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Carbohydr Polym ; 200: 381-390, 2018 Nov 15.
Artículo en Inglés | MEDLINE | ID: mdl-30177178

RESUMEN

Bacterial cellulose (BC) gel is synthesized by static culture process at the interface between air and medium. The solvent-exchanged BC gel is incorporated into polyacrylonitrile (PAN) copolymer solution under heating at 90 °C and subsequent cooling gives bacterial cellulose-polyacrylonitrile composite (BC-PAN) monolith. The BC-PAN monolith is carbonized at 1000 °C with physical activation in the presence of CO2 to obtain the activated carbon monolith, BC-PAN-AC, with large surface area and high microporosity. Unique morphologies are observed for BC gel which is propagated to the BC-PAN monolith and restored in BC-PAN-AC. The BC nanofibers remain entwined throughout the porous skeleton of the PAN backbone and the entangled structure helps in retaining the continuity of the matrix of BC-PAN-AC and reduce the grain boundary impedance for electrical conduction. Cyclic voltammetry shows that these activated carbons are good electrode materials in electric double layer capacitors (EDLC) with capability of high-speed charging and discharging.


Asunto(s)
Resinas Acrílicas/química , Celulosa/química , Carbón Orgánico/química , Gluconacetobacter/química , Nanofibras/química , Adsorción , Electroquímica , Electrodos , Solventes/química
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