RESUMEN
Nanostructuring of metals is nowadays considered as a promising strategy towards the development of materials with enhanced electrochemical performance. Porous and fully dense CuNi films were electrodeposited on a Cu plate by electrodeposition in view of their application as electrocatalytic materials for the hydrogen evolution reaction (HER). Porous CuNi film were synthesized using the hydrogen bubble template electrodeposition method in an acidic electrolyte, while fully dense CuNi were electrodeposited from a citrate-sulphate bath with the addition of saccharine as a grain refiner. The prepared films were characterized chemically and morphologically by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). The Rietveld analysis of the XRD data illustrates that both CuNi films have a nanosized crystallite size. Contact angle measurements reveal that the porous CuNi film exhibits remarkable superhydrophobic behavior, and fully dense CuNi film shows hydrophilicity. This is predominately ascribed to the surface roughness of the two films. The HER activity of the two prepared CuNi films were investigated in 1 M KOH solution at room temperature by polarization measurements and electrochemical impedance spectroscopy (EIS) technique. Porous CuNi exhibits an enhanced catalysis for HER with respect to fully dense CuNi. The HER kinetics for porous film is processed by the Volmer-Heyrovsky reaction, whereas the fully dense counterpart is Volmer-limited. This study presents a clear comparison of HER behavior between porous and fully dense CuNi films.
RESUMEN
Magnetic chitosan hydrogel has aroused immense attention in recent years due to their biomedical significance and magnetic responsiveness. Here, A new electrodeposition method is reported for the fabrication of a novel CuNi-based magnetic chitosan freestanding film (MCFF) in an acidic chitosan plating bath containing SDS-modified CuNi NPs. Contrary to chitosan's anodic and cathodic deposition, which typically involves electrochemical oxidation, the synthetic process is triggered by coordination of chitosan with Cu and Ni ions in situ generated by the controlled surface dissolution of the suspended NPs with the acidic plating bath. The NPs provide not only the ions required for chitosan growth but also become entrapped during electrodeposition, thereby endowing the composite with magnetic properties. The obtained MCFF offers a wide range of features, including good mechanical strength, magnetic properties, homogeneity, and morphological transparency. Besides the fundamental interest of the synthesis itself, sufficient mechanical strength ensures that the hydrogel can be used by either peeling it off of the electrode or by directly building a complex hydrogel electrode. Its fast and easy magnetic steering, separation and recovery, large surface area, lack of secondary pollution, and strong chelating capability could lead to it finding applications as an electrochemical detector or adsorbent.
RESUMEN
Ni-based bimetallic films with 20 at.% and 45 at.% Cu and mesostructured surfaces were prepared by electrodeposition from an aqueous solution containing micelles of P123 triblock copolymer serving as a structure-directing agent. The pH value of the electrolytic solution had a key effect on both the resulting Cu/Ni ratio and the surface topology. The catalytic activity of the CuNi films toward hydrogen evolution reaction was investigated by cyclic voltammetry (CV) in 1 M KOH electrolyte at room temperature. The Cu45Ni55 film showed the highest activity (even higher than that of a non-mesostructured pure Ni film), which was attributed to the Ni content at the utmost surface, as demonstrated by CV studies, as well as the presence of a highly corrugated surface.
RESUMEN
Although nanoporous materials have been fabricated by electrodeposition using micelles of P-123 as structure-directing entities, the possible geometry obtained has been limited to nanoporous films. Herein, a novel dual-template assisted electrodeposition method to fabricate Cu/Cu2O porous nanowires (PNs) using polymeric micelles as a soft template and polycarbonate membranes as a hard template is reported. These nanowires consist of a porous skeleton with nanosized pores of 20 nm on average and crystallized ligaments. Morphology, composition, and crystal structure are systematically investigated and the formation mechanism is discussed. The as-deposited Cu/Cu2O PNs are found to exhibit high electrocatalytic activity toward electroreduction of nitrate. At an applied cathodic potential of 0.53 V vs. the reference reversible hydrogen electrode, the selectivity for NH3 conversion is 37.3%. Our approach is anticipated to work for the synthesis of PNs of other materials that could be obtained via electrochemical means.
