Effect of molecular helical structure on self-growing and damping of single network κ-carrageenan hydrogel.

Molecular helical is ubiquitous in molecular structures, however, the impact of the structure on mechanical properties has yet to be extensively studied. In this study, we synthesized a single network κ-carrageenan (KC) hydrogel with the molecular double helix structure, and elucidated its unique self-enhancing and damping properties from a molecular structural perspective. During cycle tensile tests, the helical structure was stretched and entangled to form a directional arrangement, increasing the elastic modulus and achieving 'self-reinforcement'. Meanwhile, the molecular helices have a spring-like damping effect, allowing the hydrogel to dampen low-frequency noise while transmitting high-frequency signals. By utilizing the hydrogel to create electrodes for electrocardiogram (ECG) detection, we were able to effectively filter out noise generated by movements while retaining necessary signals. Our work thus presents a potential pathway bridging from microscopic molecular structure to macroscopic mechanical properties of materials.

Gallium-based liquid metal hybridizing MoS2 nanosheets with reversible rheological characteristics and enhanced lubrication properties.

Gallium-based liquid metal (GLM) is a promising lubricant candidate due to its high load capacity and high thermal stability. However, the lubrication performance of GLM is restricted by its metallic characteristics. Herein, this work proposes a facile method to obtain a GLM@MoS2 composite by integrating GLM with MoS2 nanosheets. The incorporation of MoS2 imparts GLM with different rheological properties. Since GLM is able to be separated from the GLM@MoS2 composite and agglomerates into bulk liquid metal again in alkaline solution, the bonding between GLM and MoS2 nanosheets is reversible. Moreover, our frictional tests demonstrate that the GLM@MoS2 composite exhibits enhanced tribological performance including reduction of friction coefficient and wear rate by 46% and 89%, respectively, in contrast to the pure GLM.

A sustained release lubrication method of agarose-sodium hyaluronate hydrogels for artificial joint.

The artificial joint prosthesis's surface is subjected to wear due to the destruction of the joint lubrication environment after surgery. In this study, an agarose-sodium hyaluronate hydrogel was used as lubricant additive in order to supply and preserve the lubricating fluid of artificial joint prostheses. A ball on disc experiment was conducted using this hydrogel to evaluate the lubrication efficiency and release rate under various frequencies. The results showed that this hydrogel could release lubricant under pressure and then absorb the released fluid after decompression. Furthermore, the agarose-sodium hyaluronate hydrogel acted as an effective transport mechanism to release sodium hyaluronate lubricant into the metal-on-polymer friction interface. Compared with pure water lubrication, the friction coefficient and wear volume were reduced by up to 62.9%, and 86.9% respectively. Moreover, the proposed lubrication method provided a long-term lubrication on artificial hip joints.

Bionic Jaw-Like Micro One-Way Valve for Rapid and Long-Distance Water Droplet Unidirectional Spreading.

A surface with asymmetric microstructures for self-driven directional spreading of liquid has attracted keen interest from researchers in recent years for its great application prospects. Inspired by the jaws of tiny insects, such as ants, a surface textured with novel jaw-like microstructures as micro one-way valves is reported. These microstructures are almost two-dimensional, thus being simple and easy to fabricate. Whereas surfaces with such jaw-like micro one-way valves exhibit amazing rapid and long-distance water droplet unidirectional spreading behaviors. The maximum forward-backward distance ratio of water droplets on surfaces with the optimized microstructures is about 14.5, almost twice those of previous research. The capillary attraction at the location of the mouth of the jaws and the pinning effect brought by the sharp edge of the jaws for the precursor film are analyzed and deduced as the main mechanisms. The findings open a promising avenue for 2D asymmetric microstructure design and effective self-driven liquid unidirectional spreading.

Economic Friendly ZnO-Based UV Sensors Using Hydrothermal Growth: A Review.

Ultraviolet (UV) sensors offer significant advantages in human health protection and environmental pollution monitoring. Amongst various materials for UV sensors, the zinc oxide (ZnO) nanostructure is considered as one of the most promising candidates due to its incredible electrical, optical, biomedical, energetic and preparing properties. Compared to other fabricating techniques, hydrothermal synthesis has been proven to show special advantages such as economic cost, low-temperature process and excellent and high-yield production. Here, we summarize the latest progress in research about the hydrothermal synthesis of ZnO nanostructures for UV sensing. We particularly focus on the selective hydrothermal processes and reveal the effect of key factors/parameters on ZnO architectures, such as the laser power source, temperature, growth time, precursor, seeding solution and bases. Furthermore, ZnO hydrothermal nanostructures for UV applications as well as their mechanisms are also summarized. This review will therefore enlighten future ideas of low-temperature and low-cost ZnO-based UV sensors.

A Design of Partial Textured Surface on Gear Washers for Reducing Friction and Wear under Low Speed and Heavy Load Conditions.

This paper presents the effort to reduce friction and wear of gear washers under low-speed and heavy-load conditions by designing the arrangement of surface textures. The influence of distributional parameters of textures on load-bearing capacity and friction coefficient of gear washers are studied numerically to obtain a preferable surface texturing design. Then, experimental tests were carried out to plot the Stribeck curves of the obtained texture arrangement compared with bare surface and another unoptimizable texture distribution arrangement to facilitate the verification of the simulation results. Theoretical predictions illustrate that the annular gear washers with partial surface texturing provide lower friction coefficients than bare washers. Textures having a sector angle of 20°, a coverage angle of 12°, a circumferential number of 8, and a radial number of 6 are selected as the final optimal surface texture distribution design. Experimental results confirm that the obtained texture arrangement moves the Stribeck curve towards the lower left, indicating thickening of oil film thickness and reduction in friction coefficient. In addition, the weight loss caused by wear is also reduced by the optimized texture design.

A Pocket-Textured Surface for Improving the Tribological Properties of Point Contact under Starved Lubrication.

This paper reports a novel pocket-textured surface for improving the tribological properties of point contact under starved lubrication by possibly storing and releasing oil, and homogenizing the surface contact pressure. The ball-on-disk experimental results confirmed the coefficient of friction (COF) and wear reduction effect of such pocket-texturing. The maximum reduction rate was 40% compared with a flat surface under the same operating conditions. Analyses on experimental results attributed the oil storage effect and enhanced the secondary lubrication effect within the starved lubrication state, to become the main mechanism. In addition, the plate elasticity and the Hertzian contact principles were employed to estimate the pressure and the load acting on the surface. The experimental results and numerical analysis substantiated the design of pocket-textured surface, making it likely to enlarge about 50% of contact surface and to reduce 90% of equivalent stress in comparison to those of conventional surfaces.

The Application of Nano-MoS2 Quantum Dots as Liquid Lubricant Additive for Tribological Behavior Improvement.

Molybdenum disulfide quantum dots (MoS2 QDs) are a promising lubricant additive for enhanced engine efficiency. In this study, MoS2 QDs were used as lubricating oil additives for ball-on-disc contact and had adequate dispersity in paroline oil, due to their super small particle size (~3 nm). Tribological results indicate that the friction coefficient of paroline oil with 0.3 wt.% MoS2 QDs reached 0.061, much lower than that of pure paroline oil (0.169), which is due to the formation of a stable tribo-film formed by the MoS2, MoO3, FeS, and FeSO4 composite within the wear track. Synergistic lubrication effects of the tribo-film and ball-bearing effect cooperatively resulted in the lowest friction and wear.

Bioinspired Topological Surface for Directional Oil Lubrication.

Directional droplet transport widely exists in biological surfaces that greatly inspire the development of a great deal of engineered devices allowing for directional liquid transport in diverse energy and water applications. Despite extensive advances in this area, it remains a challenge to guide the directional spreading of lubricating oils by virtue of the bioinspired design of surface topography in the lubricity field. In this paper, we develop a bioinspired topological surface textured with simple V-shaped posts elegantly distributed in the parallel channels, which allows for an efficient and unidirectional transport of various lubricating oils. We also clarify the propagation of a precursor film and the coalescence effect between the original droplet and the precursor film in the preferential direction, as well as the pinning effect in the reverse direction, which integrate seamlessly to create a long-range directional oil transportation. The directional oil transportation promises a potential application of directional lubrication, creating a functional surface consisting of two zones with different lubrication properties as evidenced by different friction coefficients.

Constructing a Dual-Function Surface by Microcasting and Nanospraying for Efficient Drag Reduction and Potential Antifouling Capabilities.

To improve the drag-reducing and antifouling performance of marine equipment, it is indispensable to learn from structures and materials that are found in nature. This is due to their excellent properties, such as intelligence, microminiaturization, hierarchical assembly, and adaptability. Considerable interest has arisen in fabricating surfaces with various types of biomimetic structures, which exhibit promising and synergistic performances similar to living organisms. In this study, a dual bio-inspired shark-skin and lotus-structure (BSLS) surface was developed for fabrication on commercial polyurethane (PU) polymer. Firstly, the shark-skin pattern was transferred on the PU by microcasting. Secondly, hierarchical micro- and nanostructures were introduced by spraying mesoporous silica nanospheres (MSNs). The dual biomimetic substrates were characterized by scanning electron microscopy, water contact angle characterization, antifouling, self-cleaning, and water flow impacting experiments. The results revealed that the BSLS surface exhibited dual biomimetic features. The micro- and nano-lotus-like structures were localized on a replicated shark dermal denticle. A contact angle of 147° was observed on the dual-treated surface and the contact angle hysteresis was decreased by 20% compared with that of the nontreated surface. Fluid drag was determined with shear stress measurements and a drag reduction of 36.7% was found for the biomimetic surface. With continuous impacting of high-speed water for up to 10 h, the biomimetic surface stayed superhydrophobic. Material properties such as inhibition of protein adsorption, mechanical robustness, and self-cleaning performances were evaluated, and the data indicated these behaviors were significantly improved. The mechanisms of drag reduction and self-cleaning are discussed. Our results indicate that this method is a potential strategy for efficient drag reduction and antifouling capabilities.

Slow-release lubrication effect of graphene oxide/poly(ethylene glycol) wrapped in chitosan/sodium glycerophosphate hydrogel applied on artificial joints.

The artificial joints would go through serious wear after implantation surgery due to the poor lubrication of the body fluid, and the biomimetic lubricants directly injected in vitro is easy to be absorbed by human tissues, and after a period of time, it will lose its lubrication effect. However, the composite hydrogel with slow-release lubrication effect provides a new way for the lubrication of artificial joints. In this study, Graphene oxide/Poly(ethylene glycol) (GO/PEG) composites were prepared to improve the artificial joint lubrication, and through wrapped in the Chitosan/Sodium glycerophosphate (CS/GP) hydrogel, the GO/PEG lubricant will be released under the squeezing action, thus to prolong the service time of biomimetic lubricants. The friction experimental results showed that GO/PEG had better lubrication effect, and the average friction coefficient of the slow-release solution was below 0.03, especially with the pressure increasing. GO, PEG and small molecule GP in the slow-release solution through hydrogen-bond interaction might form a particular structure, which led to the good lubricating effect. The experiments of cell and acute toxicity in vivo showed that GO and its composite hydrogel had good biocompatibility.

Carbon dots intensified poly (ethylene glycol)/chitosan/sodium glycerophosphate hydrogel as artificial synovium tissue with slow-release lubricant.

The ultra-high molecular weight polyethylene (UHMWPE) and metal artificial joint pair is limited by wear debris and short service life. Here we report the development of a hydrogel which exhibits lubricant release to intensify the lubrication effect of artificial joints.This study adopted an injectable method to prepare carbon dots/poly (ethylene glycol)/chitosan/sodium glycerophosphate (CDs/PEG/CS/GP) composite hydrogel, and the carbon dots were used to intensify the rheological and mechanical properties. In addition, the composite hydrogel had slow-release properties, and the release solution contained CDs, PEG and GP has excellent lubrication effect. At last, the MTT assay, LIVE/DEAD staining, H&E staining results and safety evaluation in BALC/c mice proved that the hydrogels had good biocompatibilility and were safety for application in vivo.

One-pot synthesis and lubricity of fluorescent carbon dots applied on PCL-PEG-PCL hydrogel.

This work presents a method for one-pot synthesis of N-doped nanometer-size carbon dots, which can be assembled with thermosensitive poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) (PCL-PEG-PCL, PCEC) hydrogel to achieve slow-release lubricity. The typical property of this green production was studied by fourier transform infrared (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscope (TEM). The photoluminescence of composite PCEC/CDs hydrogel and its released solutions were characterized by ultraviolet spectrum, and the rheological properties were tested by rotary rheometer. Tribological performance of the released solution from composite PCEC/CDs hydrogel was obtained to compare with PBS and pure CDs solution. The experimental results reveal that the CDs contain the chemical groups of N-H, C-OH/C-O-C and -COOH, etc. In addition, the diameter of the CDs is in the range of 6~8 nm. The phase transition behavior of PCEC/CDs hydrogel can be still kept and its viscoelasticity hydrogel is improved by approximatively 7%. Furthermore, friction coefficient of the released solution from composite PCEC/CDs hydrogel decreases by about 70% than that of PBS. Besides, the wear condition can be improved by a lubricating transfer film formed by released CDs. This novel strategy for slow-release application is valuable for drug delivery and bio-tribology.

Effect of Resin Type on the Tribological Properties of a Three-Dimensional Self-Lubricating Composite Surface.

In this paper, three kinds of polymer, of epoxy resin (EP), phenolic resin (PF), and unsaturated polyester (UP), were used as fillers to prepare the laminated composite surface, and the tribological properties of a composite surface were studied under dry sliding condition. The results showed that: (i) the composites surface without MoS2 exhibited high friction coefficient and high wear rate at 25 °C, while the friction coefficients were reduced when the temperature increases to 100 °C; (ii) with the addition of MoS2, the friction coefficient of the epoxy resin composite containing MoS2 (E1) was below 0.22 under a temperature of 25⁻150 °C, and the friction coefficient was increased to 0.32 as temperature increased to 150 °C, while the average friction coefficient of the unsaturated polyester composite containing MoS2 (U1) was very low and below 0.20 under a temperature of 25⁻150 °C. Analysis of the wear scars indicated that, for the MoS2-containing composite, the transfer films of the E1 and U1 were smooth and continuous under low temperature, while the transfer film of U1 was comparatively complete than that of E1 under 150 °C. The composites with solid lubrication had excellent high-temperature self-lubricating properties, which was attributed to the synergistic effect of the laminated structure, and the thermal expansion of the polymer, and finally a transfer film was formed on the sliding path.

Poly(ethylene glycol)/chitosan/sodium glycerophosphate gel replaced the joint capsule with slow-release lubricant after joint surgery.

Body fluid is normally the only lubricant after joint replacement surgery, but wear problems have occurred because body fluid has poor lubrication ability. However, traditional lubricant would be diluted by body fluids and then absorbed by the human body. Therefore, an injectable gel with the ability to slow-release lubricant was designed to replace the joint capsule. The proposed gel, poly(ethylene glycol)/chitosan/sodium glycerophosphate (PEG/CS/GP) composite gel was then tested. The tribology results showed that the PEG/CS/GP gel had excellent slow-release properties, especially under pressure, and the PEG played an important role in improving the gel's rheological and mechanical properties. Moreover, this study revealed that the release solution had a good lubrication effect because the PEG and GP could crosslink via the hydrogen bond effect.

Fabricating hierarchical micro and nano structures on implantable Co-Cr-Mo alloy for tissue engineering by one-step laser ablation.

Surface texturing is one of the effective strategies to improve bioactivity of implantable materials. In this study, hierarchical micro and nano structure (HMN) were fabricated on Co-Cr-Mo alloy substrate by a movable picosecond laser irradiation. Respectively, microgrooves with nano ripples and islands were produced on Co-Cr-Mo alloy by low and high laser power density. X-ray diffraction apparatus (XRD) phase analysis illustrated that substrate was in the phase of γ- face-centered cubic structure (FCC) before laser treatment, while it was in ε-hexagonal closest packing structure (HCP) phase dominant after laser treatment. Cell adhesion and proliferation studies showed that the HMN surface exhibits enhanced adhesion of MC3TC-E1 osteoblast and promoted cell activity. Analyzing of the morphology of osteoblast cells indicated cells were in high ratio of elongation on the HMN surface, while they mainly kept in round shape on the polished surface. Results indicated the formation of hierarchical structure on Co-Cr-Mo alloy was able to improve biological performances, suggesting the potential application in cobalt based orthopedic implants.

Laser textured Co-Cr-Mo alloy stored chitosan/poly(ethylene glycol) composite applied on artificial joints lubrication.

Arthroplasty brings the wear problems because of body fluid has poor performance as lubricant. Lubricant which is used in artificial joints will rapidly degrade and be absorbed by human body after injecting. To prolong the lubricant's effectiveness, this study prepared chitosan/poly(ethylene glycol) (CS/PEG) and textures to play a role in joint lubrication and wear protection. Chitosan (CS) and poly(ethylene glycol) which have biocompatibility and biodegradability properties can be used in human body. The tribological results shown that CS/PEG sol has excellent performance when this sol was composed by 2wt% CS and 30wt% PEG, the average friction coefficient below 0.016 under the condition of 30-90N load (pressure 4.2-12.6MPa). In this study, CS/PEG was added in the texture of artificial joints, then the surfaces of the CS/PEG formed gel via NaOH solidification effect. The CS/PEG gel film could prevent the CS/PEG sol from diluting in body fluid. Meanwhile, FT-IR, XRD, UV/vis and Raman spectra revealed that CS associated with PEG via hydrogen bond effect may form a particular structure, which leaded the good tribological performance. This study provides a new, simple and green approach to enhance tribological performances of artificial joints.

Green superlubricity of Nitinol 60 alloy against steel in presence of castor oil.

In the present work, first, we show that sliding Nitinol 60 alloy against steel under castor oil lubrication exhibits a new case of superlubricity (coefficient of friction CoF ≪ 0.01). So far, CoF below 0.01 have never been achieved under boundary lubrication at high contact pressure and in presence of vegetable oil as a green lubricant. Next, it is demonstrated that superlubricity is controlled by tribochemical reactions, involving chemical degradation of castor oil and the formation of metal oxy-hydroxides. Finally, to explain these findings, we propose a novel superlubricity mechanism consisting of hexanoic acid molecules intercalated between nickel and iron oxy-hydroxide lamellar layers, a structure very similar to the one found in Fe-Ni batteries. We propose that superlubricity is achieved due to repulsive electrostatic forces acting between the intercalated metal oxy-hydroxide lamellar compounds. This system would be suitable for practical engineering applications in many fields including biotechnologies.

Preparation and bioactive properties of chitosan and casein phosphopeptides composite coatings for orthopedic implants.

Using the layer-by-layer deposition method, functional chitosan/casein phospopeptides (CS/CPP) composite coatings were produced on Co-Cr-Mo alloy. The CS/CPP composite coatings had the dendritic topography, and were quite hydrophilic. Zeta potential measurements showed the composite coatings were negative charged at neural pH. XPS results indicated that the CS/CPP composite coatings were covalently bond to the substrate. When MC3T3-E1 cells were seeded on the CS/CPP composite coatings, no cytotoxicity was observed. The bone morphogenetic protein-2 (BMP-2) mRNA expression was significantly up-regulated in MC3T3-E1 cells cultured on the composite coatings and it was twice as much as that of cells cultured on the bare substrate. The expression of osteoprotegerin (OPG) mRNA and the ratio of OPG/receptor activator of nuclear factor-κB ligand (RNAKL) mRNA were increased 5-fold and 55-fold, respectively. These results suggested the CS/CPP composite coatings may have potential application in cobalt matrix orthopaedic implants.

Effect of aqueous solution and load on the formation of DLC transfer layer against Co-Cr-Mo for joint prosthesis.

Diamond-like carbon (DLC) coating exhibits excellent mechanical properties such as high hardness, low friction and wear, which offer a promising solution for the metal-on-metal hip joint implants. In the study, the hydrogen-free DLC coating with the element Cr as the interlay addition was deposited on the surface of the Co-Cr-Mo alloy by a unbalanced magnetron sputtering method. The coating thickness was controlled as 2 µm. Nano-indentation test indicated the hardness was about 13 GPa. DLC coated Co-Cr-Mo alloy disc against un-coated Co-Cr-Mo alloy pin (spherical end SR9.5) comprised the friction pairs in the pin-on-disc tribotest under bovine serum albumin solution (BSA) and physiological saline(PS).The tribological behavior under different BSA concetrations(2-20 mg/ml), and applied load (2-15N) was investigated.DLC transfer layer did not form under BSA solution, even though different BSA concetration and applied load changed. The coefficient of friction(COF) under 6 mg/ml BSA at 10 N was the lowest as 0.10. A higher COF of 0.13 was obtained under 20 mg/ml BSA. The boundary absorption layer of protein is the main factor for the counterparts. However, the continous DLC transfer layer was observed under PS solution, which make a lower COF of 0.08.