RESUMEN
This research reports data for the integrated obtaining of fermentable sugars (FSs), bio-oil (BO), and hydro-char (HC) - all fuel precursors - as well as platform chemicals (PCs - acetic, formic, and levulinic acid, besides furfural, and hydroxymethylfurfural) through semi-continuous hydrothermal processing of sawdust from pine wood. The influence of temperature (260, 300, and 340 °C) and the water-to-biomass ratio (25 and 50 g H2O (g biomass)-1) were the parameters considered to evaluate the mass yields, kinetic profiles, and BO properties. For FSs (and PCs), a detailed analysis considering the kinetic profiles of obtaining cellobiose, glucose, xylose, and arabinose is presented. For the conditions evaluated, a distinct behavior concerning the process parameters was observed, where 7.11 and 9.28 g (100 g biomass)-1 of FSs and PCs were synergistically obtained, respectively, after 30 min, 20 MPa, 260 °C, and 50 g H2O (g biomass)-1. Contextually, 17.59 g (100 g biomass)-1 of BO was obtained at 340 °C and the same water/biomass ratio. FTIR analysis of the BO samples suggested the presence of aldehydes, carboxylic acids, ketones, hydrocarbons, ethers as well as aromatic, alcohols, and nitrogenous compounds. Similar HC yields were achieved among the conditions analyzed, where 24.68 g (100 g biomass)-1 were obtained at 340 °C and 50 g H2O (g biomass)-1 for a higher heating value of 29.14 MJ kg-1 (1.5 times higher than the in natura biomass).
RESUMEN
Butia capitata endocarp (BCE) is a biomass residue with the potential to produce a wide variety of bio-products. The processing of BCE in a sequential process of subcritical water hydrolysis (SWH) and hydrothermal liquefaction (HTL) was investigated to obtain fermentable sugars, platform chemicals, bio-oil, and biochar. The SWH was evaluated at 230 and 260 °C and solvent: feed mass ratios (R) of 10 and 20 for the production of fermentable sugars and platform chemicals. The solid residue from SWH was sequentially submitted to the HTL at 330 and 360 °C for bio-oil and biochar production. The results were analyzed by comparing the sequential (SWH/HTL) and individual (HTL only) processes. The highest yields of fermentable sugars (5.26 g/ 100 g BCE) were obtained for SWH at 260 °C and R-20 with higher contents of xylose (2.64 g/100 g BCE) and cellobiose (1.75 g/100 g BCE). The highest yields of platform chemicals (2.44 g/100 g BCE) were obtained for SWH at 260 °C and R-10 with higher contents of acetic acid (1.78 g/100 g BCE) and furfural (0.54 g/100 g BCE). The highest yield of bio-oil (25.30 g/100 g BCE) occurred in HTL individual process at 360 °C and R-20. Sequential process SWH/HTL showed a decrease in bio-oil yield but maintained a similar biochar yield compared to HTL, in addition to the production of fermentable sugars and platform chemicals.
RESUMEN
Deffated rice bran has potential to processing into ethanol due to its lignocellulosic composition and agricultural productivity. The composition of the pretreated deffated rice bran with Deep Eutectic Solvent was investigated aiming the production of sugars and bioproducts using subcritical water hydrolysis. Changes in the deffated rice bran composition at different pretreatment times and mixtures of deep eutectic solvent were evaluated by the derivative of thermogravimetric analysis. The pretreated deffated rice bran presented an enrichment in the content of hemicelluloses (281.0%) and delignification (59.3 %). Under the same condition of subcritical water hydrolysis (230 °C/R-100) the yield of fermentable sugars increased 2.20 times in the same study time interval (20 min) when comparing pretreated and untreated deffated rice bran.
