1.
Org Biomol Chem
; 22(21): 4347-4352, 2024 May 29.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38726909
RESUMEN
The synthesis of a fully oxygenated aconitine D ring precursor from (D)-(+)-glucose is described. The route features a highly diastereoselective alkynyl Grignard ketone addition and a base-mediated enelactone to 1,3-diketone rearrangement.