofenac (DCF) as a non-steroidal pharmaceutical has been detected in aquatic samples more than other compounds due to its high consumption and limited biodegradability. In this study, ultrasound waves were applied along with an advanced nano-Fenton process (US/ANF) to remove DCF, and subsequently, the synergistic effect was determined. Before that, the efficiency of the US and ANF processes was separately studied. The central composite design was used as one of the most applicable responses surface method techniques to determine the main and interactive effect of the factors influencing DCF removal efficiency in US/ANF. The mean DCF removal efficiency under different operational conditions and at the time of 1-10 min was obtained to be about 4%, 83%, and 95% for the US, ANF, and US/ANF, respectively. Quadratic regression equations for two frequencies of US were developed using multiple regression analysis involving main, quadratic, and interaction effects. The optimum condition for DCF removal was obtained at time of 8.17 min, H/F of 10.5 and DCF concentration of 10.12 at 130 kHz US frequency. The synergy index values showed a slight synergistic effect for US/ANF (1.1). Although the synergistic effect of US/ANF is not very remarkable, it can be considered as a quick and efficient process for the removal of DCF from wastewater with a significant amount of mineralization.

Photocatalytic degradation of bisphenol a from aqueous solution using bismuth ferric magnetic nanoparticle: synthesis, characterization and response surface methodology-central composite design modeling.

Purpose: Bisphenol A (BPA), as endocrine-disrupting compound (EDC), is extensively used as an important chemical in the synthesis of polycarbonate polymers and epoxy resins. BPA absorption into the body can result in the development of metabolic disorders such as low sex-specific neurodevelopment, immune toxicity, neurotoxicity and interference of cellular pathway. Therefore, the presence of BPA in the body and the environment can create hazards that must reach standards before being discharged into the environment. Methods: In this study, bismuth ferric nanomagnetic (BFO NMPs) were successfully synthesized via sol-gel method and developed as photocatalysts for BPA removal under visible light irradiation. FE-SEM, TEM, PL, XRD, UV-Vis DRS, VSM, EDX, and FTIR were used to characterize the BFO NMPs. Results: RSM model (R2 = 0.9745) showed a good correlation between experimental and predicted removal efficiency of BPA. The investigation of four independent variables indicated that pH had the most significant positive effect on the degradation of BPA. Under optimal conditions (pH = 4.042, catalyst dose = 7.617 mg, contact time = 122.742 min and BPA concentration = 15.065 mg/L), maximum degradation was calculated to be 98.7%. After five recycles, the removal of BPA remained >82%, which indicated the proper ability to reuse the catalyst. Conclusion: In conclusion, it can be stated like BPA, the prepared BFO NMPs is a promising photocatalyst for practical application in organic pollutant decomposition.

A critical review on the existing wastewater treatment methods in the COVID-19 era: What is the potential of advanced oxidation processes in combatting viral especially SARS-CoV-2?

The COVID-19 epidemic has put the risk of virus contamination in water bodies on the horizon of health authorities. Hence, finding effective ways to remove the virus, especially SARS-CoV-2, from wastewater treatment plants (WWTPs) has emerged as a hot issue in the last few years. Herein, this study first deals with the fate of SARS-CoV-2 genetic material in WWTPs, then critically reviews and compares different wastewater treatment methods for combatting COVID-19 as well as to increase the water quality. This critical review sheds light the efficiency of advanced oxidation processes (AOPs) to inactivate virus, specially SARS-CoV-2 RNA. Although several physicochemical treatment processes (e.g. activated sludge) are commonly used to eliminate pathogens, AOPs are the most versatile and effective virus inactivation methods. For instance, TiO2 is the most known and widely studied photo-catalyst innocuously utilized to degrade pollutants as well as to photo-induce bacterial and virus disinfection due to its high chemical resistance and efficient photo-activity. When ozone is dissolved in water and wastewater, it generates a wide spectrum of the reactive oxygen species (ROS), which are responsible to degrade materials in virus membranes resulting in destroying the cell wall. Furthermore, electrochemical advanced oxidation processes act through direct oxidation when pathogens react at the anode surface or by indirect oxidation through oxidizing species produced in the bulk solution. Consequently, they represent a feasible choice for the inactivation of a wide range of pathogens. Nonetheless, there are some challenges with AOPs which should be addressed for application at industrial-scale.

Adsorptive removal of humic substances using cationic surfactant-modified nano pumice from water environment: Optimization, isotherm, kinetic and thermodynamic studies.

In this study, nano pumice (NP) and a cationic surfactant (hexadecyltrimethylammonium-chloride (HDTMA.Cl)) treated nano pumice (HMNP) were used for humic acid (HA) adsorption from an aqueous solution. The adsorption process was modeled and optimized using Response surface methodology-central composite design (RSM-CCD) and Artificial neural networks- Genetic algorithm (ANN-GA). The results show that the ANN model outperforms the RSM-CCD model in terms of response prediction. Optimization results based on the RSM-CCD approach proposed pH 3, adsorbent dose 3 g L-1, reaction time 60 min, and initial HA concentration 5 mg L-1 as optimal points of the variables, to reach the maximum adsorption efficiency of 100% and 65.4% by HMNP and NP adsorbents. The maximal adsorption capacity of NP was 1.21 mg g-1, while that of HMNP was 27.34 mg g-1. The optimal points of process parameters by the ANN-GA method are in accordance with the values suggested by the RSM-CCD method. In isotherm studies, Langmuir model was found to be the best-fitted model for both adsorbent with R2 = 0.97 for NP and 0.992 for HMNP, and also among three different kinetic models which were assessed, Pseudo-second-order model with R2 = 0.9989 for HMNP and R2 = 0.9957 for NP were the best-fitted models for HA removal. Thermodynamic studies indicated that the HA adsorption process by both of the adsorbents is endothermic and the nature of HMNP was found spontaneous while for NP was non-spontaneous. The value of ΔH for both adsorbents was in the range of 34-36.8 kJ mol-1 so the process is clarified as chemical-physical adsorption. The reusability test revealed that the adsorption effectiveness of HMNP drops from 100% to 82.4% after 10 consecutive recycles. The influence of interfacing anions indicated that the adsorption efficiency drops from 100% to 95.4% when the anions were added to the reaction solution.

Propolis efficacy on SARS-COV viruses: a review on antimicrobial activities and molecular simulations.

This current study review provides a brief review of a natural bee product known as propolis and its relevance toward combating SARS-CoV viruses. Propolis has been utilized in medicinal products for centuries due to its excellent biological properties. These include anti-oxidant, immunomodulatory, anti-inflammatory, anti-viral, anti-fungal, and bactericidal activities. Furthermore, studies on molecular simulations show that flavonoids in propolis may reduce viral replication. While further research is needed to validate this theory, it has been observed that COVID-19 patients receiving propolis show earlier viral clearance, enhanced symptom recovery, quicker discharge from hospitals, and a reduced mortality rate relative to other patients. As a result, it appears that propolis could probably be useful in the treatment of SARS-CoV-2-infected patients. Therefore, this review sought to explore the natural properties of propolis and further evaluated past studies that investigated propolis as an alternative product for the treatment of COVID-19 symptoms. In addition, the review also highlights the possible mode of propolis action as well as molecular simulations of propolis compounds that may interact with the SARS-CoV-2 virus. The activity of propolis compounds in decreasing the impact of COVID-19-related comorbidities, the possible roles of such compounds as COVID-19 vaccine adjuvants, and the use of nutraceuticals in COVID-19 treatment, instead of pharmaceuticals, has also been discussed.