1.
Org Biomol Chem
; 20(36): 7245-7249, 2022 09 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36073152
RESUMEN
Herein we present a photocatalyst- and additive-free radical hydroacylation of electron-poor double bonds under mild reaction conditions. Using 4-acyl-Hantzsch ester radical reservoirs, various Michael acceptors, enones and para-quinone methide substrates could be used. The protocol enabled further derivatizations and it could also be extended to a few unactivated alkenes. Moreover, the nature of the radical process was also investigated.