Simulation on Harmful Gas Control by Balanced Pressure Ventilation in the Fully Mechanized Caving Face under Sealed Fire Area of Small Coal Mine.

The harmful gas in the sealed fire area of a small coal mine rushes into the mining face of the lower coal seam, which restricts the efficient promotion of the working face. In this paper, based on the evolution law of caving coal rock dilatation coefficient, the characteristics of the heterogeneous distribution of permeability and voidage in goaf were obtained, and the mathematical model of gas migration in goaf is constructed. The numerical solution of gas migration in goaf under the sealed fire area of a small coal mine was realized by using the Free and Porous Media Flow module and the Transport of Dilute Matter in Porous Media module in COMSOL Multiphysics, and the corresponding measure was proposed. The results show that the fresh air flows into the goaf from both the inlet air roadway and the working face and then flows out from the upper corner. Driven by the air flow, the CO in the overlying sealed fire area of a small coal mine flows out from the upper corner of the working face, resulting in the CO overlimit. Due to the influence of air leakage and the CO overlimit in the working face, low oxygen occurs in the working face. According to the characteristics of gas emission, balanced pressure ventilation technology is proposed to control the low oxygen in the working face and the CO overlimit in the upper corner. It is found that the balanced pressure ventilation obviously increases the pressure of the working face, reduces the pressure difference between the two ends of the working face by 45.7-26.7%, and decreases the air leakage to the goaf in the upper corner of the inlet air roadway. The field application shows that the problems of low oxygen in the working face and a CO overlimit in the upper corner are effectively solved.

Influence of magma intrusion on coal geochemical characteristics: a case study of Tiefa Daxing coal mine.

Magma intrusion has an important influence on the physical and mechanical properties of coal and rock. In the area of magma intrusion, disasters such as gas outburst are prone to occur. Revealing its invasion law will be conducive to disaster management and energy development. For this purpose, changes in industrial analysis components of coal, mineral composition, major oxides, trace elements, and rare earth elements of coal under the thermal metamorphism of magma intrusion were analyzed. It is found that the moisture and volatile matter contents of the thermally affected coals in the mining face are generally lower than that of normal coals, while moisture and volatile matter contents are reduced towards to the magma intrusion contact. For example, the moisture and volatile matter of coal sample M01 decreased by 64.6% and 38.6% respectively compared with coal sample M05. During magma intrusion, some minerals remain on the surface of the coal body, resulting in changes in the mineral composition of the coal body. The decrease in carbon atom net spacing, the increase in crystallite aggregation and ductility, and aromaticity in thermally affected coals have a positive impact on the improvement of coal metamorphism. Due to the influences of magmatic intrusion, the variation rules of major oxides in coal are different, and the closer to the magmatic intrusion zone, the easier the major oxides are to be depleted. However, magma intrusion will not lead to the loss of all major oxides in thermally affected coals, such as content of CaO is 54.8%, which is higher than that of coal not affected by magmatic hydrothermal fluid. Most of the trace elements in the thermally affected coals of the No. 9 coal seam are depleted. The contents of rare earth elements are low on the whole coalbasis, with an average of 29.48 µg/g, and the distribution pattern towards to magmatic intrusion shows a wide and gentle "V" curve with left high and right low, showing the characteristics of enrichment of light rare earth elements.

A Functional Electrolyte Containing P-Phenyl Diisothiocyanate (PDITC) Additive Achieves the Interphase Stability of High Nickel Cathode in a Wide Temperature Range.

The lithium-ion batteries (LIBs) with high nickel cathode have high specific energy, but as the nickel content in the cathode active material increases, batteries are suffering from temperature limitations, unstable performance, and transition metal dissolution during long cycling. In this work, a functional electrolyte with P-phenyl diisothiocyanate (PDITC) additive is developed to stabilize the performance of LiNi0.8 Co0.1 Mn0.1 O2 (NCM811)/graphite LIBs over a wide temperature range. Compared to the batteries without the additive, the capacity retention of the batteries with PDITC-containing electrolyte increases from 23 % to 74 % after 1400 cycles at 25 °C, and from 15 % to 85 % after 300 cycles at 45 °C. After being stored at 60 °C, the capacity retention rate and capacity recovery rate of the battery are also improved. In addition, the PDITC-containing battery has a higher discharge capacity at -20 °C, and the capacity retention rate increases from 79 % to 90 % after 500 cycles at 0 °C. Both theoretical calculations and spectroscopic results demonstrate that PDITC is involved in constructing a dense interphase, inhibiting the decomposition of the electrolyte and reducing the interfacial impedance. The application of PDITC provides a new strategy to improve the wide-temperature performance of the NCM811/graphite LIBs.

Scale Effect on Uniaxial Compressive Properties of the Outburst-Prone Coal.

Coal is a naturally discontinuous, heterogeneous, and anisotropic brittle material. The uniaxial compressive strength of coals is significantly affected by the sample size-dominated microstructure of minerals and fractures. The scale effect of the mechanical properties of coal is a bridge connecting the mechanical parameters of laboratory-scale coal samples and engineering-scale coal. The scale effect of coal strength is of great significance in explaining the fracturing law of the coal seam and reveal the mechanism of coal and gas outburst disaster. The uniaxial compressive strength of outburst-prone coal samples with different scale sizes was tested, the variation law of uniaxial compressive strength with increasing scale was analyzed, and the mathematical models of both were constructed. The results show that the average compressive strength and elastic modulus of outburst coal decrease exponentially with the increase in scale size, and the decrease rate is reduced. The average compressive strength of the tested coal samples decreased from 10.4 MPa for size 60 × 30 × 30 mm3 to 1.9 MPa for scale 200 × 100 × 100 mm3, which decreases by 81.4%.

Supporting optimization of thick seam roadway with top coal based on orthogonal matrix analysis.

Aiming at the problem of large deformation and difficulty in surrounding rock control of the top coal roadway in thick seam, theoretical analysis, theoretical analysis, numerical simulation, orthogonal matrix analysis and other methods were used to study the roof deformation and support parameter optimization of the top coal roadway in thick seam. Firstly, the structural model and roof mechanical model of the top coal roadway in thick seam were established, and the deformation coefficient TK was defined based on the relationship between curvature radius and bending moment, maximum bending moment and ultimate tensile strength of beam. According to the ratio of deformation rate between TK and beam to determine the roof deformation mode of top coal roadway, the discriminant conditions of roadway roof stability under two deformation conditions are obtained. Due to the characteristics of serious coal-rock fragmentation, large roof deformation, and integration of top coal and side coal. Therefore, the combined support method of "high prestressed long and short anchor cables" is proposed by double arch bearing structure control technology. Finally, based on the orthogonal matrix analysis method of supporting parameters optimization of the top coal roadway in thick seam, the analysis amount of supporting scheme is significantly reduced, the comprehensive evaluation of multi-factor and multi-supporting effect of roadway support is realized, and the optimal supporting scheme is obtained. Compared with the surrounding rock of the roadway without support, the deformation of the roof is reduced by 27.27%, the deformation of the two sides is reduced by 45.24%, and the tensile failure volume is reduced by 54.66%. The top coal roadway in thick seam has been effectively controlled, which provides guarantee for high yield and high efficiency of the mine.

Bolt-Cable-Mesh Integrated Support Technology for Water Drenching Roadway in Thick Coal Seam.

Aiming at the problems of large deformation and difficult control of the mining roadway water drenching in a thick coal seam, the principle of double-arch zoning cooperative surrounding rock control is studied by using the combined method of theoretical analysis, numerical simulation, and industrial experiment. The water-rock interaction of the surrounding rock of water-drenching roadway is proposed, taking into account the damage to the mechanical parameters of the surrounding rock caused by soaking water. The water-mechanical-damage coupling model for surrounding rock of a coal seam roadway is constructed, and is numerically solved by the code development using the FISH language. The principle of "high prestressed bolt-cable-mesh" zone coordinated control is revealed, and the existence of a compressive stress arch is verified by FLAC3D software. The three support schemes were compared and analyzed by numerical simulation software. We affirmed the bolt length of 2400 mm, spacing of 0.9 m, row spacing of 1 m, cable length of 7300 mm, and arrangement 3-2-3 as the optimal support scheme and applied this scheme in the Zhangcun Coal Mine. The results show that the maximum deformation of the roadway roof is 142 mm, and the ultimate convergence of the two sides is 83 mm. The surrounding rock has been effectively controlled.

Numerical simulation of roadway deformation and failure under different degrees of dynamic disturbance.

Deformation and failure of the roadway surrounding rock under dynamic disturbance were explored, which is essential for the control of the surrounding rock. The impact of dynamic disturbance on the deformation and failure of the roadway surrounding rock was studied from a single factor perspective using numerical simulation software. The disturbance intensity, frequency, and time were determined to affect the deformation and plastic zone of the surrounding rock. Firstly, a multi-factor integrated study was achieved using an orthogonal experimental design, and the impact of the three factors on the deformation and plastic zone of the surrounding rock were studied by applying mean value and extreme difference. The results show that the degree of influence of deformation of the roof is time > intensity > frequency in order. The impact of the plastic zone volume is intensity > frequency > time in order. Finally, a multivariate regression model was established using multiple regression analysis. The P = 0 < 0.05 for the regression model is obtained by variance analysis, and the equation regression is significant, which can effectively predict the deformation and failure of the surrounding rock under dynamic disturbance.

1,2,3,4-Tetrakis(2-cyanoethoxy)butane (TCEB)-Assisted Construction of Self-Repair Electrode Interface Films to Improve the Performance of 4.5 V Pouch LiCoO2/Artificial Graphite Full Cells Operating at 45 °C.

1,2,3,4-Tetrakis(2-cyanoethoxy)butane (TCEB) is first evaluated as a functional electrolyte additive to increase the charge cutoff voltage and energy density of pouch LiCO2 (LCO)/artificial graphite (AG) lithium-ion batteries (LIBs) at a high temperature of 45 °C. The charge (0.7 C) and discharge (1 C) tests show that TCEB effectively improves the cycle stability of cells under a high charge cutoff voltage of 4.5 V. At 25 °C, the capacity retention of the cells with TCEB increases from 0.0% to 72.1% after 1200 cycles. At 45 °C, the capacity retention of the cells without TCEB after 50 cycles is close to 0.0%, while the capacity retention of the cells with TCEB is still 81.6%, even after 350 cycles. The spectroscopic characterization results demonstrate that the TCEB electrolyte additive participates in the construction of a self-repair electrode/electrolyte interface film. Subsequently, low impedance and strong protective layers are formed on the two electrode surfaces. The quantitative analysis results and a theoretical calculation also show that TCEB effectively inhibits the dissolution of Co3+ and maintains the structural integrity of electrode materials. These results indicate that TCEB endows LIBs with excellent cycle stability and is a promising electrolyte additive for the high-voltage and high-temperature conditions of LCO-based LIBs.