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1.
Clin Transl Oncol ; 2024 Apr 16.
Artículo en Inglés | MEDLINE | ID: mdl-38625493

RESUMEN

BACKGROUND: Cancer stem cells (CSCs) represent a potential mechanism contributing to tumorigenesis, metastasis, recurrence, and drug resistance. The objective of this study is to investigate the status quo and advancements in CSC research utilizing bibliometric analysis. METHODS: Publications related to CSCs from 2010 to 2022 were collected from the Web of Science Core Collection database. Various analytical tools including CiteSpace, VOSviewer, Scimago Graphica, and GraphPad Prism were used to visualize aspects such as co-authorship, co-occurrence, and co-citation within CSC research to provide an objective depiction of the contemporary status and developmental trajectory of the CSC field. RESULTS: A total of 22,116 publications were included from 1942 journals written by 95,992 authors. Notably, China emerged as the country with the highest number of publications, whereas the United States exerted the most significant influence within the field. MD Anderson Cancer Center emerged as the institution making the most comprehensive contributions. Wicha M.S. emerged as the most prolific and influential researcher. Among journals, Cancers emerged as a focal point for CSC research, consistently publishing a wealth of high-quality papers. Furthermore, it was observed that most journals tended to approach CSC research from molecular, biological, and immunological perspectives. The research into CSCs encompassed a broad array of topics, including isolation and enrichment techniques, biomarkers, biological characteristics, cancer therapy strategies, and underlying biological regulatory mechanisms. Notably, exploration of the tumor microenvironment and extracellular vesicles emerged as burgeoning research frontiers for CSCs. CONCLUSION: The research on CSCs has garnered growing interest. A trend toward multidisciplinary homogeneity is emerging within the realm of CSCs. Further investigation could potentially center on the patients of extracellular vesicles and the tumor microenvironment in relation to CSCs.

2.
Front Immunol ; 15: 1364506, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-38571938

RESUMEN

Introduction: Tertiary lymphoid structures (TLSs) are ectopic lymphoid formations that arise in non-lymphoid tissues due to chronic inflammation. The pivotal function of TLSs in regulating tumor invasion and metastasis has been established across several cancers, such as lung cancer, liver cancer, and melanoma, with a positive correlation between increased TLS presence and improved prognosis. Nevertheless, the current research about the clinical significance of TLSs in breast cancer remains limited. Methods: In our investigation, we discovered TLS-critical genes that may impact the prognosis of breast cancer patients, and categorized breast cancer into three distinct subtypes based on critical gene expression profiles, each exhibiting substantial differences in prognosis (p = 0.0046, log-rank test), with Cluster 1 having the best prognosis, followed by Cluster 2, and Cluster 3 having the worst prognosis. We explored the impact of the heterogeneity of these subtypes on patient prognosis, the differences in the molecular mechanism, and their responses to drug therapy and immunotherapy. In addition, we designed a machine learning-based classification model, unveiling highly consistent prognostic distinctions in several externally independent cohorts. Results: A notable marker gene CXCL13 was identified in Cluster 3, potentially pivotal in enhancing patient prognosis. At the single-cell resolution, we delved into the adverse prognosis of Cluster 3, observing an enhanced interaction between fibroblasts, myeloid cells, and basal cells, influencing patient prognosis. Furthermore, we identified several significantly upregulated genes (CD46, JAG1, IL6, and IL6R) that may positively correlate with cancer cells' survival and invasive capabilities in this subtype. Discussion: Our study is a robust foundation for precision medicine and personalized therapy, presenting a novel perspective for the contemporary classification of breast cancer.


Asunto(s)
Neoplasias de la Mama , Neoplasias Hepáticas , Neoplasias Pulmonares , Estructuras Linfoides Terciarias , Humanos , Femenino , Neoplasias de la Mama/genética , Neoplasias de la Mama/patología , Estructuras Linfoides Terciarias/patología , Pronóstico , Neoplasias Pulmonares/patología
3.
Materials (Basel) ; 17(5)2024 Mar 05.
Artículo en Inglés | MEDLINE | ID: mdl-38473670

RESUMEN

A new heat source combination, consisting of a uniform body heat source and a tilted double ellipsoidal heat source, has been developed for cold metal transfer (CMT) wire-arc additive manufacturing of Mg-Gd-Y-Zn-Zr alloy. Simulations were conducted to analyze the temperature field and stress distribution during the process. The optimal combination of feeding speed and welding speed was found to be 8 m/min and 8 mm/s, respectively, resulting in the lowest thermal accumulation and residual stress. Z-axis residual stress was identified as the main component of residual stress. Electron Backscatter Diffraction (EBSD) testing showed weak texture strength, and Kernel Average Misorientation (KAM) analysis revealed that the 1st layer had the highest residual stress, while the 11th layer had higher residual stress than the 6th layer. Microhardness in the 1st, 11th, and 6th layers varies due to residual stress impacts on dislocation density. Higher residual stress increases dislocation density, raising microhardness in components. The experimental results were highly consistent with the simulated results.

4.
Nanoscale ; 16(5): 2608-2620, 2024 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-38226643

RESUMEN

Although nanozymes exhibit properties superior to those of natural enzymes and conventional engineered enzymes, the development of highly specific nanozymes remains a challenge. New yolk-shell Fe3O4 molecularly imprinted (MIP@void@Fe3O4) nanozymes with peroxidase-like activity were developed by modelling the substrate channels of natural enzymes through molecular imprinting techniques and interfacial affinity modifications in this study. To establish a platform technology for the adsorption and determination of inorganic and organic contaminants, lead ion (Pb2+) and diazinon (DIZ), respectively, were selected as imprinting templates, and a hollow mesoporous shell was synthesized. The as-prepared MIP@void@Fe3O4 nanozymes, characterized using TEM, HRTEM, SEM, FT-IR, TGA, VSM and XPS, not only affirmed the successful fabrication of a magnetic nanoparticle with a unique hollow core-shell structure but also facilitated an exploration of the interfacial bonding mechanisms between Fe3O4 and other shell layers. The enrichment of the MIP@void@Fe3O4 nanozymes due to imprinting was approximately 5 times higher than the local substrate concentration and contributed to the increased activity. Based on selective and competitive recognition experiments, the synthesized nanozymes could selectively recognize organic and inorganic targets with the lowest detection limits (LOD) of 6.6 × 10-9 ppm for Pb2+ and 5.13 × 10-11 M for DIZ. Therefore, the proposed biosensor is expected to be a potent tool for trace pollutant detection, which provides a rational design for more advanced and subtle methods to bridge the activity gap between natural enzymes and nanozymes.


Asunto(s)
Compuestos Inorgánicos , Impresión Molecular , Espectroscopía Infrarroja por Transformada de Fourier , Plomo , Impresión Molecular/métodos , Óxido Ferrosoférrico/química , Magnetismo , Adsorción
5.
Environ Sci Pollut Res Int ; 30(54): 114936-114955, 2023 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-37880402

RESUMEN

The illegal dumping of construction waste (CW) poses an increasingly serious environmental pollution problem with the accelerated rate of urbanization. As CW disposal capacity struggles to match municipal needs, some CW is being diverted to higher resource endowment cities rather than recycled. To address this situation, it is necessary to obtain reliable information on the characteristics and evolution of CW generation networks in China. This study combines a modified gravity model with Social Network Analysis (SNA) to analyze the spatial association networks of CW generation in four Chinese urban agglomerations between 2000 and 2020. Results reveal the evolution characteristics of the CW generation network, including increasing density and correlation and decreasing network efficiency. Furthermore, the Quality Assurance Procedure (QAP) indicates that urbanization level and population size are positively correlated with CW generations, whereas distance plays a negative role, but resources are insignificant for network formation. The findings provide insight into current patterns of waste distribution and a theoretical basis for government policy formulation in the future.


Asunto(s)
Industria de la Construcción , Residuos Industriales , Urbanización , China , Ciudades , Contaminación Ambiental/legislación & jurisprudencia , Industria de la Construcción/legislación & jurisprudencia , Residuos Industriales/legislación & jurisprudencia , Administración de Residuos/legislación & jurisprudencia , Política Ambiental
6.
Sensors (Basel) ; 23(15)2023 Aug 02.
Artículo en Inglés | MEDLINE | ID: mdl-37571646

RESUMEN

Mastering the strain transfer mechanism in distributed fiber optic (DFO) sensors holds the key to analyzing strain measurement errors from DFO sensing systems. However, the impact of the monitored structure's strain distribution on the strain transfer mechanism in DFO sensors has often been overlooked in the existing research. To address this issue, a strain transfer model of surface-bonded DFO sensors with multilayered structures was established based on the shear lag theory. The closed-form solutions of the strain transfer coefficient of DFO sensors subjected to uniform, parabolic, single-linear gradient, and bilinear gradient strains were obtained. With a high-accuracy optical frequency-domain reflectometer (OFDR), the theoretical model was validated by laboratory tests. Upon parametric analysis, suggestions were further offered about designing and installing DFO sensors.

7.
Materials (Basel) ; 16(16)2023 Aug 21.
Artículo en Inglés | MEDLINE | ID: mdl-37630007

RESUMEN

Double-pulsed gas metal arc welding (DP-GMAW) is a high-performance welding method with low porosity and high frequency. Periodic shrinkage and expansion of the melt pool during DP-GMAW leads to unusual remelting, and the re-solidification behavior of the weld metal can significantly refine the weld structure. The advantages of DP-GMAW have been proven. In order to better apply DP-GMAW to aluminum alloy arc additive manufacturing, in this paper, the single-pass deposition layer parameters (double-pulse amplitude, double-pulse frequency and travel speed) of DP-GMAW will be optimized using the response surface method (RSM) with the width, height, and penetration of the deposition layer as the response values to find the superior process parameters applicable to the additive manufacturing of aluminum alloy DP-GMAW. The results show that the aluminum alloy components made by DP-GMAW additive are well formed. Due to the stirring of double-pulse arc and the abnormal remelting and solidification of metal, the microstructures in the middle and top areas show disordered growth. The average ultimate tensile strength of the transverse tensile specimen of the member can reach 175.2 MPa, and the elongation is 10.355%.

8.
Materials (Basel) ; 16(9)2023 May 05.
Artículo en Inglés | MEDLINE | ID: mdl-37176429

RESUMEN

The hot cracking behaviors of Mg-5Zn-xEr (x = 0.83, 1.25, 2.5, 5 wt.%) alloys are investigated by optimized hot cracking experimental apparatus, optical microscope, and scanning electron microscope, such as contraction behaviors, feeding behaviors, and permeability characteristics. It is found that the solid phase fraction at hot crack initiation and within the freezing range both increased with increasing Er contents up to 2.5 wt.% and then decreased at 5 wt.% Er content. The Mg-5Zn-5Er alloy exhibits the lowest solid phase fraction (87.4%) and a reduced freezing range (74.2 °C), which leads to more effective liquid feeding in the latter stages of solidification. Combined with the grain size, the permeability of the mushy zone, and fracture morphology, the overall permeability is optimal in the Mg-5Zn-5Er alloy, which is beneficial for feeding the cavities and micro-pores. Meanwhile, a large amount of W phase precipitated by the eutectic reaction (L→α-Mg + W phase), which facilitates healing of the incurred cracking. Conversely, the Mg-5Zn-2.5Er alloy shows inferior feeding ability due to the lowest solid phase fraction (98.3%), wide freezing range (199.5 °C), and lowest permeability. Therefore, the Mg-5Zn-2.5Er alloy exhibits maximal hot cracking susceptibility, and the Mg-5Zn-5Er alloy exhibits minimal hot cracking susceptibility. This work provides guidance for improving the hot cracking resistance of cast Mg-Zn-Er alloy and enables an understanding of the hot cracking behaviors of Mg-Zn-RE alloys.

9.
Psychol Res Behav Manag ; 16: 939-948, 2023.
Artículo en Inglés | MEDLINE | ID: mdl-36992980

RESUMEN

Purpose: Grit plays a critical role in the academic achievement and future career success of college students. The family environment has an important influence on the development of individual grit, but the mechanisms linking family and grit are not well known. To further understand these relationships, this study sought to explore the mediating role of basic psychological needs between parental autonomy support and grit, and the moderating role of achievement motivation. Methods: The present study model was developed according to the proposed hypotheses and was analyzed using structural equation modeling. A total of 984 college students in Hunan Province, China participated in the present study. The following tools were used: Perceived Parental Autonomy Support Scale, Basic Psychological Needs Scales, Short Grit Scale, and Achievement Motivation Scale. Results: Parental autonomy support was positively correlated with basic psychological needs and grit, and both basic psychological needs and achievement motivation were positively correlated with grit. Basic psychological needs mediated the effect of parental autonomy support on grit. Achievement motivation moderated the second half of the path of the mediation model. Conclusion: Parental autonomy support influences perseverance through the mediation of basic psychological needs, and achievement motivation plays a moderating role. Findings of this study reveal the influence of family environment on grit, and give reference to the development of grit.

10.
Materials (Basel) ; 16(6)2023 Mar 13.
Artículo en Inglés | MEDLINE | ID: mdl-36984183

RESUMEN

Due to their excellent mechanical properties and large specific surface area, graphene and its derivatives are widely used in metal matrix composites as reinforcements. In this study, the thermal reduction behavior of large-size graphene oxide are investigated systematically, and reduced graphene oxide (RGO) with few residual oxygen groups and good structural integrity is obtained. ZK61 matrix composites with varying content of in situ RGO are fabricated using the semi-powder metallurgy method. The results reveal that the addition of RGO can cause the refinement of the grains and the second phase, which is attributed to the uniform distribution of the RGO throughout the matrix. The formation of nano-MgO particles is beneficial in increasing the interfacial bonding strength between the RGO and the matrix, resulting in simultaneous increments in yield strength and elongation in the RGO/ZK61 composites. The composite containing 0.6 wt.% RGO shows a superior mechanical property, including microhardness of 79.9 HV, yield strength of 203 MPa and excellent elongation of 17.5%, with increases of 20.9%, 8.6% and 7.4%, respectively, when compared with the ZK61 alloy. Quantitative analysis indicates that the main strengthening mechanisms of RGO-reinforced magnesium matrix composites are load transfer strengthening and grain refinement strengthening.

11.
PNAS Nexus ; 2(1): pgac289, 2023 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-36712936

RESUMEN

Changing attitudes in diplomatic relations is a common feature of international politics. However, such changes may trigger risky domino-like cascades of "friend-to-enemy" transitions among other counties and yielding catastrophic damage that could reshape the global network of international relationships. While previous attention has been focused on studying single pairs of international relationships, due to the lack of a systematic framework, it remains still unknown whether, and how, a single transition of attitude between two countries could trigger a cascade of attitude transitions among other countries. Here, we develop such a framework and construct a global evolving network of relations between country pairs based on 70,756,728 international events between 1,225 country pairs from January 1995 to March 2020. Our framework can identify and quantify the cascade of transitions following a given original transition. Surprisingly, weaker transitions are found to initiate most of the largest cascades. We also find that transitions are not only related to the balance of the local environment, but also global network properties such as betweenness centrality. Our results suggest that these transitions have a substantial impact on bilateral trade volumes and scientific collaborations. Our results reveal reaction chains of international relations, which could be helpful for designing early warning signals and mitigation methods for global international conflicts.

12.
Environ Sci Pollut Res Int ; 30(6): 15490-15504, 2023 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-36169820

RESUMEN

In the twenty-first century, global warming and other environmental issues have become the focus of international attention. The total generation of carbon emissions for the railway transportation industry in the BRIC countries (Brazil, Russia, Indian and China) accounted for 25.73% of the global carbon emissions in this industry during 2017. Therefore, it is necessary to identify the influencing factors of carbon emission in the railway transportation industry for the BRIC, in order to better control and reduce carbon emissions and to achieve the global goal of "net-zero emission." The logarithmic mean divisia index (LMDI) decomposition method was used to examine the factors that influenced carbon emissions from the railway transportation industry in the BRIC from 1997 to 2017. According to the findings, the total carbon emissions of the railway transportation industry in BRIC were 60.92 million tons in 2017, increased by 98.62% compared to 1997. The factor of economic output effect has contributed positively to the increase in carbon emissions in all identified countries. However, the effect of population size effect, energy structure, and transportation intensity effect for carbon emission demonstrated heterogeneity in BRIC. In addition, policy suggestions are put forward for the reduction of carbon emissions from the railway transportation industry in BRIC.


Asunto(s)
Dióxido de Carbono , Carbono , Carbono/análisis , Dióxido de Carbono/análisis , Desarrollo Económico , China , Transportes
13.
Materials (Basel) ; 15(24)2022 Dec 09.
Artículo en Inglés | MEDLINE | ID: mdl-36556592

RESUMEN

This paper investigated the effect of silicon phase morphology and size on microstructure, mechanical properties, and corrosion resistance of the AlSi10Mg alloys fabricated by selective laser melting (SLM). Using different heat treatment conditions for SLM-fabricated alloys, the microstructure characteristics and mechanical properties are analyzed. The corrosion behavior analysis is also performed using potentiodynamic polarization, electrochemical and immersion tests. Results show that the AlSi10Mg alloy directly fabricated by SLM has a continuous eutectic silicon network, which has a small driving force for corrosion and facilitates the deposition of corrosion products and generates a dense protective film. On the contrary, the formation of large isolated and uniformly distributed silicon particles produces a greater corrosion driving force after heat treatment, which makes most of the corrosion products transfer to the solution. The corrosion resistance of AlSi10Mg alloy directly fabricated by SLM is better than that of the alloys with heat treatment. Moreover, the heat treatment reduces the hardness of AlSi10Mg alloys due to the decrease in the solid solution strengthening effect.

14.
Materials (Basel) ; 15(22)2022 Nov 16.
Artículo en Inglés | MEDLINE | ID: mdl-36431617

RESUMEN

Ultrasonic-magnetic field coaxial hybrid GTAW(U-M-GTAW) is a new non-melting electrode welding method proposed by combining ultrasonic assisted GTAW(U-GTAW) and magnetic assisted GTAW(M-GTAW) on the regulation characteristics of the GTAW arc. U-M-GTAW introduces ultrasonic and magnetic field effects into GTAW to improve arc characteristics. The orthogonal experiment was designed to investigate the degree of influence of different process parameters on the arc. The degree of influence of ultrasonic power P, radiator height H, magnetic field current CW, welding current CW and tungsten electrode height HT on ΔL1 (degree of arc root diameter change), ΔL2 (degree of maximum diameter change) and ΔS (degree of area change) were analyzed. In the parameter range, P has the greatest degree of influence on ΔL1 and ΔL2. As all process parameters increase, L1 shows a tendency to decrease, indicating an increase in the compression of the arc root. ΔL2 with the increase in P and CW shows a trend of first decreasing and then increasing. ΔL2 with the increase in H decreases, indicating that the acoustic radiation force increases, the arc energy increases, and the dark region decreases. The magnetic field current increases, the bottom of the arc expands, and the height of the tungsten electrode increases, the arc dispersion and thus the difference between the dark and luminous regions at the bottom increases, resulting in ΔL2 with the increase in CM and HT increases. CW has the greatest degree of influence on ΔS. ΔS decreases and then increases as P and H increase, which indicates that the force on acoustic radiation increases and then decreases in the range. An increase in the magnetic field current increases the rotation of the arc, leading to an increase in the arc area. An increase in welding current leads to an increase in arc energy, expansion of the arc morphology, and an increase in ΔS. The tungsten electrode height increases, the arc diverges, the dark region increases, the luminous area decreases, and ΔS increases. Finally, combined with the analysis of ultrasonic field and magnetic field theory, changes in process parameters will affect the force of the arc and thus the arc morphology. The U-M-GTAW arc under the action of acoustic radiation force, the plasma flow is shifted in the direction of the arc axis, and the arc contraction, under the action of magnetic field force to generate circumferential current, the arc undergoes periodic rotation, which improves GTAW arc characteristics.

15.
Environ Sci Pollut Res Int ; 29(39): 58648-58663, 2022 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-35794327

RESUMEN

The problems of data leakage and unreliable information transfer in the management process make sustainability management an inevitable need for future development. Globally, there is increasing attention paid to blockchain technology and particularly its application in addressing sustainable management issues, both from academia and industry. Aiming to deepen the understanding of how blockchain technology could deal with sustainable management issues across different disciplines, this paper investigates the latest research on the application of blockchain technology in sustainable management published from 2017 to 2021. It is found that there is a drastic surge of publications in the recent 2 years. The analysis focuses on authors' origins, the collaboration network of the keywords, countries, and research topics covered. The application of blockchain technology in five key sectors of sustainable management, encompassing energy management, construction management, supply chain management, environmental management, and e-government management, is selected for further analysis detail. Also, a general framework for applying blockchain technology is proposed for broadening its use and dealing with sustainable management issues. The findings show that the identified 108 publications are distributed in 75 different journals, and scholars from China, the UK, and the USA have been working closely in BT-based sustainable management research. Blockchain technology is just emerging in sustainable management, and there is a great potential for applying blockchain technology to improve sustainable management performance and, more importantly, to provide solutions to quite a few long-lasting problems in these sectors. Opportunities for future research are also presented and discussed.


Asunto(s)
Cadena de Bloques , China , Publicaciones , Tecnología
16.
Urban Rail Transit ; 8(2): 134-145, 2022.
Artículo en Inglés | MEDLINE | ID: mdl-35765539

RESUMEN

With the rapid development of China's economy and society, China's railway transportation system has been dramatically improved in terms of its scale and operational efficiency. To uncover the underlying relationship between urbanization and railway network structure, this paper examines the evolution of China's railway transportation system from 1999 to 2019 by applying complex network theory. The results show that China's railway network (CRN) has become more connected, more "small-world" and more heterogeneous since the beginning of the twenty-first century. Based on the train flow and train travel distance, the evolutionary course of CRN is found to undergo two apparent stages, with a turning point in 2007. By calculating the regional railway connection index (RRCI), it is revealed that the planned core cities in different regions act as bridges connecting the regions to the rest of the whole network.

17.
Materials (Basel) ; 15(6)2022 Mar 11.
Artículo en Inglés | MEDLINE | ID: mdl-35329527

RESUMEN

The effect of the Ca2Mg6Zn3 phase on the corrosion behavior of biodegradable Mg-4.0Zn-0.2Mn-xCa (ZM-xCa, x = 0.1, 0.3, 0.5 and 1.0 wt.%) alloys in Hank's solution was investigated with respect to phase spacing, morphology, distribution and volume fraction. With the increase in Ca addition, the volume fraction of the Ca2Mg6Zn3 phase increased from 2.5% to 7.6%, while its spacing declined monotonically from 43 µm to 30 µm. The Volta potentials of secondary phases relative to the Mg matrix were measured by using scanning kelvin probe force microscopy (SKPFM). The results show that the Volta potential of the intragranular spherical Ca2Mg6Zn3 phase (+109 mV) was higher than that of the dendritic Ca2Mg6Zn3 phase (+80 mV). It is suggested that the Ca2Mg6Zn3 acted as a cathode to accelerate the corrosion process due to the micro-galvanic effect. The corrosion preferred to occur around the spherical Ca2Mg6Zn3 phase at the early stage and developed into the intragranular region. The corrosion rate increased slightly with increasing Ca content from 0.1 wt.% to 0.5 wt.% because of the enhanced micro-galvanic corrosion effect. The decrease in the phase spacing and sharp increase in the secondary phase content resulted in a dramatic increase in the corrosion rate of the ZM-1.0Ca alloy.

18.
Environ Sci Pollut Res Int ; 29(4): 5072-5091, 2022 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-34415521

RESUMEN

Nowadays, the development of green economy and the improvement of environmental efficiency have been a hotspot in both academia and industry. Especially, the effect of the collaborative agglomeration of manufacturing and productive services industries on environmental efficiency has drawn attention from Chinese policymakers, during a critical period of industrial transformation and upgrading and ecological civilization construction in China. However, few studies have explored whether and how industrial collaborative agglomeration affects environmental efficiency based on population structure perspective. To bridge this gap, using the methods of the stochastic frontier approach (SFA), the moderating effect of population structure, and the spatial effect, and employing the panel data of 66 cities in eastern China during 2009-2018, this paper studies the effect of industrial collaborative agglomeration on environmental efficiency and measure the fluctuates of influence including population structure. The results show that industrial collaborative agglomeration has the effect of improving environmental efficiency, and both of them have strong spatial spillover effect. Direct effect of the industrial collaborative agglomeration is more significant positive than indirect effect. It indicates that the environmental efficiency is affected by the industrial collaborative agglomeration in both the local region and neighboring regions. In addition, population density, aging and quality play a positive moderate role by strengthening the spillover effect of industrial collaborative agglomeration, while the moderating effect of population urbanization is not significant. Then, the recommendations and policy implications to improve environmental efficiency are put forward based on the research results: optimizing the coordinated governance system of regional ecological environment, accelerating the innovation of industrial value chain, and promoting the sustainable development of industry and ecology with the advantage of population structure.


Asunto(s)
Desarrollo Económico , Industrias , China , Ciudades , Eficiencia , Urbanización
19.
ACS Appl Mater Interfaces ; 13(49): 59288-59297, 2021 Dec 15.
Artículo en Inglés | MEDLINE | ID: mdl-34856800

RESUMEN

Most nontraditional intrinsic luminescent (NTIL) polymers currently show blue fluorescence. Tuning the emission color of NTIL polymers is of fundamental importance for their applications, but it still remains a scientific challenge. Herein, we initially develop an efficient strategy for bathochromic shifting of NTIL polymers by through-space acceptor-donor charge transfer between the in chain and the side chain. A variety of functionalized polyketones (FPK-R; where R = H, Ph, Me, tBu, F, and Cl) with furan rings built into the polymer chain were prepared by the Paal-Knorr reaction. FPK-R polymers showed bright and bathochromic-shifted fluorescence compared with their counterparts. The emission color could be tuned by changing the postfunctionalization conversion and varying the styrenic monomer substituent. Experimental and theoretical investigations revealed that the color tunability originated from enhanced through-space charge transfer between the side chain phenyl and the in chain furan rings.

20.
ACS Appl Mater Interfaces ; 13(48): 57880-57892, 2021 Dec 08.
Artículo en Inglés | MEDLINE | ID: mdl-34797646

RESUMEN

Synergetic self-healing anticorrosion behaviors, by forming a self-assembly protective layer and repairing coating passive barrier, exhibit great potential in handling the notorious metal corrosion phenomenon. Herein, we developed a nanofiber-supported anticorrosion coating with synergistic protection effects of both self-healing and active corrosion inhibition, via a facile electrospinning combined coating technique. Polycaprolactone (PCL) nanofiber integrated with 2-mecapobenzothiazole-loaded halloysite nanotubes (HNTs-MBT) is directly deposited on the surface of metal substrate, forming an interconnected fiber network framework. The encapsulated corrosion inhibitor MBT can be released by a pH-triggered manner to realize instant corrosion protections. Additionally, coating defects could be repeatedly repaired by continuous polymer fiber upon heat treatment and the anticorrosion efficiency effectively remained, even after three cycles of damage-healing. Moreover, the repaired coating also exhibited durable anticorrosion performance, mainly attributed to the synergetic effects of both thermal-triggered bulk healing and active corrosion inhibition. This type of dual-functional coating provides efficient anticorrosive performances and may show great promise in long-term corrosion protection.

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