Enhancing electrokinetics and desalination efficiency through catalysts and electrode modifications in microbial desalination cells.

Microbial desalination cells (MDCs) are considered as a sustainable technology for water desalination, wastewater treatment, and power generation. However, this neoteric technology suffers from different challenges, including sluggish oxygen reduction reaction and poor electron transfer from microbes to electrodes, ultimately leading to less power generation and desalination efficiency. This review delves into the intricate roles of both abiotic and biocatalysts in enhancing performance of MDCs through ion removal and charge transfer mechanisms. Detailed discussions highlight the comparative advantages and limitations of different catalyst types and insights into electrode modifications to optimise catalytic activity and biofilm formation. Further, recent advancements in electrode engineering, including surface coatings and integration of nanomaterial, geared towards enhancing efficiency of MDC and performance stability are discussed. Finally, future recommendations are provided, focusing on innovative catalyst designs, material integration, and considerations for scale-up and commercialisation, thereby offering a comprehensive roadmap for the continued advancement of MDC.

Co-pyrolysis of plastic waste and eucalyptus waste wood for fuel pellets production: A study of fuel, mechanical, and combustion characteristics under varying binder proportion.

The study explores the effect of varying molasses proportions as a binder on the characteristics of densified char obtained through the slow co-pyrolysis of plastic waste and Eucalyptus wood waste (Waste low-density polyethylene - Eucalyptus wood (WLDPE-EW) and Waste Polystyrene - Eucalyptus wood (WPS-EW)). Pyrolysis was conducted at 500 °C with a residence time of 120 min, employing plastic to wood waste ratios of 1:2 and 1:3 (w/w). The focus was on how varying the proportion of molasses (10-30 %), influences the physical and combustion properties of the resulting biofuel pellets. Our findings reveal that the calorific value of the pellets decreased from 28.94 to 27.44 MJ/Kg as the molasses content increased. However, this decrease in calorific value was compensated by an increase in pellet mass density, which led to a higher energy density overall. This phenomenon was attributed to the formation of solid bridges between particles, facilitated by molasses, effectively decreasing particle spacing. The structural integrity of the pellets, as measured by the impact resistance index, improved significantly (43-47 %) with the addition of molasses. However, a significant change in the combustion characteristics depicted by lower ignition and burnout temperatures were observed due to decrease in fixed carbon value and increase in volatile matter content, as the proportion of molasses increased. Despite these changes, the pellets demonstrated a stable combustion profile, suggesting that molasses are an effective binder for producing biofuel pellets through the densification of char derived from the co-pyrolysis of plastic and Eucalyptus wood waste. The optimized molasses concentration analyzed through multifactor regression analysis was 16.96 % with 28 % WLDPE proportion to produce WLDPE-EW char pellets. This study highlights the potential of using molasses as a sustainable binder to enhance the mechanical and combustion properties of biofuel pellets, offering a viable pathway for the valorization of waste materials.

PDA-Fe3O4 decorated carbon felt anode enhancing electrochemical performance of microbial fuel cells: Effect of electrode materials on electroactive biofilm.

Anode modification is an effective strategy for enhancing the electrochemical performance of microbial fuel cell (MFC). However, the impacts of the modified materials on anode biofilm development during MFC operation have been less studied. We prepared a novel PDA-Fe3O4-CF composite anode by coating original carbon felt anode (CF) with polydopamine (PDA) and Fe3O4 nanoparticles. The composite anode material was characterized by excellent hydrophilicity and electrical conductivity, and the anodic biofilm exhibited fast start-up, higher biomass, and more uniform biofilm layer after MFC operation. The MFC reactor assembled with the composite anode achieved a maximum power density of 608 mW m-2 and an output voltage of 586 mV, which were 316.4% and 72.4% higher than the MFC with the original CF anode, respectively. Microbial community analysis indicated that the modified anode biofilm had a higher relative abundance of exoelectrogen species in comparison to the unmodified anode. The PICRUSt data revealed that the anodic materials may affect the bioelectrochemical performance of the biofilm by influencing the expression levels of key enzyme genes involved in biofilm extracellular polymer (EPS) secretion and extracellular electron transfer (EET). The growth of the anodic biofilm would exert positive or negative influences on the efficiency of electricity production and electron transfer of the MFCs at different operating stages. This work expands the knowledge of the role that anodic materials play in the development and electrochemical performance of anodic biofilm in MFCs.

Simultaneous ammonia and organics degradation from municipal landfill leachate by electrochemical oxidation.

The two primary issues for wide implementation of the electrochemical oxidation of wastewater are the significant cost of electrode and high energy consumption. On the other side, conventional biological processes and membrane technology have several drawbacks for recalcitrant landfill leachate (LL) treatment. To address these issues, graphite/PbO2 anode was used to treat medium to mature age (biodegradability index, 5-day biochemical oxygen demand/chemical oxygen demand: 0.25) LL. To reduce the cost of the oxidation process and maximize the efficiency, operating conditions were optimized. The optimum parameter values were obtained as 24.7 mA cm-2, 180 ± 3 rpm, and 1.9 cm of current density, stirring rate, and electrode gap, respectively. Dissolved organic carbon (DOC), chemical oxygen demand (COD), and ammonia-N removal efficiencies of 55 ± 1.4%, 81 ± 1.9%, and 56 ± 3% were obtained after 8 h of degradation at optimum conditions. The decrease in aromatic substances and ultraviolet (UV) quenching materials were evaluated by UV-Visible spectroscopy and Specific UV absorbance. The conversion of aromatic compounds into simpler molecule compounds was also verified by Fourier-transform infrared spectroscopy analysis. The lab-scale anode synthesis cost was evaluated as 0.42 USD.

From slag to green: Aided-phytoremediation as a sustainable tool to rehabilitate land contaminated by steel slag and assessment of CO2 sequestration.

Steel slag (SS) has many applications, but its immediate reuse is not possible due to its inherent swelling potential and presence of toxic metals. Therefore, it can only be used after the aging process, which can be either natural or artificial. While few large-scale steel plants afford artificial aging, many small-scale ones opt for natural aging through stockpiling of SS. This results in an increase in soil pH to over 12, thus damaging the ecosystem and making it unviable for plant growth. This research focuses on the reclamation of land affected by SS through the formation of a Phyto-barrier using 22 native plant species aided by the application of a 2 % (v/v) solution of the organic amendment. Furthermore, the superior performance of plants belonging to the Fabaceae family was ascertained, while establishing Sesbania grandiflora as an able species for aided-phytoremediation due to its remarkable growth (≈ 10 ft tall and 33 cm in circumference) during the study period. The CO2 sequestered by the plantation showed that maximum sequestration has been done by Sesbania grandiflora (49.96 kg CO2 / tree/ year), and least by Azadirachta indica (0.35 kg CO2/tree/year). The overall CO2 sequestered by the plantation stood at 3.85 tons/year. A cost-benefit analysis of using aided-phytoremediation indicates an expense of 90 $ per year as the recurring expense, while carbon credits if monetized, would yield 154 $ to 308 $ as returns. The investigations of this study established a new approach to vegetation over SS-affected land, through native species and the application of organic amendment.

Effect of solution chemistry on the sedimentation, dissolution, and aggregation of the bimetallic Fe/Cu nanoparticles pre- and post-grafted with carboxymethyl cellulose.

The suitability of iron-based nanomaterials or composites for in-situ remediation hinges on their physicochemical stability. Introducing surface modifications like metal doping or polymer grafting can regulate interparticle forces, influencing particle stability. Thus, probing how grafting methods (i.e., pre- or post-grafting) tune material properties controlling interparticle forces, comprehend the synergistic effect of metal doping and polymer grafting, and evaluate stability under varying geochemical conditions are the way forward in designing sustainable remediation strategies. To this end, time-dependent sedimentation, dissolution, and aggregation of four synthesized iron-based nanoparticles (bare iron (Fe), copper doped bimetallic iron/copper (Fe/Cu), pre- and post-grafted Fe/Cu with carboxymethyl cellulose (CMC) - CMCpre-Fe/Cu and CMCpost-Fe/Cu, respectively) were carried out as a function of solution chemistry (i.e., pH - 5 to 10, ionic strength, IS - 0 to 100 mM NaCl, initial particle concentration, C0-20 to 200 mg.L-1) mimicking geoenvironmental conditions. CMCpre-Fe/Cu exhibited markedly higher particle availability (> 91 %) against sedimentation than others (bare Fe/Cu (11.28 %) > bare Fe (7.33 %) > CMCpost-Fe/Cu (6.09 %)) - suggesting the pivotal role of grafting method on particle stability. XDLVO energy profiles revealed pre-grafting altered magnetic properties favoring surface charge-driven electrostatic repulsion over magnetic attraction, thereby limiting aggregation-induced particle settling. In contrast, superior magnetic force overrides the electrostatic behavior for bare and post-grafted particles. Unlike bare and post-grafted nanoparticles, CMCpre-Fe/Cu aggregate size correlated positively with [H+] and IS, consistent with their settling behavior. Rise in C0 showed a visible negative effect on particle aggregation and, thereby, sedimentation except for CMCpre-Fe/Cu by facilitating particle collision through Brownian movement. Both acidic pH and copper doping promoted nanoparticle dissolution, whereas pre-grafting can provide a plausible solution against nanoparticle toxicity and loss of reactivity due to ionic release. To recapitulate, these findings are imperative in building a sustainable framework for environmental remediation application.

Progress and perspectives on carbon-based materials for adsorptive removal and photocatalytic degradation of perfluoroalkyl and polyfluoroalkyl substances (PFAS).

Per- and polyfluoroalkyl substances (PFAS) (also known as 'forever chemicals') have emerged as trace pollutants of global concern, attributing to their persistent and bio-accumulative nature, pervasive distribution, and adverse public health and environmental impacts. The unregulated discharge of PFAS into aquatic environments represents a prominent threat to the wellbeing of humans and marine biota, thereby exhorting unprecedented action to tackle PFAS contamination. Indeed, several noteworthy technologies intending to remove PFAS from environmental compartments have been intensively evaluated in recent years. Amongst them, adsorption and photocatalysis demonstrate remarkable ability to eliminate PFAS from different water matrices. In particular, carbon-based materials, because of their diverse structures and many exciting properties, offer bountiful opportunities as both adsorbent and photocatalyst, for the efficient abatement of PFAS. This review, therefore, presents a comprehensive summary of the diverse array of carbonaceous materials, including biochar, activated carbon, carbon nanotubes, and graphene, that can serve as ideal candidates in adsorptive and photocatalytic treatment of PFAS contaminated water. Specifically, the efficacy of carbon-mediated PFAS removal via adsorption and photocatalysis is summarised, together with a cognizance of the factors influencing the treatment efficiency. The review further highlights the neoteric development on the novel innovative approach 'concentrate and degrade' that integrates selective adsorption of trace concentrations of PFAS onto photoactive surface sites, with enhanced catalytic activity. This technique is way more energy efficient than conventional energy-intensive photocatalysis. Finally, the review speculates the cardinal challenges associated with the practical utility of carbon-based materials, including their scalability and economic feasibility, for eliminating exceptionally stable PFAS from water matrices.

Effective method for upcycling construction and demolition waste into concrete: A life cycle approach.

Different property enhancement techniques have already been established to support upcycling of construction and demolition waste as aggregate in concrete. However, the most suitable and sustainable method is still unknown. Quality improvement of recycled coarse aggregate (RCA) after any treatment method and its environmental impact is estimated using life cycle analysis (LCA). This article compares the environmental impacts of such treatment methods on RCA and aims to find out the most suitable method with minimum impacts. The functional unit of this study is considered the preparation of 1 tonne of treated aggregate (recycled), considering reduction in water absorption after the treatment. An LCA is carried out using the SimaPro software (https://simapro.com/) followed by ISO 14040/44 guidelines. Based on the LCA environmental profiles, thermal treatment is the highest emission contributing removal method followed by mechanical grinding. In strengthening of attached mortar methods, accelerated carbonation process is the major emission contributing method followed by a specific microbial treatment. Moreover, a sensitivity analysis was performed by varying the energy mix with a focus on renewable-based energy mix. The sensitivity analysis shows a shift on selection for the suitable treatment method and other possibilities considering renewable-based energy mix. A preliminary assessment and probable impact prediction could be conceptualized before the adoption of any treatment method on RCA for a particular location.

Synthesis and commercialization of bioplastics: Organic waste as a sustainable feedstock.

Substituting synthetic plastics with bioplastics, primarily due to their inherent biodegradable properties, represents a highly effective strategy to address the current global issue of plastic waste accumulation in the environment. Advances in bioplastic research have led to the development of materials with improved properties, enabling their use in a wide range of applications in major commercial sectors. Bioplastics are derived from various natural sources such as plants, animals, and microorganisms. Polyhydroxyalkanoate (PHA), a biopolymer synthesized by bacteria through microbial fermentation, exhibits physicochemical and mechanical characteristics comparable to those of synthetic plastics. In response to the growing demand for these environmentally friendly plastics, researchers are actively investigating various cleaner production methods, including modification or derivatization of existing molecules for enhanced properties and new-generation applications to expand their market share in the coming decades. By 2026, the commercial manufacturing capacity of bioplastics is projected to reach 7.6 million tonnes, with Europe currently holding a significant market share of 43.5 %. Bioplastics are predominantly utilized in the packaging industry, indicating a strong focus of their application in the sector. With the anticipated rise in bioplastic waste volume over the next few decades, it is crucial to comprehend their fate in various environments to evaluate the overall environmental impact. Ensuring their complete biodegradation involves optimizing waste management strategies and appropriate disposal within these facilities. Future research efforts should prioritize exploration of their end-of-life management and toxicity assessment of degradation products. These efforts are crucial to ensure the economic viability and environmental sustainability of bioplastics as alternatives to synthetic plastics.

Life cycle assessment of fermentative production of lactic acid from bread waste based on process modelling using pinch technology.

Bread waste (BW), a rich source of fermentable carbohydrates, has the potential to be a sustainable feedstock for the production of lactic acid (LA). In our previous work, the LA concentration of 155.4 g/L was achieved from BW via enzymatic hydrolysis, which was followed by a techno-economic analysis of the bioprocess. This work evaluates the relative environmental performance of two scenarios - neutral and low pH fermentation processes for polymer-grade LA production from BW using a cradle-to-gate life cycle assessment (LCA). The LCA was based on an industrial-scale biorefinery process handling 100 metric tons BW per day modelled using Aspen Plus. The LCA results depicted that wastewater from anaerobic digestion (AD) (42.3-51 %) and cooling water utility (34.6-39.5 %), majorly from esterification, were the critical environmental hotspots for LA production. Low pH fermentation yielded the best results compared to neutral pH fermentation, with 11.4-11.5 % reduction in the overall environmental footprint. Moreover, process integration by pinch technology, which enhanced thermal efficiency and heat recovery within the process, led to a further reduction in the impacts by 7.2-7.34 %. Scenario and sensitivity analyses depicted that substituting ultrapure water with completely softened water and sustainable management of AD wastewater could further improve the environmental performance of the processes.

Composite of graphitic carbon nitride and TiO2 as photo-electro-catalyst in microbial fuel cell.

The widespread application of surfactants and their subsequent discharge in the receiving water bodies is a very common issue in developing countries. In the present investigation, a composite of graphitic carbon nitride (GCN) and TiO2 was used as a photo-electro-catalyst in a microbial fuel cell (MFC)-based hybrid system for bio-electricity production and simultaneous pollutant removal (organic matter and sodium dodecyl sulphate, SDS). The GCN: TiO2 composite with a ratio of 70:30 (by wt. %) revealed a better electrochemical response; thus, it was used as a photo-electro-catalyst in MFC. Additionally, the photochemical characterization indicated a decrease in the band gap and charge recombination of GCN-TiO2 composite compared to standalone TiO2, which indicated a conducive effect of GCN addition. Further, on the actual use as a photo-electro-catalyst, the GCN-TiO2 catalysed MFC attained 58.2 ± 9.6% and 86.5 ± 7.1% of COD and SDS removal; while simultaneously harvesting a maximum power density of 1.07 W m-3, which was higher than standalone TiO2-catalysed MFC. The follow-up treatment in the charcoal bio-filter and photo-cathodic chamber of the hybrid system further improved the overall COD and SDS removal efficiency to 92.1 ± 2.7 and 95.6 ± 1.5%, respectively. The electro-catalytic performance of the GCN-TiO2 can be attributed to the presence of nitrogen-active species in the composite. The results of this investigation demonstrated a potential MFC-based hybrid system for the simultaneous secondary and tertiary treatment of municipal wastewater. Consequently, the outcome of this investigation indicates an innovative research direction in the field of photo-electro-catalyst, which can fit into the role of a photo-catalyst as well as an electro-catalyst.

Life Cycle Assessment of Microbial 2,3-Butanediol Production from Brewer's Spent Grain Modeled on Pinch Technology.

Microbial production of 2,3-butanediol (BDO) has received considerable attention as a promising alternate to fossil-derived BDO. In our previous work, BDO concentration >100 g/L was accumulated using brewer's spent grain (BSG) via microbial routes which was followed by techno-economic analysis of the bioprocess. In the present work, a life cycle assessment (LCA) was conducted for BDO production from the fermentation of BSG to identify the associated environmental impacts. The LCA was based on an industrial-scale biorefinery processing of 100 metric tons BSG per day modeled using ASPEN plus integrated with pinch technology, a tool for achieving maximum thermal efficiency and heat recovery from the process. For the cradle-to-gate LCA, the functional unit of 1 kg of BDO production was selected. One-hundred-year global warming potential of 7.25 kg CO2/kg BDO was estimated while including biogenic carbon emission. The pretreatment stage followed by the cultivation and fermentation contributed to the maximum adverse impacts. Sensitivity analysis revealed that a reduction in electricity consumption and transportation and an increase in BDO yield could reduce the adverse impacts associated with microbial BDO production.

A review on the scope of remediating chlorinated paraffin contaminated water bodies and soils/sediments.

Chlorinated paraffins (CPs) involve a wide range of complex mixtures of chlorinated alkanes. The versatility of their physicochemical properties and their wide range of use has turned them into ubiquitous materials. This review covers the scope of remediating CP-contaminated water bodies and soil/sediments via thermal, photolytic, photocatalytic, nanoscale zero-valent iron (NZVI), microbial and plant-based remediation techniques. Thermal treatments above 800 °C can lead to almost 100 % degradation of CPs by forming chlorinated polyaromatic hydrocarbons and thus should be supported with appropriate pollution control measures leading to high operational and maintenance costs. The hydrophobic nature of CPs lowers their water solubility and reduces their subsequent photolytic degradation. However, photocatalysis can have considerably higher degradation efficiency and generates mineralized end products. The NZVI also showed promising CP removal efficiency, especially at lower pH, which is challenging to achieve during field application. CPs can also be bioremediated by introducing both naturally occurring bacteria and also by engineered bacterial strains which are capable of producing specific enzymes (like LinA2 and LinB) to catalyze CP degradation. Depending on the type of CP, bioremediation can even achieve a dechlorination efficiency of >90 %. Moreover, enhanced degradation rates can be achieved through biostimulation. Phytoremediation has also exhibited CP bioaccumulation and transformation tendencies, both at lab-scale and in field-scale studies. The future research scope can include developing more definitive analytical techniques, toxicity and risk assessment studies of CPs and their degradation products, and technoeconomic and environmental assessment of different remediation approaches.

Cigarettes butt littering: The story of the world's most littered item from the perspective of pollution, remedial actions, and policy measures.

Cigarettes butt (CB) is one of the most littered items on the planet. This paper critically analyzes the factors responsible for CB littering, and associated environmental ramifications, and reviews all the possible technical, behavioural, and policy-based solutions. Even while smoking has declined globally, middle-income nations have seen an increase in consumption, which may be related to increased affordability and a lack of public awareness. The smokers' individual beliefs and habits, environmental ignorance, covert littering as a result of social taboos associated with smoking, and behavioural gaps between intention and action might all be contributing factors to CBs' littering behaviour. The low biodegradability of cellulose acetate filters and toxic chemical leaching from CBs are the most important aspects of CB environmental toxicity. The small size and low economic value of CB contribute to the inefficiencies of current waste collection and management systems. The current research on CB valorisation includes fired-clay bricks, asphalt concrete, biofilms, sound absorber, cellulose pulp, pesticides, and insecticides as downstream mitigation strategies. This study highlights the urgent need for policymakers to enforce regulations enabling innovative cigarette designs, the creation of deposit-refund schemes, extended producer responsibility and stringent waste collection mechanisms. Adopting gentler marketing strategies and non-confrontational behavioural nudges could result in an overall reduction in CB pollution.

Biochar-mediated removal of pharmaceutical compounds from aqueous matrices via adsorption.

Pharmaceutical is one of the noteworthy classes of emerging contaminants. These biologically active compounds pose a range of deleterious impacts on human health and the environment. This is attributed to their refractory behavior, poor biodegradability, and pseudopersistent nature. Their large-scale production by pharmaceutical industries and subsequent widespread utilization in hospitals, community health centers, and veterinary facilities, among others, have significantly increased the occurrence of pharmaceutical residues in various environmental compartments. Several technologies are currently being evaluated to eliminate pharmaceutical compounds (PCs) from aqueous environments. Among them, adsorption appears as the most viable treatment option because of its operational simplicity and low cost. Intensive research and development efforts are, therefore, currently underway to develop inexpensive adsorbents for the effective abatement of PCs. Although numerous adsorbents have been investigated for the removal of PCs in recent years, biochar-based adsorbents have garnered tremendous scientific attention to eliminate PCs from aqueous matrices because of their decent specific surface area, tunable surface chemistry, scalable production, and environmentally benign nature. This review, therefore, attempts to provide an overview of the latest progress in the application of biochar for the removal of PCs from wastewater. Additionally, the fundamental knowledge gaps in the domain knowledge are identified and novel strategic research guidelines are laid out to make further advances in this promising approach towards sustainable development.

Bread waste - A potential feedstock for sustainable circular biorefineries.

The management of staggering volume of food waste generated (∼1.3 billion tons) is a serious challenge. The readily available untapped food waste can be promising feedstock for setting up biorefineries and one good example is bread waste (BW). The current review emphasis on capability of BW as feedstock for sustainable production of platform and commercially important chemicals. It describes the availability of BW (>100 million tons) to serve as a feedstock for sustainable biorefineries followed by examples of platform chemicals which have been produced using BW including ethanol, lactic acid, succinic acid and 2,3-butanediol through biological route. The BW-based production of these metabolites is compared against 1G and 2G (lignocellulosic biomass) feedstocks. The review also discusses logistic and supply chain challenges associated with use of BW as feedstock. Towards the end, it is concluded with a discussion on life cycle analysis of BW-based production and comparison with other feedstocks.

Environmental impact evaluation of landfill mining of legacy waste with on-site sorting using life cycle assessment.

The present research is aimed at assessing the environmental impacts of landfill mining of soil-like material with on-site sorting for land application using life cycle assessment. The scenario is compared with no-landfill mining (base scenario) and future scenario (including material recycling and incineration). Soil-like material is processed using windrow composting. The impact assessment was performed using the EASETECH™ software tool. ReCipE 2016 midpoint world impact method with eight impact categories was used for assessing the environmental profiles. The functional unit of the assessment was 1 t of recovered waste in India. Overall, the results showed that excavation of landfilled waste with on-site recovery of soil and land application of soil resulted in higher environmental benefits compared to no mining condition in global warming potential (GWP), freshwater eutrophication (FEW), human toxicity (HT), and fossil depletion (FD), while higher impacts were observed in terrestrial acidification (TA), terrestrial ecotoxicity (TE), marine eutrophication (ME), and photochemical oxidation (PCO). After composting, land application of recovered soil contributed to environmental offsets in GWP, HT, and FEW while contributing to TE emissions. Emissions associated with excavation and on-site sorting contributed 55.1% to freshwater toxicity, 25.5% to human toxicity, 16.2% to climate change, and 10.8% to terrestrial acidification. The choice of energy, transportation, and fuel for waste activities affected the performance of alternative scenarios in GWP. Application of recovered metals in the manufacturing process, incineration of plastic, and textile components improved the environmental performance. The outcomes of this research will equip regulatory bodies in the development of guidelines and frameworks on material and energy recovery from the waste components mined from legacy waste.

Thermo-chemo-sonic pretreatment of lignocellulosic waste: Evaluating anaerobic biodegradability and environmental impacts.

In the present study, yard waste was pretreated by thermo-chemo-sonic pretreatment prior to anaerobic digestion to improve its anaerobic biodegradability. First, the pretreatment conditions were optimized using Box-Behnken design based response surface methodology for the maximum organic matter solubilisation. Then, the possible mechanism of delignification by thermo-chemo-sonic pretreatment was discussed. Moreover, the anaerobic digestion performance of untreated yard waste (UYW) and pretreated yard waste (PYW) was compared. The optimum pretreatment condition based on the increase in soluble COD and volatile solids (VS) was: 2997 kJ/kgTS ultrasonic energy, 74 °C, and 10.1 pH. The highest methane yield of 374 ± 28 mL/gVSadded for the PYW at the optimum condition was achieved, which was 37.5 % higher than the UYW (272 ± 16 mL/gVSadded). Finally, the environmental impacts associated with anaerobic digestion of both UYW and PYW were compared. The life cycle assessment confirmed a positive environmental impact of pretreatment.

Valorization of wastewater: A paradigm shift towards circular bioeconomy and sustainability.

Limitation in the availability of natural resources like water is the main drive for focussing on resource recovery from wastewater. Rapid urbanization with increased consumption of natural resources has severely affected its management and security. The application of biotechnological processes offers a feasible approach to concentrating and transforming wastewater for resource recovery and a step towards a circular economy. Wastewater generally contains high organic materials, nutrients, metals and chemicals, which have economic value. Hence, its management can be a valuable resource through the implementation of a paradigm transformation for value-added product recovery. This review focuses on the circular economy of "close loop" process by wastewater reuse and energy recovery identifying the emerging technologies for recovering resources across the wastewater treatment phase. Conventional wastewater treatment technologies have been discussed along with the advanced treatment technologies such as algal treatment, anammox technology, microbial fuel cells (MFC). Apart from recovering energy in the form of biogas and biohydrogen, second and third-generation biofuels as well as biohythane and electricity generation have been deliberated. Other options for resource recovery are single-cell protein (SCP), biopolymers as well as recovery of metals and nutrients. The paper also highlights the applications of treated wastewater in agriculture, aquaponics, fisheries and algal cultivation. The concept of Partitions-release-recover (PRR) has been discussed for a better understanding of the filtration treatment coupled with anaerobic digestion. The review provides a critical evaluation on the importance of adopting a circular economy and their role in achieving sustainable development goals (SDGs). Thus, it is imperative that such initiatives towards resource recovery from wastewater through integration of concepts can aid in providing wastewater treatment system with resource efficiency.

Biochar admixture cement mortar fines for adsorptive removal of heavy metals in single and multimetal solution: Insights into the sorption mechanisms and environmental significance.

The combined action of biochar and C-S-H (calcium-silicate-hydrate) in the cement mortars as adsorbents was explored for treating heavy metals from water. The biochar admixture cement mortars were ground to fines for use as adsorbents with the rationale that combined action of Ca, Si, Al etc. based industrial waste with conventional adsorbent biochar could enhance the removal efficiency of contaminants and therefore the overarching aim was to study the removal capacity for three selected heavy metals (Pb2+, Cu2+ and Zn2+) commonly found in the aqueous waste stream. Batch adsorption was carried out on single and multi-metal systems to determine the removal efficiency under varied conditions such as pH, dosage of adsorbent, the effect of contact time and the initial concentration of the adsorbate. For Pb(II), Cu (II) and Zn(II), pH 5 was optimized for single and multi-metal batch sorption studies. A dosage of 20 mg for single metal and 70 mg for multi-metal of an adsorbent dose was found to be sufficient to remove about 70-90% of the three heavy metals in 25 mL solution. Langmuir model best described the isotherm data with maximum adsorption capacities of 476, 81, 123 mg/g for Pb2+, Cu2+ and Zn2+ for BC-40 during single metal adsorption, which were quite comparable to other C-S-H and cement-based adsorbents. The metal hydroxides precipitation, the ion exchange between the Ca2+ and metal ions and metal complexation were explained as plausible mechanisms for the heavy metal removal.